期刊
CHEMICAL COMMUNICATIONS
卷 58, 期 30, 页码 4731-4734出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc00404f
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资金
- National Natural Science Foundation of China [42022012, 22106023]
- Science and Technology Planning Project of Guangdong Province, China [2020B1212060055, 2020B1515020015, 2021A1515011378]
- GDAS' Project of Science and Technology Development [2020GDASYL-20200104018]
LaCoO3 perovskites with different spin states of Co3+ were prepared by calcination, and LaCoO3 with electron filling in the e(g) orbital exhibited the best catalytic activity due to a moderate interaction between the surface oxygen.
LaCoO3 perovskites with different spin states of Co3+ were prepared by calcination at 600-1000 degrees C. LaCoO3 with electron filling in the e(g) orbital at 1 exhibited a moderate interaction between the surface oxygen, resulting in the best catalytic activity. This was verified by the O p-band center.
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