4.8 Review

The mechanochemical synthesis of polymers

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Article Chemistry, Multidisciplinary

Mechanochemically-Assisted Synthesis of Polyimides

Tilo Rensch et al.

Summary: Polyimides were synthesized with a high yield in under 1 hour using a beat and heat approach, involving solvent-free vibrational ball milling and thermal treatment, exploring various additives and conducting quantum chemical calculations. Water removal was identified as the crucial step in the reaction mechanism, making this method significantly faster and more versatile than traditional solution-based processes.

CHEMSUSCHEM (2022)

Article Polymer Science

The mechanochemical Friedel-Crafts polymerization as a solvent-free cross-linking approach toward microporous polymers

Annika Krusenbaum et al.

Summary: This study presents the mechanochemical Friedel-Crafts alkylation of 1,3,5-triphenylbenzene with two organochloride cross-linking agents, DCM and CHCl3. The DCM-linked polymers showed flexibility and sensitivity to parameter changes, while the CHCl3-linked polymers exhibited a rigid structure with consistent high porosity. The environmentally friendly approach resulted in higher SSA(BET) values compared to traditional synthesis methods.

JOURNAL OF POLYMER SCIENCE (2022)

Article Chemistry, Multidisciplinary

A Diarylacetonitrile as a Molecular Probe for the Detection of Polymeric Mechanoradicals in the Bulk State through a Radical Chain-Transfer Mechanism

Takumi Yamamoto et al.

Summary: This study introduces an innovative strategy to detect mechanoradicals visually and quantitatively, using a fluorescent molecular probe that generates relatively stable radicals. Mechanoradicals generated by ball milling of polystyrene samples were successfully detected through this radical chain-transfer mechanism, enabling visualization and quantitative evaluation of mechanoradicals generated by polymer-chain scission.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Highly Efficient Solid-State Hydrolysis of Waste Polyethylene Terephthalate by Mechanochemical Milling and Vapor-Assisted Aging

Vjekoslav Strukil

Summary: Despite advancements in chemical recycling of synthetic polymers, efficient conversion of post-consumer PET into TPA under ambient conditions remains a challenge. Mechanochemistry and solid-state ball milling show promise in achieving this conversion, as demonstrated in this study on a gram-scale depolymerization of PET into TPA.

CHEMSUSCHEM (2021)

Review Chemistry, Multidisciplinary

Tailoring the Properties of Optical Force Probes for Polymer Mechanochemistry

Siyang He et al.

Summary: The correlation between the mechanical properties of polymer materials and their molecular constituents has led to the development of optical force probes (OFPs) to study unique mechanical behaviors. Polymers exhibit diverse properties, requiring tailored OFP solutions to meet energy, time, and spatial resolution needs. Researchers continue to highlight notable examples and address future challenges in this emerging field.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Review Crystallography

Synthesis of Metal Organic Frameworks by Ball-Milling

Cheng-An Tao et al.

Summary: Metal-organic frameworks (MOFs) have unique periodic pore structure and excellent properties, making them widely used in various fields. Ball milling is an efficient method for large-scale synthesis of MOFs, with influencing factors including additives, metal sources, organic linkers, and reaction conditions. The future development prospect of MOFs synthesis by grinding is proposed.

CRYSTALS (2021)

Review Chemistry, Multidisciplinary

The many flavours of mechanochemistry and its plausible conceptual underpinnings

Robert T. O'Neill et al.

Summary: Mechanochemistry involves diverse phenomena where mechanical load influences chemical reactions, such as motor protein function, organic synthesis in a ball mill, reactions at a propagating crack, chemical actuation, and polymer fragmentation. The rate of deformation in mechanochemistry affects which and how many bonds break, either powering macroscopic motion in otherwise endergonic reactions or being driven by spontaneous chemical reactions. The complexity of mechanochemistry lies in the dynamic coupling between inertial motion at the microscale and changes in chemical bonding across multiple length scales and timescales.

NATURE REVIEWS CHEMISTRY (2021)

Article Polymer Science

Simple and Rapid Mechanochemical Synthesis of Lactide and 3S-(Isobutyl)morpholine-2,5-dione-Based Random Copolymers Using DBU and Thiourea

Tobias F. Burton et al.

