期刊
DALTON TRANSACTIONS
卷 51, 期 13, 页码 5034-5040出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt00453d
关键词
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资金
- KAKENHI (JSPS) [21K14604]
- Nanotechnology Platform of MEXT, Japan
- Grants-in-Aid for Scientific Research [21K14604] Funding Source: KAKEN
A novel hydrogen-bonded metal-organic framework was prepared and showed asymmetric thermal hysteresis behavior with a 4-fold interpenetrating diamond framework.
A novel hydrogen-bonded metal-organic framework (H-MOF) [Co(HL)(2)](DMF)(1.2)(H2O)(2.4)(1.solv), in which L = 2,2':6',2 ''-terpyridine-5,5 ''-diyl biscarboxylate, was prepared. An intermolecular single H-bond between carboxy and carboxylate sites was present in this compound. The crystal structure of 1.soly showed a 4-fold interpenetrating H-bonded diamond framework. After the desorption of the crystal solvents, 1.desoly exhibited normal and reverse spin-crossover (SCO) behaviours, providing an asymmetric thermal hysteresis loop.
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