期刊
DALTON TRANSACTIONS
卷 51, 期 13, 页码 5203-5207出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt00288d
关键词
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资金
- Fundamental Research Fund of Xi'an Jiaotong University [xxj032019005]
- China Postdoctoral Science Foundation [2020M673370]
- National Natural Science Foundation of China [22001202]
- State Key Laboratory of Structural Chemistry open fund [20200032]
Designs and developments of proton conductors are highly important in chemistry and energy fields. In this study, a novel metal-organic framework H(2)DAB-MgNi(ox)(3) was synthesized and showed enhanced proton conductivity by Mg substitution.
Designs and developments of proton conductors are highly important in chemistry and energy fields. In this study, a novel metal-organic framework H(2)DAB-MgNi(ox)(3) was synthesized. X-ray powder diffraction, scanning transmission electron microscopy, and scanning transmission electron microscopy-energy-dispersive X-ray mapping measurements demonstrated that the H(2)DAB-MgNi(ox)(3) had a solid-solution structure, with the homogeneous distribution of Mg and Ni elements. The proton conductivity of H(2)DAB-MgNi(ox)(3) was enhanced from that of H(2)DAB-Ni-2(ox)(3) at 95% relative humidity by Mg substitution.
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