4.6 Article

A reduced electrophilicity for simple Lewis acids A involved in non-covalent interactions with Lewis bases B

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Summary: The strength of non-covalent interactions between copper, silver, gold, and simple Lewis bases has been systematically studied, revealing unique relationships between the equilibrium geometry, dissociation energy, and stretching force constant. While the relationship between D-e and k(sigma) may not be proportional, a general expression involving nucleophilicities and electrophilicities has been determined. The electrophilicity order among the studied Lewis acids has been established and a reduced electrophilicity parameter has been introduced for further analysis.

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