期刊
CHEMICAL COMMUNICATIONS
卷 58, 期 35, 页码 5375-5378出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc00928e
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资金
- Spanish MINECO [PGC2018-098630-B-I00, PID2020-118329RB-I00]
- Aragon government [E31_20R PLATON]
- EU [862893 FATMOLS]
- DOE Office of Science User Facility [DEAC02-05CH11231]
This article presents a designed dimetallic Fe(ii) helicate made with biphenylene-bridged bispyrazolylpyridine ligands, which exhibits spin crossover at temperatures higher than ambient. It is also demonstrated that this helicate has the ability to encapsulate an S = 5/2 tris-oxalato Fe(iii) ion, leading to a significant reduction in the spin relaxation dynamics of the encapsulated guest.
A designed dimetallic Fe(ii) helicate made with biphenylene-bridged bispyrazolylpyridine ligands and exhibiting a process of spin crossover at temperatures above ambient is shown to encapsulate an S = 5/2 tris-oxalato Fe(iii) ion. The spin relaxation dynamics of this guest are strongly reduced upon encapsulation.
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