Design and NMR characterization of reversible head-to-tail boronate-linked macrocyclic nucleic acids

Review Chemistry, Multidisciplinary

Biomedical Applications of Calixarenes: State of the Art and Perspectives

Yu-Chen Pan et al.

Summary: Calixarenes and their derivatives, as versatile supramolecular hosts, have extensive biomedical applications in biosensing, bioimaging, and therapy, showing great potential as therapeutic agents.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Review Chemistry, Multidisciplinary

Cucurbituril-Based Biomacromolecular Assemblies

Yao-Hua Liu et al.

Summary: The use of cucurbiturils (CBs) in biomacromolecular assemblies has made significant progress in various applications, including biosensors, biochemical reaction regulation, and disease treatment. CBs have also shown the ability to promote subcellular bioimaging in different organelles, demonstrating diverse applications in the field of supramolecular chemistry.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Boronic Acid-Mediated Activity Control of Split 10-23 DNAzymes

Megane Debiais et al.

Summary: The 10-23 DNAzyme is a Mg2+-dependent catalytic oligonucleotide that can cleave RNA in a sequence-specific manner. In this study, new split 10-23 DNAzymes were designed using nonfunctional fragments that, when assembled with Mg2+ ions, form boronate internucleoside linkages to restore DNAzyme activity. The best-performing system was identified through systematic evaluation, highlighting key features for controlling DNAzyme activity via boronate linkages.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

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Article Chemistry, Organic

Synthesis, Structural, and Conformational Analysis of 4′-C-Alkyl-2′-O-Ethyl-Uridine Modified Nucleosides

Rahul R. Nikam et al.

Summary: The study presents a method for synthesizing dual modified nucleosides and an alternative route for specific nucleoside synthesis. X-ray structure analysis reveals the conformation of nucleosides, while computational studies shed light on the interactions between different conformational forms.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2021)

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Review Chemistry, Multidisciplinary

Design of Cyclodextrin-Based Functional Systems for Biomedical Applications

Wanjia Xu et al.

Summary: Cyclodextrins are oligosaccharides with a unique structure that can be used to design various functional materials, leading to a wide range of biomedical applications.

FRONTIERS IN CHEMISTRY (2021)

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Review Biochemistry & Molecular Biology

Modified internucleoside linkages for nuclease-resistant oligonucleotides

Guillaume Clave et al.

Summary: In recent years, researchers have made significant modifications to drugs derived from nucleic acids, including altering the internucleoside linkage, which can impact the properties and biological activities of nucleic acids. Ongoing studies continue to explore the potential applications of these modified nucleic acid derivatives.

RSC CHEMICAL BIOLOGY (2021)

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Article Chemistry, Multidisciplinary

Chemo-enzymatic access to C-4 '-hydroxyl-tetrahydrofurano-spironucleosides

Pallavi Rungta et al.

Summary: The study introduced spirocyclic restriction into nucleosides to achieve structural pre-organisation, leading to the synthesis of C-4 '-hydroxyl-tetrahydrofurano-spironucleosides. Assessing the selectivity of monoacylation in the sugar derivative revealed that different acyl chain lengths could increase reaction rate without affecting enzyme selectivity. The modification of a hydroxytetrahydrofuran ring in furano-nucleosides demonstrated the ability to generate C4'-exo, NE-conformational restriction in nucleosides.

NEW JOURNAL OF CHEMISTRY (2021)

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Review Chemistry, Organic

Supramolecular Catalysts Featuring Crown Ethers as Recognition Units

Stefano Di Stefano et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

Chiral Macrocycle-Enabled Counteranion Trapping for Boosting Highly Efficient and Enantioselective Catalysis

Rui Ning et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Chemistry, Multidisciplinary

Functional Supramolecular Polymeric Networks: The Marriage of Covalent Polymers and Macrocycle-Based Host-Guest Interactions

Danyu Xia et al.

CHEMICAL REVIEWS (2020)

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Review Chemistry, Multidisciplinary

Functionalized Macrocycles in Supramolecular Organocatalysis

Dana Kauerhof et al.

CHEMPLUSCHEM (2020)

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Review Chemistry, Inorganic & Nuclear

Tailoring pillararene-based receptors for specific metal ion binding: From recognition to supramolecular assembly

Yuyu Fang et al.

COORDINATION CHEMISTRY REVIEWS (2020)

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Review Chemistry, Multidisciplinary

Design, synthesis and applications of responsive macrocycles

Jingjing Yu et al.

COMMUNICATIONS CHEMISTRY (2020)

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Review Chemistry, Multidisciplinary

Pillararene-Based Supramolecular Functional Materials

Qi Li et al.

TRENDS IN CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

Controlled release of the guest molecule via borate formation of a fluorinated boronic ester cage

Hisatsugu Takata et al.

CHEMICAL COMMUNICATIONS (2020)

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Review Chemistry, Multidisciplinary

Applications of Pillar[n]arene-Based Supramolecular Assemblies

Tomoki Ogoshi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Review Chemistry, Multidisciplinary

Cucurbit[8]uril (CB[8])-Based Supramolecular Switches

Elena Pazos et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Review Chemistry, Multidisciplinary

Macrocycles as Ion Pair Receptors

Qing He et al.

CHEMICAL REVIEWS (2019)

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Review Chemistry, Multidisciplinary

Revisiting Fluorescent Calixarenes: From Molecular Sensors to Smart Materials

Rajesh Kumar et al.

CHEMICAL REVIEWS (2019)

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Review Chemistry, Multidisciplinary

The Hexameric Resorcinarene Capsule at Work: Supramolecular Catalysis in Confined Spaces

Carmine Gaeta et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

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Review Multidisciplinary Sciences

Chiral Heterocycle-Based Receptors for Enantioselective Recognition

Vaibhav N. Khose et al.

