期刊
CHEMICAL COMMUNICATIONS
卷 58, 期 36, 页码 5470-5473出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc00683a
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资金
- National Natural Science Foundation of China [21731002, 21975104, 22150004, 22071141]
- Guangdong Major Project of Basic and Applied Research [2019B030302009]
- Guangdong Basic and Applied Basic Research Foundation [2019A1515012162]
- Open Fund of Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications [2020A05]
In this study, we successfully synthesized high-nuclear regioisomeric core-shell metallofullerenes using heteroleptic ligands, and also demonstrated the formation of a polymeric ExMF structure.
The controlled synthesis of high-nuclear regioisomeric core-shell exohedral metallofullerenes (ExMFs) is challenging. Herein, we demonstrated the synthesis of regioisomeric core-shell cuprofullerene C-60@Cu-24(I) and its 3-D coordination polymer using heteroleptic ligands, realizing high-nuclear regioisomeric ExMFs and a polymeric ExMF structure.
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