Summary: This study explores the mechanochemical ring-opening copolymerization of leucine-derived 3S-(isobutyl)morpholine-2,5-dione (MD) and lactide (LA) using a catalytic system composed of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) and 3-[3,5-bis(trifluoromethyl)phenyl]-1-cyclohexylthiourea (TU). The feasibility of ring-opening copolymerizations in mechanochemical systems and the beneficial cocatalytic effects of TU for ROP control were demonstrated. Further parallels between solution-and mechanochemical-based ROPs were observed.

ACS MACRO LETTERS (2021)

Article Chemistry, Multidisciplinary

Benzene Ring Knitting Achieved by Ambient-Temperature Dehalogenation via Mechanochemical Ullmann-Type Reductive Coupling

Hao Chen et al.

Summary: A novel method using mechanochemical Ullmann-type reactions to promote direct aromatic ring knitting has been demonstrated to afford CPNs with high surface areas and mesoporous architecture under neat and ambient conditions. The versatility of this approach has been confirmed by successful construction of various CPNs and even highly crystalline graphite product, showing good electrochemical performance in lithium-ion batteries. This strategy expands the frontiers of CPN synthesis and provides new opportunities for their scalable applications.

ADVANCED MATERIALS (2021)

Article Chemistry, Multidisciplinary

Introduction of a Luminophore into Generic Polymers via Mechanoradical Coupling with a Prefluorescent Reagent

Koji Kubota et al.

Summary: A novel strategy was developed to introduce a luminophore into generic polymers through mechanical stimulation, resulting in the successful incorporation of a luminophore into the polymer. This method allowed for the direct preparation of luminescent polymeric materials, potentially transforming existing commodity polymers into more valuable functional materials.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Tackling Solubility Issues in Organic Synthesis: Solid-State Cross-Coupling of Insoluble Aryl Halides

Tamae Seo et al.

Summary: The study presents a fast and efficient solid-state method for Suzuki-Miyaura cross-coupling reactions that can handle reactions which are not feasible under traditional solution conditions. A new luminescent organic material with strong red emission was discovered and successfully prepared through molecular transformations.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

Solvent-Free Mechanochemical Post-Polymerization Modification of Ionic Polymers

Joo Won Lee et al.

Summary: A solvent-free mechanochemical reaction was used to modify ammonium-functionalized polyether to imine within 1 hour without bond breakage. This approach shows potential for a wide range of aldehydes, suggesting a new method for post-polymerization modification of polymers.

CHEMSUSCHEM (2021)

Article Chemistry, Physical

Unveiling mechanochemistry: Kinematic-kinetic approach for the prediction of mechanically induced reactions

Eva Gil-Gonzalez et al.

Summary: Mechanochemistry has attracted significant attention in recent decades, although the conversion of mechanical energy into chemical energy remains poorly understood. Neglecting experimental parameters makes reproducibility of results challenging. The proposed kinematic-kinetic approach offers a reliable method for parametrizing and modeling mechanically induced reactions.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Article Chemistry, Physical

The Mechanism of Surface-Radical Generation and Amorphization of Crystalline Quartz Sand upon Mechanochemical Grinding

Kapish Gobindlal et al.

Summary: Structural and morphological changes during mechanochemical grinding of quartz sand were characterized using various analytical techniques. Surface area increased rapidly during the initial 60 minutes of grinding but did not lead to formation of mechanoradicals. Instead, a significant increase in species levels was observed after an initial lag phase. Analysis over 600 minutes revealed matrix amorphization.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

Article Green & Sustainable Science & Technology

Extensive Screening of Solvent-Linked Porous Polymers through Friedel-Crafts Reaction for Gas Adsorption

Vepa Rozyyev et al.

Summary: This study presents a simplified variant of Friedel-Crafts synthesis for highly porous COPs based on solvent-mediated crosslinking, leading to the production of 29 new COPs with high gas uptake capabilities. The findings suggest significant potential in producing sustainable porous materials through a simple and scalable methodology developed in this research.

ADVANCED ENERGY AND SUSTAINABILITY RESEARCH (2021)

Article Chemistry, Multidisciplinary

Depolymerization of polystyrene under ambient conditions

Viktor P. Balema et al.

Summary: Depolymerization of polystyrene to monomeric styrene is achieved through mechanochemical processing in metal-based milling media, generating carbon-centered free radicals detected by EPR spectroscopy even in air.

