期刊
CHEMICAL COMMUNICATIONS
卷 58, 期 25, 页码 4091-4094出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc00377e
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The low temperature regioselective hydrosilylation of various alkenes with Mn-2(CO)(10) under UV irradiation is achieved with Mn loadings as low as 1 mol%, in the absence of additives and with excellent selectivity and yields. The generation of a manganese radical allows the anti-Markovnikov hydrosilylation products to be selectively obtained in yields up to 99%.
The low temperature regioselective hydrosilylation of various alkenes with (1,1,1,3,5,5,5-heptamethyltrisiloxane) (MDM)-M-H is described using Mn-2(CO)(10) under UV irradiation with Mn loadings as low as 1 mol%, in the absence of additives and with excellent selectivity and yields. The generation of a manganese radical allowed the anti-Markovnikov hydrosilylation products to be selectively obtained in yields up to 99%.
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