☆ 4.6 Article

Electroreduction of NO3- on tubular porous Ti electrodes

CATALYSIS SCIENCE & TECHNOLOGY (2022)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Editorial Material Chemistry, Physical

Electrocatalytic Nitrate Reduction for Sustainable Ammonia Production

Phebe H. van Langevelde et al.

Summary: Phebe van Langevelde, Ioannis Katsounaros, and Marc Koper are renowned researchers in the field of electrocatalysis and renewable energy. Their research interests span from fundamental aspects of electrocatalysis to physical electrochemistry and theoretical electrochemistry. They have received various national and international awards for their contributions to the field.

JOULE (2021)

添加到收藏夹

Article Chemistry, Physical

Earth-abundant elements a sustainable solution for electrocatalytic reduction of nitrate

Ana S. Fajardo et al.

Summary: The study reveals that carbon (as boron-doped diamond) and tin have the highest average selectivity towards nitrogen gas evolution (55% and 64% respectively), outperforming platinum (Pt) which only has 1% selectivity, while having comparable energy efficiencies per order removal of nitrate. Therefore, earth-abundant elements for electrocatalysis show tremendous promise as innovative, low-cost, and sustainable processes for the water treatment marketplace.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

添加到收藏夹

Article Chemistry, Analytical

Electrochemical removal of nitrate from wastewater with a Ti cathode and Pt anode for high efficiency and N2 selectivity

Jiachao Yao et al.

Summary: In this study, electrochemical denitrification using a Ti cathode and Pt anode was investigated to enhance the removal efficiency of NO3- and the selectivity of NO3- to N2. Optimal conditions were determined for NO3- removal, achieving a high removal efficiency and selectivity under these conditions. Additionally, in situ FTIR spectroscopy and cyclic voltammetry were utilized to determine the reduction mechanism.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2021)

添加到收藏夹

Review Chemistry, Physical

On the assessment of electrocatalysts for nitrate reduction

Ioannis Katsounaros

Summary: To study the electrochemical reduction of nitrate, it is necessary to establish standardized testing protocols and pay attention to factors such as solution processes, product analysis, sensitivity to experimental parameters, electrolytic cell design, and pH changes caused by high current density.

CURRENT OPINION IN ELECTROCHEMISTRY (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Efficient Nitrogen Fixation to Ammonia through Integration of Plasma Oxidation with Electrocatalytic Reduction

Laiquan Li et al.

Summary: The process of converting N-2 to NH3 can be decoupled into a two-step process for efficient and selective ammonia production, utilizing air and water as low-cost raw materials. Surface boron-rich nickel boride electrocatalyst plays a key role in enhancing activity, selectivity, and stability, resulting in significant ammonia production with nearly 100% Faradaic efficiency.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Physical

Ammonia and Nitric Acid Demands for Fertilizer Use in 2050

Jeonghoon Lim et al.

Summary: Access to nitrogen-based fertilizers is crucial for maximizing agricultural yield, but the production process contributes significantly to carbon emissions. The market size and value of ammonia and nitric acid will be heavily influenced by the growing global population and food demand over the next three decades. Developing carbon-free technologies for nitrogen and nitrate reduction to meet fertilizer manufacturing demands is essential to address the environmental impact of current production methods.

ACS ENERGY LETTERS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Built-in Electric Field Triggered Interfacial Accumulation Effect for Efficient Nitrate Removal at Ultra-Low Concentration and Electroreduction to Ammonia

Wu-Ji Sun et al.

Summary: The built-in electric field in the electrocatalyst significantly accumulates NO3- ions and lowers the energy of reaction intermediates, leading to efficient nitrate removal and NH3 production. The CuCl (111) and rutile TiO2 (110) electrocatalyst shows the best performance among reported studies at 100 mg L-1 of nitrate concentration.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Reaction intermediate-mediated electrocatalyst synthesis favors specified facet and defect exposure for efficient nitrate-ammonia conversion

Qi Hu et al.

Summary: The study demonstrates that in alkaline media, the NH3 yield rate catalyzed by defective Cu(100) facets in NO3-RR is 2.3 times higher than that of the Haber-Bosch process. It is discovered that the intermediates of NO3-RR, N*, can serve as capping agents for controlling the exposed facets during the reduction.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Pd doping-weakened intermediate adsorption to promote electrocatalytic nitrate reduction on TiO2 nanoarrays for ammonia production and energy supply with zinc-nitrate batteries

Ying Guo et al.

Summary: This study presents a highly efficient Pd-doped TiO2 nanoarray electrode for ammonia production through nitrate electroreduction, achieving high yields and selectivity. By introducing Pd, the adsorption abilities of intermediates were weakened, leading to record-high NH3 yield, NH3 FE, and nitrate conversion.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

添加到收藏夹

Article Engineering, Environmental

Factors Impeding Replacement of Ion Exchange with (Electro)Catalytic Treatment for Nitrate Removal from Drinking Water

Charles J. Werth et al.

