Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes

Review Chemistry, Multidisciplinary

Rare Earth Starting Materials and Methodologies for Synthetic Chemistry

Fabrizio Ortu

Summary: This review provides an overview of the important starting materials and ligands used in rare earth synthetic chemistry, covering their preparations and applications in modern synthetic methodologies.

CHEMICAL REVIEWS (2022)

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Article Chemistry, Multidisciplinary

Bis-Cyclooctatetraenyl Thulium(II): Highly Reducing Lanthanide Sandwich Single-Molecule Magnets

Jules Moutet et al.

Summary: Divalent lanthanide organometallics are highly reducing compounds known for single electron transfer reactivity and small molecule activation. This study presents a rare organometallic sandwich compound of divalent thulium with the cyclooctatetraenyl ligand, introducing it as an additional strategy for designing high-performing Single Molecule Magnets. The first divalent thulium sandwich complex with f(13) configuration behaves as a single-molecule magnet even in the absence of a DC field.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Tuning the Regioselective Functionalization of Trifluoromethylated Dienes via Lanthanum-Mediated Single C-F Bond Activation

Tarun Kumar et al.

Summary: A highly selective method was developed in this study for the regio- and stereoselective addition of a variety of aldehydes onto trifluoromethylated benzofulvenes. The resulting products have potential for further applications and can be transformed into benzofulvenes carrying a difluorovinyl group.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

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Article Chemistry, Multidisciplinary

Diphosphanylmetallocenes of Main-Group Elements

Carsten Mueller et al.

Summary: The transmetalation of magnesocenes can be used to synthesize metalocenes from different groups, showing novel coordination chemistry properties.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

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Article Chemistry, Inorganic & Nuclear

Accessing Mononuclear Triphenylcyclopentadienyl Lanthanide Complexes by Using Tridentate Nitrogen Ligands: Synthesis, Structure, Luminescence, and Catalysis

Daniil A. Bardonov et al.

Summary: A series of novel mononuclear compounds have been synthesized and studied, showing luminescent properties in the near-infrared and visible regions, with complex 4 exhibiting a total quantum yield of 50%. Additionally, these compounds have been utilized in the polymerization of ethylene.

ORGANOMETALLICS (2021)

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Review Chemistry, Inorganic & Nuclear

Lanthanides and actinides: Annual survey of their organometallic chemistry covering the year 2019

Joy H. Farnaby et al.

Summary: This review summarizes the progress in organo-f-element chemistry in 2019, focusing on the discovery of new types of complexes, diverse reactivities of lanthanide metals, and reports on novel catalytic reactions. Advancements in hydrocarbyl complexes of the actinides are also highlighted.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Chemistry, Multidisciplinary

Scandium and lanthanum hydride complexes stabilized by super-bulky penta-arylcyclopentadienyl ligands

Yang Wang et al.

Summary: In this study, hydrogenolysis reactions were used to synthesize two different bimetallic complexes, and DFT calculations were conducted to elucidate the reaction profiles.

CHEMICAL COMMUNICATIONS (2021)

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Review Chemistry, Multidisciplinary

Alkyl complexes of divalent lanthanides and heavy alkaline earth metals

D. O. Khristolyubov et al.

Summary: The review discusses the synthesis, structure, reactivity, and catalytic activity of alkyl derivatives of rare earth metals in the +2 oxidation state (Sm, Eu, Yb) and their analogues containing heavy alkaline earth metals (Ca, Sr, Ba), highlighting the unique features of these compounds with highly reactive M7C bonds. The bibliography includes 157 references.

RUSSIAN CHEMICAL REVIEWS (2021)

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Article Chemistry, Inorganic & Nuclear

Direct Synthesis of Pentaarylcyclopentadienyl Sandwich and Half-Sandwich Complexes of s-, p-, and d-Block Metals

Yannick Schulte et al.