NEW JOURNAL OF CHEMISTRY (2021)

Review Chemistry, Multidisciplinary

Mechanochemistry for Synthesis

Tomislav Friscic et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Polymer Science

Truxene-based Conjugated Microporous Polymers via Different Synthetic Methods

Meng-Yang Wang et al.

CHINESE JOURNAL OF POLYMER SCIENCE (2020)

Article Chemistry, Multidisciplinary

Atom Transfer Radical Polymerization in the Solid-State

Hong Y. Cho et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Chemistry, Multidisciplinary

Direct Mechanocatalysis: Using Milling Balls as Catalysts

Wilm Pickhardt et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Article Chemistry, Multidisciplinary

Mechanochemical Cyclodehydrogenation with Elemental Copper: An Alternative Pathway toward Nanographenes

Sven Graetz et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

Article Chemistry, Physical

Five-Minute Mechanosynthesis of Hypercrosslinked Microporous Polymers

Jet-Sing M. Lee et al.

CHEMISTRY OF MATERIALS (2020)

Article Chemistry, Physical

Hypercrosslinked mesoporous polymers: Synthesis, characterization and its application for catalytic reduction of 4-nitrophenol

Huimin Zhou et al.

COLLOID AND INTERFACE SCIENCE COMMUNICATIONS (2020)

Article Polymer Science

The Next 100 Years of Polymer Science

Alaa S. Abd-El-Aziz et al.

MACROMOLECULAR CHEMISTRY AND PHYSICS (2020)

Review Chemistry, Inorganic & Nuclear

Transport properties in porous coordination polymers

Jet-Sing M. Lee et al.

COORDINATION CHEMISTRY REVIEWS (2020)

Editorial Material Polymer Science

Polymer Mechanochemistry and the Emergence of the Mechanophore Concept

Guillaume De Bo

MACROMOLECULES (2020)

Article Metallurgy & Metallurgical Engineering

The Use of Mechanical Activation of Polyvinyl Chloride in the Presence of Alkalis for Synthesis of Porous Carbon Materials

Yu. G. Kryazhev et al.

PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES (2020)

Article Chemistry, Physical

In-situ reaction monitoring of a mechanochemical ball mill reaction with solid state NMR

Jan Gerrit Schiffmann et al.

SOLID STATE NUCLEAR MAGNETIC RESONANCE (2020)

Article Chemistry, Inorganic & Nuclear

Rapid mechanochemical synthesis of metal-organic frameworks using exogenous organic base

Zihao Wang et al.

DALTON TRANSACTIONS (2020)

Review Materials Science, Multidisciplinary

Electrochemical polymerization: an emerging approach for fabricating high-quality luminescent films and super-resolution OLEDs

Manlin Zhao et al.

JOURNAL OF MATERIALS CHEMISTRY C (2020)

Review Chemistry, Physical

Emerging applications of porous organic polymers in visible-light photocatalysis

Tian-Xiong Wang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

Review Chemistry, Multidisciplinary

Porous organic polymers: a promising platform for efficient photocatalysis

Ting Zhang et al.

MATERIALS CHEMISTRY FRONTIERS (2020)

Article Engineering, Environmental

Amide-based covalent organic frameworks materials for efficient and recyclable removal of heavy metal lead (II)

Guiliang Li et al.

CHEMICAL ENGINEERING JOURNAL (2019)

Article Chemistry, Multidisciplinary

Mechanochemical Phosphorylation of Polymers and Synthesis of Flame-Retardant Cellulose Nanocrystals

Blaine G. Fiss et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Chemistry, Organic

Mechanochemical synthesis of poly(trimethylene carbonate)s: an example of rate acceleration

Sora Park et al.

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY (2019)

Review Polymer Science

Highly Porous Organic Polymers for Hydrogen Fuel Storage

Kimberley Cousins et al.

POLYMERS (2019)

Article Chemistry, Multidisciplinary

Sustainable Porous Polymer Catalyst for Size-Selective Cross-Coupling Reactions

Sungyoon Kim et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Chemistry, Organic

Mechanochemical amorphization of chitin: impact of apparatus material on performance and contamination

Thomas Di Nardo et al.

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY (2019)

Article Chemistry, Physical

Tailoring the porosity of a mesoporous carbon by a solvent-free mechanochemical approach

Desiree Leistenschneider et al.