Summary: Nitrate is a widespread pollutant in groundwater and is currently removed at water treatment plants through ion exchange, which is effective but costly. (Electro)catalytic treatment, which reduces nitrate to dinitrogen gas or ammonium using a bimetal catalyst and atomic hydrogen, has emerged as a promising alternative. However, there are technical challenges limiting its widespread adoption, including precious metal amounts and cost, hydrogen efficiency and safety, and product selectivity.

ACS ES&T ENGINEERING (2021)

添加到收藏夹

Article Engineering, Environmental

Scalable Reactor Design for Electrocatalytic Nitrite Reduction with Minimal Mass Transfer Limitations

Chenxu Yan et al.

Summary: The PPTL flow reactor with potential control and custom-made cathode showed efficient nitrite removal with high current efficiency, but encountered issues such as ammonium production and significant current loss at more negative potentials. A reactive transport model was developed to simulate the kinetic data, indicating the reactor being more reaction limited than mass transfer limited. This parametrized model can be used to scale, operate, or modify the PPTL reactor for more efficient nitrite removal from larger flow streams.

ACS ES&T ENGINEERING (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Nitrate electroreduction: mechanism insight, in situ characterization, performance evaluation, and challenges

Yuting Wang et al.

Summary: Excessive nitrate ions in the environment pose a significant threat to human health by disrupting the natural nitrogen cycle. Nitrate electroreduction, utilizing green electrons as reductants, shows promise due to its ability to operate under ambient conditions. Understanding the nitrate reaction mechanism is crucial for designing efficient electrocatalysts for selective nitrate reduction.

CHEMICAL SOCIETY REVIEWS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Electrochemical oxidation of molecular nitrogen to nitric acid - towards a molecular level understanding of the challenges

Megha Anand et al.

Summary: This work discusses the possible reaction mechanisms of electrochemical N-2 oxidation (N2OR) and its competition with the parasitic oxygen evolution reaction (OER) at the molecular level. The author suggests design strategies for N-2 oxidation electro-catalysts by comparing the performance of two catalysts and establishes trends/scaling relations to correlate OER and N2OR activities. The challenges associated with electrochemical N2OR are highlighted.

CHEMICAL SCIENCE (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

From the Birkeland-Eyde process towards energy-efficient plasma-based NOX synthesis: a techno-economic analysis

Kevin H. R. Rouwenhorst et al.

Summary: Plasma-based NOX synthesis via the Birkeland-Eyde process was one of the early industrial nitrogen fixation methods, but it never dominated the field due to the invention of the Haber-Bosch process. However, recent interest in plasma technology for nitrogen fixation has resurged with the availability of low cost, renewable electricity. Energy consumption for NOX synthesis with plasma technology is currently competitive with the commercial process, but further optimization is needed to achieve full competitiveness through effective plasma-catalyst coupling.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

A single-site iron catalyst with preoccupied active centers that achieves selective ammonia electrosynthesis from nitrate

Panpan Li et al.

Summary: The necessity for sustainable ammonia production using economic and environment-friendly technologies is increasing globally. This study presents an iron-based single-atom catalyst with uniform atomic dispersion on carbon, which exhibits high NH3 yield rate and faradaic efficiency. The catalyst's high selectivity for NH3 is attributed to the unique electronic structures of the individual Fe sites.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

NOx production in a rotating gliding arc plasma: potential avenue for sustainable nitrogen fixation

Fatme Jardali et al.

Summary: A novel rotating gliding arc plasma was proposed for direct NOx production to yield high nitrogen content organic fertilizers without pollution associated with ammonia emission. Higher NOx concentrations were achieved in steady mode with the lowest energy consumption, attributed to combined thermal and vibrationally-promoted Zeldovich mechanisms.

GREEN CHEMISTRY (2021)

添加到收藏夹

Review Chemistry, Physical

Recent discoveries in the reaction mechanism of heterogeneous electrocatalytic nitrate reduction

Zixuan Wang et al.

Summary: This review paper discusses the fundamental mechanisms and methods of heterogeneous electrocatalytic nitrate reduction technology, exploring the nitrate reduction reaction mechanism and product selectivity, evaluating electrocatalyst performance, and factors influencing reactivity and selectivity. It emphasizes how mechanistic studies have advanced the understanding of NO3RR, and how targeted studies can lead to improved synergy between experimental and computational results, predictive mechanistic understanding, and discovery of new NO3RR electrocatalysts.

CATALYSIS SCIENCE & TECHNOLOGY (2021)

添加到收藏夹

Article Chemistry, Applied

Bimetallic Cu-based hollow fibre electrodes for CO2 electroreduction

Ivan Merino-Garcia et al.

CATALYSIS TODAY (2020)

添加到收藏夹

Article Chemistry, Physical

Mild and Selective Hydrogenation of Nitrate to Ammonia in the Absence of Noble Metals

Lin Wei et al.

ACS CATALYSIS (2020)

添加到收藏夹

Article Chemistry, Physical

Boosting Selective Nitrate Electroreduction to Ammonium by Constructing Oxygen Vacancies in TiO2

Ranran Jia et al.

ACS CATALYSIS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Direct Electrochemical Ammonia Synthesis from Nitric Oxide

Jun Long et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Electrochemical Oxidation of Nitrogen towards Direct Nitrate Production on Spinel Oxides

Chencheng Dai et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Review Chemistry, Multidisciplinary

Recent Advances and Challenges of Electrocatalytic N2 Reduction to Ammonia

Geletu Qing et al.