SYMMETRY-BASEL (2018)

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Review Chemistry, Multidisciplinary

Biochemical sensing with macrocyclic receptors

Roberta Pinalli et al.

CHEMICAL SOCIETY REVIEWS (2018)

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Article Chemistry, Organic

RNA- based boronate internucleosidic linkages: an entry into reversible templated ligation and loop formation

Alejandro Gimenez Molina et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2018)

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Review Chemistry, Organic

The Use of Resorcinarene Cavitands in Metal-Based Catalysis

Nallusamy Natarajan et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2017)

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Article Biochemistry & Molecular Biology

Synthesis of Disaccharide Nucleosides Utilizing the Temporary Protection of the 2′,3′-cis-Diol of Ribonucleosides by a Boronic Ester

Hidehisa Someya et al.

MOLECULES (2017)

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Article Chemistry, Physical

Discrete, Hexagonal Boronate Ester-Linked Macrocycles Related to Two-Dimensional Covalent Organic Frameworks

Anton D. Chavez et al.

CHEMISTRY OF MATERIALS (2016)

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Review Chemistry, Organic

The Dynamic Covalent Chemistry of Esters, Acetals and Orthoesters

Rene-Chris Brachvogel et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2016)

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Growth rates and water stability of 2D boronate ester covalent organic frameworks

Brian J. Smith et al.

CHEMICAL COMMUNICATIONS (2015)

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Review Chemistry, Physical

Self-healing polymer materials constructed by macrocycle-based host-guest interactions

Xianpeng Yang et al.

SOFT MATTER (2015)

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Article Chemistry, Multidisciplinary

pH-controlled DNA- and RNA-templated assembly of short oligomers

Renaud Barbeyron et al.

CHEMICAL SCIENCE (2015)

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Article Chemistry, Multidisciplinary

DNA-templated borononucleic acid self assembly: a study of minimal complexity

Renaud Barbeyron et al.

RSC ADVANCES (2015)

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Review Chemistry, Multidisciplinary

Rotaxane and Catenane Host Structures for Sensing Charged Guest Species

Matthew J. Langton et al.

ACCOUNTS OF CHEMICAL RESEARCH (2014)

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Review Chemistry, Multidisciplinary

Dynamic Covalent Chemistry Approaches Toward Macrocycles, Molecular Cages, and Polymers

Yinghua Jin et al.

ACCOUNTS OF CHEMICAL RESEARCH (2014)

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Review Chemistry, Multidisciplinary

Disulfide exchange: exposing supramolecular reactivity through dynamic covalent chemistry

Samuel P. Black et al.

CHEMICAL SOCIETY REVIEWS (2014)

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Review Chemistry, Multidisciplinary

Dynamic combinatorial/covalent chemistry: a tool to read, generate and modulate the bioactivity of compounds and compound mixtures

Andreas Herrmann

CHEMICAL SOCIETY REVIEWS (2014)

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Review Chemistry, Multidisciplinary

Recent advances in dynamic covalent chemistry

Yinghua Jin et al.

CHEMICAL SOCIETY REVIEWS (2013)

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Review Chemistry, Multidisciplinary

Metallocavitands: an emerging class of functional multimetallic host molecules

Peter D. Frischmann et al.

CHEMICAL SOCIETY REVIEWS (2013)

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Article Biochemistry & Molecular Biology

The Conformationally Constrained N-Methanocarba-dT Analogue Adopts an Unexpected C4′-exo Sugar Pucker in the Structure of a DNA Hairpin

Pradeep S. Pallan et al.

BIOCHEMISTRY (2012)

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Review Chemistry, Multidisciplinary

Supramolecular polymers constructed by crown ether-based molecular recognition

Bo Zheng et al.

CHEMICAL SOCIETY REVIEWS (2012)

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Article Chemistry, Organic

Cyclization of peptoids by formation of boronate esters

Sara Chirayil et al.

TETRAHEDRON LETTERS (2012)

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Article Chemistry, Multidisciplinary

Dynamic and Programmable DNA-Templated Boronic Ester Formation

Anthony R. Martin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

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Article Chemistry, Multidisciplinary

Boronic acid building blocks: tools for self assembly

Ryuhei Nishiyabu et al.

CHEMICAL COMMUNICATIONS (2011)

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Article Chemistry, Organic

Expanding the borononucleotide family: synthesis of borono-analogues of dCMP, dGMP and dAMP

Anthony R. Martin et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2009)

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Article Chemistry, Multidisciplinary

Multicomponent assembly of boronic acid based macrocycles and cages

Nicolas Christinat et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

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Article Chemistry, Multidisciplinary

Borononucleotides: synthesis, and formation of a new reversible boronate internucleosidic linkage

Delphine Luvino et al.

CHEMICAL COMMUNICATIONS (2008)

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Article Chemistry, Multidisciplinary

Boron-based rotaxanes by multicomponent self-assembly

Nicolas Christinat et al.

CHEMICAL COMMUNICATIONS (2008)

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Article Chemistry, Multidisciplinary

Boronic esters as a system for crystallization-induced dynamic self-assembly equipped with an on-off switch for equilibration

Nobuharu Iwasawa et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)

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Article Chemistry, Organic

A detailed examination of boronic acid-diol complexation

G Springsteen et al.

TETRAHEDRON (2002)

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Article Chemistry, Organic

Evidence for spontaneous, reversible paracyclophane formation. Aprotic solution structure of the boron neutron capture therapy drug, L-p-boronophenylalanine

BK Shull et al.

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 (2000)

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Design and NMR characterization of reversible head-to-tail boronate-linked macrocyclic nucleic acids

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