CARBON (2019)

Article Chemistry, Multidisciplinary

Introduction to Covalent Organic Frameworks: An Advanced Organic Chemistry Experiment

Maria Jose Mancheno et al.

JOURNAL OF CHEMICAL EDUCATION (2019)

Article Chemistry, Physical

Experimental Evidence of Confined Methane Hydrate in Hydrophilic and Hydrophobic Model Carbons

Mirian E. Casco et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2019)

Article Nanoscience & Nanotechnology

Upcycling of polyurethane waste by mechanochemistry: synthesis of N-doped porous carbon materials for supercapacitor applications

Christina Schneidermann et al.

BEILSTEIN JOURNAL OF NANOTECHNOLOGY (2019)

Article Chemistry, Multidisciplinary

Investigations of Thermally Controlled Mechanochemical Milling Reactions

Nikola Cindro et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

Article Chemistry, Multidisciplinary

Direct Mechanocatalysis: Palladium as Milling Media and Catalyst in the Mechanochemical Suzuki Polymerization

Christian G. Vogt et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Multidisciplinary Sciences

Rapid mechanochemical encapsulation of biocatalysts into robust metal-organic frameworks

Tz-Han Wei et al.

NATURE COMMUNICATIONS (2019)

Review Chemistry, Multidisciplinary

Mechanochemistry of Gaseous Reactants

Carsten Bolm et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Nitrogen-Doped Biomass-Derived Carbon Formed by Mechanochemical Synthesis for Lithium-Sulfur Batteries

Christina Schneidermann et al.

CHEMSUSCHEM (2019)

Article Chemistry, Physical

The effect of milling parameters on the mechanochemical synthesis of Pd-CeO2 methane oxidation catalysts

Maila Danielis et al.

CATALYSIS SCIENCE & TECHNOLOGY (2019)

Article Chemistry, Multidisciplinary

Mechanochemical synthesis of N-doped porous carbon at room temperature

Mirian Elizabeth Casco et al.

NANOSCALE (2019)

Article Chemistry, Multidisciplinary

Metrics of Green Chemistry and Sustainability: Past, Present, and Future

Roger A. Sheldon

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2018)

Article Engineering, Chemical

Dry grinding in planetary ball mills: Evaluation of a stressing model

Christine Burmeister et al.

ADVANCED POWDER TECHNOLOGY (2018)

Article Chemistry, Multidisciplinary

Accelerating Membrane-based CO2 Separation by Soluble Nanoporous Polymer Networks Produced by Mechanochemical Oxidative Coupling

Xiang Zhu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Review Chemistry, Physical

Methane Hydrate in Confined Spaces: An Alternative Storage System

Lars Borchardt et al.

CHEMPHYSCHEM (2018)

Review Chemistry, Multidisciplinary

Mechanochemistry and organic synthesis: from mystical to practical

J. Andersen et al.

GREEN CHEMISTRY (2018)

Review Chemistry, Multidisciplinary

The Green ChemisTREE: 20 years after taking root with the 12 principles

Hanno C. Erythropel et al.

GREEN CHEMISTRY (2018)

Article Engineering, Chemical

Experimental and Theoretical Study of the Self-Initiation Reaction of Methyl Acrylate in Free-Radical Polymerization

Hossein Riazi et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2018)

Article Chemistry, Multidisciplinary

Electrochemically Controlled Cationic Polymerization of Vinyl Ethers

Brian M. Peterson et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Review Polymer Science

Porous ionic polymers: Design, synthesis, and applications

Dan Xu et al.

PROGRESS IN POLYMER SCIENCE (2018)

Article Chemistry, Multidisciplinary

Mechanochemistry as an emerging tool for molecular synthesis: what can it offer?

Joseph L. Howard et al.

CHEMICAL SCIENCE (2018)

Article Chemistry, Physical

Solvent-free synthesis of a porous thiophene polymer by mechanochemical oxidative polymerization

S. Graetz et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

Article Chemistry, Multidisciplinary

Viologen-Hypercrosslinked Ionic Porous Polymer Films as Active Layers for Electronic and Energy Storage Devices

Luxin Wang et al.

ADVANCED MATERIALS INTERFACES (2018)

Article Chemistry, Multidisciplinary

Insights into Mechanochemical Reactions at Targetable and Stable, Sub-ambient Temperatures

Joel Andersen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Review Chemistry, Multidisciplinary

Polymer Mechanochemistry: Manufacturing Is Now a Force to Be Reckoned With

Niamh Willis-Fox et al.

