4.7 Article

Green synthesis of the battery material lithium sulfide via metathetic reactions

期刊

CHEMICAL COMMUNICATIONS
卷 58, 期 36, 页码 5498-5501

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc01077a

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资金

  1. National Key Research and Development Program of China [2018YFE0111600]
  2. Haihe Laboratory of Sustainable Chemical Transformations
  3. China Postdoctoral Science Foundation [BX20190231, 2019M661009]

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This study presents a synthesis method for lithium sulfide through spontaneous metathesis reactions between lithium salts and sodium sulfide. The method is cost-effective, scalable, and environmentally friendly, paving the way for practical solid-state lithium batteries based on SSEs.
We report a synthesis of lithium sulfide, the cost-determining material for making sulphide solid electrolytes (SSEs), via spontaneous metathesis reactions between lithium salts (halides and nitrate) and sodium sulfide. This innovative method is economical, scalable and green. It will pave the way to developing practical SSE-based solid-state lithium batteries.

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