期刊
CHEMICAL COMMUNICATIONS
卷 58, 期 36, 页码 5514-5517出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc00491g
关键词
-
资金
- SERB, India [CRG/2020/000780]
- IIT Madras
AgSbF6 has been established as an effective catalyst for the hydroboration of diverse isocyanates, yielding selective N-boryl formamides or N-boryl methylamines under different conditions. Additionally, this catalyst system selectively hydroborates various N-heterocycles, with pyridine derivatives preferentially undergoing 1,4 hydroboration and quinolines observed to undergo complete heterocycle hydrogenation to form tetrahydroquinoline (after hydrolysis).
AgSbF6 has been established as an effective catalyst for the hydroboration of structurally and electronically diverse isocyanates under ligand- and solvent-free conditions which selectively yielded either N-boryl formamides or N-boryl methylamines under different conditions. Further, various N-heterocycles can be selectively hydroborated using this simple catalytic system; pyridine derivatives undergo preferential 1,4 hydroboration whereas the formation of tetrahydroquinoline (after hydrolysis) via complete heterocycle hydrogenation was observed for quinolines.
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