Article Green & Sustainable Science & Technology

The In Situ Electrolyte Concept: Using Activation Chemicals as Electrolytes for Carbon-Based Supercapacitors

Desiree Leistenschneider et al.

ADVANCED SUSTAINABLE SYSTEMS (2018)

Article Chemistry, Multidisciplinary

Mechanically controlled radical polymerization initiated by ultrasound

Hemakesh Mohapatra et al.

NATURE CHEMISTRY (2017)

Article Chemistry, Multidisciplinary

Mechanochemistry: A Force of Synthesis

Jean-Louis Do et al.

ACS CENTRAL SCIENCE (2017)

Article Chemistry, Multidisciplinary

Mechanochemical Suzuki polycondensation - from linear to hyperbranched polyphenylenes

S. Graetz et al.

GREEN CHEMISTRY (2017)

Article Polymer Science

Luminescent Sensing of Volatile Organic Compounds Using a Zn-based Coordination Polymer with Tunable Morphology

Rodrigo Chan-Navarro et al.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2017)

Article Chemistry, Organic

Altering Product Selectivity by Mechanochemistry

Jose G. Hernandez et al.

JOURNAL OF ORGANIC CHEMISTRY (2017)

Article Chemistry, Multidisciplinary

Constructing Ultraporous Covalent Organic Frameworks in Seconds via an Organic Terracotta Process

Suvendu Karak et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Polymer Science

50th Anniversary Perspective: Polymer Functionalization

Eva Blasco et al.

MACROMOLECULES (2017)

Review Multidisciplinary Sciences

The atom, the molecule, and the covalent organic framework

Christian S. Diercks et al.

SCIENCE (2017)

Article Polymer Science

Solid-State Synthesis of Conjugated Nanoporous Polycarbazoles

Xiang Zhu et al.

ACS MACRO LETTERS (2017)

Article Chemistry, Multidisciplinary

Feedback Kinetics in Mechanochemistry: The Importance of Cohesive States

Benjamin P. Hutchings et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Article Chemistry, Organic

Solid-state mechanochemical w-functionalization of poly(ethylene glycol)

Michael Y. Malca et al.

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY (2017)

Review Chemistry, Organic

Main group mechanochemistry

Agota A. Geciauskaite et al.

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY (2017)

Article Nanoscience & Nanotechnology

Mechanical Synthesis of COF Nanosheet Cluster and Its Mixed Matrix Membrane for Efficient CO2 Removal

Changchang Zou et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

Article Chemistry, Organic

Mechanochemical borylation of aryldiazonium salts; merging light and ball milling

Jose G. Hernandez

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY (2017)

Review Pharmacology & Pharmacy

Screening for new pharmaceutical solid forms using mechanochemistry: A practical guide

Dritan Hasa et al.

ADVANCED DRUG DELIVERY REVIEWS (2017)

Article Chemistry, Multidisciplinary

Mechanochemical synthesis of two-dimensional aromatic polyamides

Yang Yang et al.

CHEMICAL COMMUNICATIONS (2017)

Article Chemistry, Multidisciplinary

Solvent-Free Mechanochemical Synthesis of Nitrogen-Doped Nanoporous Carbon for Electrochemical Energy Storage

Christina Schneidermann et al.

CHEMSUSCHEM (2017)

Review Chemistry, Multidisciplinary

Hypercrosslinked porous polymer materials: design, synthesis, and applications

Liangxiao Tan et al.

CHEMICAL SOCIETY REVIEWS (2017)

Article Chemistry, Multidisciplinary

Mechanochemical Friedel-Crafts Alkylation-A Sustainable Pathway Towards Porous Organic Polymers

Erik Troschke et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Review Chemistry, Physical

Experimental Polymer Mechanochemistry and its Interpretational Frameworks

Sergey Akbulatov et al.

CHEMPHYSCHEM (2017)

Article Chemistry, Multidisciplinary

Warming up for mechanosynthesis - temperature development in ball mills during synthesis

Hannes Kulla et al.