CHEMICAL REVIEWS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Electrolyte Engineering for Efficient Electrochemical Nitrate Reduction to Ammonia on a Titanium Electrode

Joshua M. McEnaney et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

添加到收藏夹

Editorial Material Energy & Fuels

Recycling fertilizer

Lauren F. Greenlee

NATURE ENERGY (2020)

添加到收藏夹

Article Energy & Fuels

Electrochemical reduction of nitrate to ammonia via direct eight-electron transfer using a copper-molecular solid catalyst

Gao-Feng Chen et al.

NATURE ENERGY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Towards Green Ammonia Synthesis through Plasma-Driven Nitrogen Oxidation and Catalytic Reduction

Lander Hollevoet et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Plasma-Based N2 Fixation into NOx: Insights from Modeling toward Optimum Yields and Energy Costs in a Gliding Arc Plasmatron

Elise Vervloessem et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

添加到收藏夹

Article Electrochemistry

Microtubular Gas Diffusion Electrode Based on Ruthenium-Carbon Nanotubes for Ambient Electrochemical Nitrogen Reduction to Ammonia

Xin Wei et al.

CHEMELECTROCHEM (2020)

添加到收藏夹

Article Chemistry, Physical

A nitrogen fixation strategy to synthesize NO via the thermally assisted photocatalytic conversion of air

Yu Yu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Preparation of Ti, Ti/TiC or Ti/TiN based hollow fibres with extremely low electrical resistivity

Ronald P. H. Jong et al.

RSC ADVANCES (2020)

添加到收藏夹

Article Multidisciplinary Sciences

A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements

Suzanne Z. Andersen et al.

NATURE (2019)

添加到收藏夹

Article Chemistry, Physical

Plasma-Activated Electrolysis for Cogeneration of Nitric Oxide and Hydrogen from Water and Nitrogen

Hrishikesh Patel et al.

ACS ENERGY LETTERS (2019)

添加到收藏夹

Article Energy & Fuels

Multi-site electrocatalysts for hydrogen evolution in neutral media by destabilization of water molecules

Cao-Thang Dinh et al.

NATURE ENERGY (2019)

添加到收藏夹

Review Chemistry, Physical

Electrocatalytic reduction of nitrate: Fundamentals to full-scale water treatment applications

Sergi Garcia-Segura et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

添加到收藏夹

Article Electrochemistry

Enabling real-time detection of electrochemical desorption phenomena with sub-monolayer sensitivity

Daniel B. Trimarco et al.

ELECTROCHIMICA ACTA (2018)

添加到收藏夹

Article Electrochemistry

Electrocatalytic reduction of Nitrate on Copper single crystals in acidic and alkaline solutions

Elena Perez-Gallent et al.

ELECTROCHIMICA ACTA (2017)

添加到收藏夹

Article Chemistry, Physical

Low temperature plasma-catalytic NOx synthesis in a packed DBD reactor: Effect of support materials and supported active metal oxides

B. S. Patil et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2016)

添加到收藏夹

Article Multidisciplinary Sciences

Three-dimensional porous hollow fibre copper electrodes for efficient and high-rate electrochemical carbon dioxide reduction

Recep Kas et al.

NATURE COMMUNICATIONS (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Cobalt-Embedded Nitrogen-Rich Carbon Nanotubes Efficiently Catalyze Hydrogen Evolution Reaction at All pH Values**

Xiaoxin Zou et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

添加到收藏夹

Article Environmental Sciences

Tracing nitrate pollution sources and transformation in surface- and ground-waters using environmental isotopes

Yan Zhang et al.

SCIENCE OF THE TOTAL ENVIRONMENT (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Powering denitrification: the perspectives of electrocatalytic nitrate reduction

Matteo Duca et al.

ENERGY & ENVIRONMENTAL SCIENCE (2012)

添加到收藏夹

Review Energy & Fuels

Catalysis for NOx abatement

Sounak Roy et al.

APPLIED ENERGY (2009)

添加到收藏夹

Review Chemistry, Multidisciplinary

Nitrogen Cycle Electrocatalysis

Victor Rosca et al.

CHEMICAL REVIEWS (2009)

添加到收藏夹

Article Chemistry, Physical

Activated Carbon Supported Metal Catalysts for Nitrate and Nitrite Reduction in Water

Olivia Salome G. P. Soares et al.

CATALYSIS LETTERS (2008)

添加到收藏夹

Article Electrochemistry

Kinetic study of nitrate reduction on Pt(110) electrode in perchloric acid solution

Satoshi Taguchi et al.

ELECTROCHIMICA ACTA (2008)

添加到收藏夹

Article Geosciences, Multidisciplinary

How a century of ammonia synthesis changed the world

Jan Willem Erisman et al.

NATURE GEOSCIENCE (2008)

添加到收藏夹

Article Engineering, Environmental

Electrochemical denitrificaton of simulated ground water

BP Dash et al.

WATER RESEARCH (2005)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.