A stable silylborane with diminished boron Lewis acidity

A new dimethyl(phenyl)silylborane having a naphthalene-1,8-diaminato (dan) substituent on the boron center, PhMe2Si-B(dan), was synthesized. Owing to the diminished boron Lewis acidity, it is highly stable toward air. Synthetic application of the silylborane to catalytic silylboration and silylation of alkynes is also described.

Automated summary

This article describes the synthesis of a new stable compound PhMe2Si-B(dan) and its application in catalytic silylboration and silylation reactions of alkynes.