期刊
ORGANIC CHEMISTRY FRONTIERS
卷 9, 期 10, 页码 2766-2772出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2qo00280a
关键词
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资金
- National Natural Science Foundation of China [21472141, 21571144]
- Zhejiang Provincial Natural Science Foundation of China [LY18B020011, LQ19B020004]
A carboxyl-assisted reaction method has been developed for the site- and enantio-selective additions of polyfunctional nucleophiles to imines and carbonyls. This method provides efficient access to delta-substituted-beta-keto esters and beta-substituted ketones with good yields and enantioselectivities. Additionally, short synthetic routes to bioactive molecules have been achieved.
Carboxyl-assisted site- and enantio-selective additions of polyfunctional nucleophiles to imines and carbonyls were developed, affording delta-substituted-beta-keto esters and beta-substituted ketones with good yields and enantioselectivities. Besides, short synthetic routes to bioactive molecules were also achieved.
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