期刊
CHEMICAL COMMUNICATIONS
卷 58, 期 25, 页码 4028-4031出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc00925k
关键词
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资金
- Defense Threat Reduction Agency [HDTRA1-19-1-0007]
- National Science Foundation (NSF) DMREF/GOALI [2119433]
- Soft and Hybrid Nanotechnology Experimental (SHyNE) Resource [NSF ECCS-1542205]
- State of Illinois
- MRSEC program at the Materials Research Center [NSF DMR-1720139]
- IIN
- Keck Foundation
- State of Illinois, through the IIN
- Ryan Fellowship
- IIN y at Northwestern University
- NSF Graduate Research Fellowship [DGE-1842165]
- Department of Defense (DoD) through the National Defense Science & Engineering Graduate (NDSEG) Fellowship Program
- Div Of Chem, Bioeng, Env, & Transp Sys
- Directorate For Engineering [2119433] Funding Source: National Science Foundation
This article presents a method of replacing carboxylate linkers with triazolate coordination in MOF-74 via solvent-assisted linker exchange, resulting in the synthesis of the novel NU-250.
Metal-organic frameworks (MOFs) containing open metal sites are advantageous for wide applications. Here, carboxylate linkers are replaced with triazolate coordination in pre-formed Zn-MOF-74 via solvent-assisted linker exchange (SALE) to prepare the novel NU-250, within the known hexagonal channel-based MAF-X25 series that has not previously been synthesized de novo.
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