ORGANOMETALLICS (2020)

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Article Chemistry, Inorganic & Nuclear

C-P vs C-H Bond Cleavage of Triphenylphosphine at Platinum(0): Mechanism of Formation, Reactivity, Redox Chemistry, and NMR Chemical Shift Calculations of a μ-Phosphanido Diplatinum(II) Platform

Andreas Berkefeld et al.

ORGANOMETALLICS (2020)

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Article Chemistry, Inorganic & Nuclear

Ready Approach to Organophosphines from ArCl via Selective Cleavage of C-P Bonds by Sodium

Jingjing Ye et al.

ORGANOMETALLICS (2020)

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Article Chemistry, Multidisciplinary

Highly fluorescent aryl-cyclopentadienyl ligands and their tetra-nuclear mixed metallic potassium-dysprosium clusters

Selvakumar Arumugam et al.

RSC ADVANCES (2020)

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Article Chemistry, Inorganic & Nuclear

Cu-Catalyzed P-C bond formation/cleavage: straightforward synthesis/ring-expansion of strained cyclic phosphoniums

Maryne Duval et al.

DALTON TRANSACTIONS (2020)

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Article Chemistry, Multidisciplinary

Conversion of triphenylphosphine oxide to organophosphorus via selective cleavage of C-P, O-P, and C-H bonds with sodium

Jian-Qiu Zhang et al.

COMMUNICATIONS CHEMISTRY (2020)

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Article Chemistry, Inorganic & Nuclear

Synthesis and Structures of s- and p-Block Metal Complexes Containing Sterically Demanding Pentaarylcyclopentadienyl Substituents

Yannick Schulte et al.

ORGANOMETALLICS (2019)

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Article Chemistry, Inorganic & Nuclear

Synthesis of a Ga-Stabilized As-Centered Radical and a Gallastibene by Tailoring Group 15 Element-Carbon Bond Strengths

Christoph Helling et al.

INORGANIC CHEMISTRY (2019)

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Article Chemistry, Inorganic & Nuclear

Aryloxy Alkyl Magnesium versus Dialkyl Magnesium in the Lanthanidocene-Catalyzed Coordinative Chain Transfer Polymerization of Ethylene

Mikhail E. Minyaev et al.

ORGANOMETALLICS (2019)

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Article Chemistry, Multidisciplinary

Synthesis and Magnetism of Neutral, Linear Metallocene Complexes of Terbium(II) and Dysprosium(II)

Colin A. Gould et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Review Chemistry, Multidisciplinary

Synthetic Applications of Transition-Metal-Catalyzed C-P Bond Cleavage

Lili Wang et al.

CHEMISTRY-AN ASIAN JOURNAL (2018)

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Article Chemistry, Inorganic & Nuclear

Deca-Arylsamarocene: An Unusually Inert Sm(II) Sandwich Complex

Niels J. C. van Velzen et al.

ORGANOMETALLICS (2018)

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Article Chemistry, Multidisciplinary

Lanthanidocenes: Synthesis, Structure, and Bonding of Linear Sandwich Complexes of Lanthanides

Mathieu Xemard et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Article Chemistry, Inorganic & Nuclear

Different Reductive Reactivities of SmCp2x(THF)n (Cpx = C5Me5 and C5H3tBu2) Samarocenes toward P2Ph4: THF Ring-Opening and Ligand-Exchange Pathways

Nikolay A. Pushkarevsky et al.

ORGANOMETALLICS (2017)

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Article Chemistry, Multidisciplinary

A designer ligand field for blue-green luminescence of organoeuropium(II) sandwich complexes with cyclononatetraenyl ligands

Kenshiro Kawasaki et al.

CHEMICAL COMMUNICATIONS (2017)

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Article Chemistry, Organic

α-Regioselective Barbier Reaction of Carbonyl Compounds and Allyl Halides Mediated by Praseodymium

San Wu et al.