CHEMICAL COMMUNICATIONS (2017)

Article Nanoscience & Nanotechnology

Mechanoassisted Synthesis of Sulfonated Covalent Organic Frameworks with High Intrinsic Proton Conductivity

Yongwu Peng et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

Article Chemistry, Multidisciplinary

Recent Developments in Mechanochemical Materials Synthesis by Extrusion

Deborah E. Crawford et al.

ADVANCED MATERIALS (2016)

Article Chemistry, Multidisciplinary

Rational design and synthesis of a porous, task-specific polycarbazole for efficient CO2 capture

Tian Jin et al.

CHEMICAL COMMUNICATIONS (2016)

Article Chemistry, Multidisciplinary

Exploring the Effect of Temperature on a Mechanochemical Reaction by in Situ Synchrotron Powder X-ray Diffraction

Krunoslav Uzarevic et al.

CRYSTAL GROWTH & DESIGN (2016)

Article Chemistry, Inorganic & Nuclear

Advances in organometallic synthesis with mechanochemical methods

Nicholas R. Rightmire et al.

DALTON TRANSACTIONS (2016)

Article Chemistry, Multidisciplinary

Paving the way for methane hydrate formation on metal-organic frameworks (MOFs)

Mirian E. Casco et al.

CHEMICAL SCIENCE (2016)

Article Chemistry, Physical

Nitrogen-enriched, ordered mesoporous carbons for potential electrochemical energy storage

Jinhui Zhu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2016)

Article Chemistry, Physical

A mechanochemically synthesized covalent organic framework as a proton-conducting solid electrolyte

Digambar Balaji Shinde et al.

JOURNAL OF MATERIALS CHEMISTRY A (2016)

Review Nanoscience & Nanotechnology

Mesoporous materials for energy conversion and storage devices

Wei Li et al.

NATURE REVIEWS MATERIALS (2016)

Review Chemistry, Multidisciplinary

Polymer Mechanochemistry: From Destructive to Productive

Jun Li et al.

ACCOUNTS OF CHEMICAL RESEARCH (2015)

Article Chemistry, Multidisciplinary

Trapping Reactive Intermediates by Mechanochemistry: Elusive Aryl N-Thiocarbamoylbenzotriazoles as Bench-Stable Reagents

Vjekoslav Strukil et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

Cocrystal Formation through Mechanochemistry: from Neat and Liquid-Assisted Grinding to Polymer-Assisted Grinding

Dritan Hasa et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

Mechanochemical reactions studied by in situ Raman spectroscopy: base catalysis in liquid-assisted grinding

Martina Tireli et al.

CHEMICAL COMMUNICATIONS (2015)

Review Chemistry, Multidisciplinary

Porous polymer catalysts with hierarchical structures

Qi Sun et al.

CHEMICAL SOCIETY REVIEWS (2015)

Article Chemistry, Multidisciplinary

Charged Porous Polymers using a Solid CO Cross-Coupling Reaction

Pengfei Zhang et al.

CHEMISTRY-A EUROPEAN JOURNAL (2015)

Article Chemistry, Physical

One-Pot Solvent-Free Synthesis of Nitrogen and Magnesium Codoped Mesoporous Carbon Composites for CO2 Capture

Zhongzheng Zhang et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2015)

Article Chemistry, Multidisciplinary

Mechanochemical Ruthenium-Catalyzed Olefin Metathesis

Jean-Louis Do et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Review Biochemistry & Molecular Biology

Green Chemistry Metrics with Special Reference to Green Analytical Chemistry

Marek Tobiszewski et al.

MOLECULES (2015)

Article Instruments & Instrumentation

Fabrication of novel cryomill for synthesis of high purity metallic nanoparticles

Nirmal Kumar et al.

REVIEW OF SCIENTIFIC INSTRUMENTS (2015)

Article Multidisciplinary Sciences

In situ X-ray diffraction monitoring of a mechanochemical reaction reveals a unique topology metal-organic framework

Athanassios D. Katsenis et al.

NATURE COMMUNICATIONS (2015)

Article Multidisciplinary Sciences

Porous coordination polymers with ubiquitous and biocompatible metals and a neutral bridging ligand

Shin-ichiro Noro et al.

