4.7 Article

Amorphous palladium-based alloy nanoparticles as highly active electrocatalysts for ethanol oxidation

期刊

CHEMICAL COMMUNICATIONS
卷 58, 期 28, 页码 4488-4491

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc00956k

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资金

  1. National Natural Science Foundation of China [21971008, 22101016]
  2. Beijing Natural Science Foundation [Z210016]
  3. Fundamental Research Funds for the Central Universities [buctrc201916, buctrc201823]

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Amorphous Pd-P metal-metalloid alloy nanoparticles exhibit higher electrochemical performance in ethanol oxidation reaction compared to crystalline Pd nanoparticles, thanks to abundant defective coordination unsaturated sites and P alloying, which enhance the adsorption of OH.
Amorphous Pd-P metal-metalloid alloy nanoparticles showed a higher electrochemical ethanol oxidation reaction performance than crystalline Pd nanoparticles. The high performance was attributed to the rich defective coordination unsaturated sites and the P alloying, which enhanced the OH adsorption.

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