JOURNAL OF ORGANIC CHEMISTRY (2016)

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Article Chemistry, Inorganic & Nuclear

Divalent Tetra- and Penta-phenylcyclopentadienyl Europium and Samarium Sandwich and Half-Sandwich Complexes: Synthesis, Characterization, and Remarkable Luminescence Properties

Rory P. Kelly et al.

ORGANOMETALLICS (2015)

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Article Chemistry, Inorganic & Nuclear

Base-Free Lanthanoidocenes(II) Coordinated by Bulky Pentabenzylcyclopentadienyl Ligands

Alexander N. Selikhov et al.

ORGANOMETALLICS (2015)

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Article Instruments & Instrumentation

MX1: a bending-magnet crystallography beamline serving both chemical and macromolecular crystallography communities at the Australian Synchrotron

Nathan Philip Cowieson et al.

JOURNAL OF SYNCHROTRON RADIATION (2015)

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Article Chemistry, Multidisciplinary

Physical Properties of Superbulky Lanthanide Metallocenes: Synthesis and Extraordinary Luminescence of [EuII(CpBIG)2] (CpBIG=(4-nBu-C6H4)5-Cyclopentadienyl)

Sjoerd Harder et al.

CHEMISTRY-A EUROPEAN JOURNAL (2013)

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Article Chemistry, Inorganic & Nuclear

Synthesis and characterisation of alkaline earth bis(diphenylphosphano)metallocene complexes and heterobimetallic alkaline earth metal/platinum(II) complexes [Ae(thf)x(η5-C5H4PPh2)2Pt(Me)2] (Ae = Ca, Sr, Ba)

Daisy P. Daniels et al.

DALTON TRANSACTIONS (2012)

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Article Chemistry, Inorganic & Nuclear

C-P or C-H Bond Cleavage of Phosphine Oxides Mediated by an Yttrium Hydride

Erli Lu et al.

ORGANOMETALLICS (2012)

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Review Chemistry, Inorganic & Nuclear

Penta-arylcyclopentadienyl complexes

Leslie D. Field et al.

COORDINATION CHEMISTRY REVIEWS (2011)

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Article Chemistry, Inorganic & Nuclear

Investigation of novel and reinvestigation of known cyclopentadienylphosphanes: News on [1,5] sigmatropic rearrangements

Crispin Lichtenberg et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2010)

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Article Chemistry, Multidisciplinary

Remarkable stability of metallocenes with superbulky ligands: Spontaneous reduction of Sm(III) to Sm(II)

Christian Ruspic et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

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Article Chemistry, Inorganic & Nuclear

Accessing decaphenylmetallocenes of ytterbium, calcium, and barium by desolvation of solvent-separated ion pairs: Overcoming adverse solubility properties

Glen B. Deacon et al.

ORGANOMETALLICS (2008)

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Article Chemistry, Multidisciplinary

Dinuclear alkynyllanthanoid(II) dications with pentaphenylcyclopentadienyl or tri-tert-butyldiphosphacyclopentadienyl counter ions

CM Forsyth et al.

CHEMICAL COMMUNICATIONS (2006)

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Article Chemistry, Inorganic & Nuclear

An improved synthesis of sodium and potassium cyclopentadienide

TK Panda et al.

ORGANOMETALLICS (2003)

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Review Chemistry, Multidisciplinary

Metal-mediated reductive hydrodehalogenation of organic halides

F Alonso et al.

CHEMICAL REVIEWS (2002)

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Article Chemistry, Organic

Reduction of organic halides with lanthanum metal: A novel generation method of alkyl radicals

T Nishino et al.

JOURNAL OF ORGANIC CHEMISTRY (2002)

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Article Chemistry, Organic

Three-component coupling of acylphosphonates and two carbonyl compounds promoted by low-valent samariums:: One-pot synthesis of β-hydroxyphosphonates

K Takaki et al.

JOURNAL OF ORGANIC CHEMISTRY (2000)

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Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes

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