NATURE COMMUNICATIONS (2015)

Article Chemistry, Physical

Advancing polymers of intrinsic microporosity by mechanochemistry

Pengfei Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2015)

Article Chemistry, Multidisciplinary

Direct In Situ Investigation of Milling Reactions Using Combined X-ray Diffraction and Raman Spectroscopy

Lisa Batzdorf et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

Laboratory Real-Time and In Situ Monitoring of Mechanochemical Milling Reactions by Raman Spectroscopy

Davor Gracin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Article Chemistry, Multidisciplinary

Application and Comparison of Cocrystallization Techniques on Trospium Chloride Cocrystals

Veronika Sladkova et al.

CRYSTAL GROWTH & DESIGN (2014)

Article Chemistry, Multidisciplinary

Mechanochemical Synthesis of Amide Functionalized Porous Organic Polymers

Lalit Rajput et al.

CRYSTAL GROWTH & DESIGN (2014)

Article Chemistry, Multidisciplinary

Mechanochemical synthesis and characterisation of two new bismuth metal organic frameworks

L. Troebs et al.

CRYSTENGCOMM (2014)

Article Polymer Science

Mechanochemical Synthesis of Poly(phenylene vinylenes)

Jens B. Ravnsbaek et al.

ACS MACRO LETTERS (2014)

Article Chemistry, Multidisciplinary

Real-Time In Situ Powder X-ray Diffraction Monitoring of Mechanochemical Synthesis of Pharmaceutical Cocrystals

Ivan Halasz et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

Article Chemistry, Multidisciplinary

Solvent-assisted mechanochemistry

Graham A. Bowmaker

CHEMICAL COMMUNICATIONS (2013)

Review Chemistry, Multidisciplinary

Mechanochemical organic synthesis

Guan-Wu Wang

CHEMICAL SOCIETY REVIEWS (2013)

Editorial Material Chemistry, Multidisciplinary

Mechanochemistry

Stuart L. James et al.

CHEMICAL SOCIETY REVIEWS (2013)

Review Chemistry, Multidisciplinary

Polymer mechanochemistry: techniques to generate molecular force via elongational flows

Preston A. May et al.

CHEMICAL SOCIETY REVIEWS (2013)

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The historical development of mechanochemistry

Laszlo Takacs

CHEMICAL SOCIETY REVIEWS (2013)

Review Chemistry, Multidisciplinary

Process engineering with planetary ball mills

Christine Friederike Burmeister et al.

CHEMICAL SOCIETY REVIEWS (2013)

Review Chemistry, Multidisciplinary

Mechanochemistry of inorganic and organic systems: what is similar, what is different?

Elena Boldyreva

CHEMICAL SOCIETY REVIEWS (2013)

Article Materials Science, Textiles

Solid-state Polymerization of EDOT Derivatives Containing Acenaphthenequinoxaline Ring

Xirali Mamtimin et al.

FIBERS AND POLYMERS (2013)

Article Chemistry, Multidisciplinary

Chemically Stable Multilayered Covalent Organic Nanosheets from Covalent Organic Frameworks via Mechanical Delamination

Suman Chandra et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Multidisciplinary

Mechanochemical Synthesis of Chemically Stable Isoreticular Covalent Organic Frameworks

Bishnu P. Biswal et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Polymer Science

Green Polymer Chemistry and Bio-based Plastics: Dreams and Reality

Rolf Muelhaupt

MACROMOLECULAR CHEMISTRY AND PHYSICS (2013)

Article Chemistry, Multidisciplinary

Real-time and in situ monitoring of mechanochemical milling reactions

Tomislav Friscic et al.

NATURE CHEMISTRY (2013)

Review Chemistry, Multidisciplinary

Nanoarchitectonics for Mesoporous Materials

Katsuhiko Ariga et al.

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN (2012)

Article Chemistry, Multidisciplinary

Poly(ethylene glycol) as reaction medium for mild Mizoroki-Heck reaction in a ball-mill

Valerie Declerck et al.

CHEMICAL COMMUNICATIONS (2012)

Review Chemistry, Multidisciplinary

Mechanochemistry: opportunities for new and cleaner synthesis

Stuart L. James et al.

CHEMICAL SOCIETY REVIEWS (2012)

Article Chemistry, Multidisciplinary

A Superacid-Catalyzed Synthesis of Porous Membranes Based on Triazine Frameworks for CO2 Separation

Xiang Zhu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Article Chemistry, Multidisciplinary

Microporous Polycarbazole with High Specific Surface Area for Gas Storage and Separation

Qi Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Review Chemistry, Multidisciplinary

Ball milling in organic synthesis: solutions and challenges

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