期刊
CHEMICAL COMMUNICATIONS
卷 58, 期 28, 页码 4532-4535出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc01018f
关键词
-
资金
- Fundacion Seneca [19890/GERM/15]
- Ministerio de Ciencia, Innovacion y Universidades [PGC2018-100719-B-I00]
- Universidad de Murcia
The first series of neutral, tris-chelate, phosphorescent Pt(IV) complexes, which combine specific ligands and react under mild conditions, were synthesized. The modulation of emission characteristics can be achieved by derivatization of the ligands.
The first series of neutral, tris-chelate, phosphorecent Pt(iv) complexes is reported, which combine two cyclometalated 2-arylpyridine ligands and a dimetalated biaryl. The introduction of biaryl ligands is achieved under mild conditions through the oxidative addition of dibenzoiodolium ions to Pt(ii) precursors to give Pt(iv) intermediates with a singly metalated 2-(2-iodoaryl)aryl ligand, followed by the reductive metalation of the C-I bond. The modulation of emission characteristics via derivatization of both types of ligands is demonstrated.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据