期刊
CHEMICAL SOCIETY REVIEWS
卷 51, 期 7, 页码 2873-2905出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cs01093j
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资金
- Federal Ministry of Education and Research (Bundesministerium fur Bildung und Forschung, BMBF) [03SF0498]
- European Research Council (ERC) under the European Union [948521]
- Deutsche Forschungsgemeinschaft [469290370]
- Samsung Research Funding & Incubation Center of Samsung Electronics [SRFC-MA1902-05]
- European Research Council (ERC) [948521] Funding Source: European Research Council (ERC)
Mechanochemistry, as a tool for polymer synthesis, utilizes mechanical forces to induce chemical reactions, offering advantages such as reduced solvent consumption and the accessibility of novel structures. This review focuses on the constructive mechanochemical synthesis of linear and porous polymers, as well as post-polymerization modifications.
Mechanochemistry - the utilization of mechanical forces to induce chemical reactions - is a rarely considered tool for polymer synthesis. It offers numerous advantages such as reduced solvent consumption, accessibility of novel structures, and the avoidance of problems posed by low monomer solubility and fast precipitation. Consequently, the development of new high-performance materials based on mechanochemically synthesised polymers has drawn much interest, particularly from the perspective of green chemistry. This review covers the constructive mechanochemical synthesis of polymers, starting from early examples and progressing to the current state of the art while emphasising linear and porous polymers as well as post-polymerisation modifications.
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