Gram-scale synthesis of a covalent nanocage that preserves the redox properties of encapsulated fullerenes

Article Chemistry, Multidisciplinary

Synthesis, aromatization and cavitates of an oxanorbornene-fused dibenzo[de,qr]tetracene nanobox

Han Chen et al.

Summary: A new nanobox capable of binding C-70 in solution with high selectivity against C-60 and its derivatives has been reported in this study.

CHEMICAL SCIENCE (2022)

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Review Chemistry, Multidisciplinary

Large π-Extended and Curved Carbon Nanorings as Carbon Nanotube Segments

Jinyi Wang et al.

Summary: The article discusses the challenges of designing and synthesizing topologically unique molecules, focusing on curved aromatic molecules and their unique properties in electronics, optics, self-assembly, and charge transport. The potential applications of these molecules in various optoelectronic and biomedical materials are also highlighted.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

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Review Chemistry, Multidisciplinary

Gas-Phase Structural Analysis of Supramolecular Assemblies

Lukasz Polewski et al.

Summary: Ion mobility spectrometry and gas-phase IR action spectroscopy are two popular structure-sensitive mass-spectrometric methods for investigating supramolecular assemblies. These methods can distinguish isomers, reveal subtle structural details, and study amino acid complexes and peptide assemblies.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

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Article Chemistry, Multidisciplinary

Ion Mobility Mass Spectrometry Uncovers Guest-Induced Distortions in a Supramolecular Organometallic Metallosquare

Cristian Vicent et al.

Summary: The study investigated the encapsulation of tetracationic palladium metallosquare with four pyrene-bis-imidazolylidene ligands using ESI TWIM-MS and determined Collision Cross Sections (CCS). The host exhibited expansion when fullerenes or polycyclic aromatic hydrocarbons were encapsulated, with expansions ranging from 13 to 49 angstrom(2). DFT calculations were used to obtain energy-minimized structures of the complexes in the gas phase.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

A Self-Assembled Palladium(II) Barrel for Binding of Fullerenes and Photosensitization Ability of the Fullerene-Encapsulated Barrel

Prioti Choudhury Purba et al.

Summary: The study introduces a new Pd-6 barrel host for efficient encapsulation of fullerene extracts, addressing solubility and purification issues. The barrel exhibits strong binding affinity towards C-70 over C-60, resulting in predominant extraction of C-70 from a mixture. Fullerene-encapsulated barrels show efficient visible-light-induced singlet oxygen generation, with noteworthy preferential binding of C-70.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

A three-shell supramolecular complex enables the symmetry-mismatched chemo- and regioselective bis-functionalization of C60

Ernest Ubasart et al.

Summary: A three-shell matryoshka-like complex has been developed for selective functionalization of the C-60 inner shell to form a single trans-3 fullerene bis-adduct. This approach demonstrates potential for achieving selective synthesis of fullerene bis-adducts, which have been shown to exhibit superior properties.

NATURE CHEMISTRY (2021)

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Review Chemistry, Applied

Fullerenes for rechargeable battery applications: Recent developments and future perspectives

Zhipeng Jiang et al.

Summary: The development of high-performance batteries relies on exploring new materials, with Fullerene C-60 being one such material with unique properties beneficial for battery applications. Recent progress has been made in the field, but there are still key issues that need to be addressed in the future.

JOURNAL OF ENERGY CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Long-Lived C60 Radical Anion Stabilized Inside an Electron-Deficient Coordination Cage

Shota Hasegawa et al.

Summary: This study stabilizes the free C-60(center dot-) radical anion within a self-assembled coordination cage, showing that the confined C-60 molecule has a significantly extended lifetime which allows for further investigation and application.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Review Materials Science, Multidisciplinary

Emerging electronic applications of fullerene derivatives: an era beyond OPV

Jian Liu et al.

Summary: Fullerene derivatives have played a crucial role in the field of organic photovoltaics and shown potential in emerging research areas, requiring new design strategies and device engineering considerations for properties such as strong electron-donating ability and water permeability.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

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Article Chemistry, Multidisciplinary

3,6-Fluoren[5]arenes: synthesis, structure and complexation with fullerenes C60 and C70

Jia-Qi Wang et al.

Summary: A new class of macrocyclic arenes, 3,6-fluoren[5]arenes, were successfully synthesized in good yields and could form stable complexes with fullerenes C-60 and C-70 due to their symmetric pentagon structures with big and rich-electron cavities.

CHEMICAL COMMUNICATIONS (2021)

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Review Chemistry, Inorganic & Nuclear

Coordination-driven assemblies based on meso-substituted porphyrins: Metal-organic cages and a new type of meso-metallaporphyrin macrocycles

Edmundo G. Percastegui et al.

COORDINATION CHEMISTRY REVIEWS (2020)

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Article Chemistry, Multidisciplinary

Host-Guest-Induced Electron Transfer Triggers Radical-Cation Catalysis

Rebecca L. Spicer et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Multidisciplinary

The Green Box: An Electronically Versatile Perylene Diimide Macrocyclic Host for Fullerenes

Timothy A. Barendt et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Multidisciplinary

A Chichibabin's Hydrocarbon-Based Molecular Cage: The Impact of Structural Rigidity on Dynamics, Stability, and Electronic Properties

Yong Ni et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Inorganic & Nuclear

The Influence of Redox-Active Linkers on the Stability and Physical Properties of a Highly Electroactive Porphyrin Nanoprism

Kaitlyn G. Dutton et al.

INORGANIC CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

Self-Assembled Perylene Bisimide-Cored Trigonal Prism as an Electron-Deficient Host for C60 and C70 Driven by Like Dissolves Like

Xingmao Chang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Review Chemistry, Physical

Advances in supramolecular host-mediated reactivity

Mariko Morimoto et al.

NATURE CATALYSIS (2020)

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Article Chemistry, Multidisciplinary

A covalent organic cage compound acting as a supramolecular shadow mask for the regioselective functionalization of C60

Viktoria Leonhardt et al.

CHEMICAL SCIENCE (2020)

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Article Chemistry, Multidisciplinary

Reversible reduction drives anion ejection and C60 binding within an FeII4L6 cage

Zhenpin Lu et al.

CHEMICAL SCIENCE (2020)

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Article Chemistry, Multidisciplinary

Photoactive preorganized subphthalocyanine-based molecular tweezers for selective complexation of fullerenes

German Zango et al.

CHEMICAL SCIENCE (2020)

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Article Chemistry, Multidisciplinary

A Size-Flexible Organometallic Box for the Encapsulation of Fullerenes

Victor Martinez-Agramunt et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Review Chemistry, Multidisciplinary

Strategies for binding multiple guests in metal-organic cages

Felix J. Rizzuto et al.

NATURE REVIEWS CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

A Peanut-Shaped Polyaromatic Capsule: Solvent-Dependent Transformation and Electronic Properties of a Non-Contacted Fullerene Dimer

Kyosuke Matsumoto et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Review Chemistry, Inorganic & Nuclear

Supramolecular catalysis based on discrete heterometallic coordination-driven metallacycles and metallacages

Wen-Xi Gao et al.

COORDINATION CHEMISTRY REVIEWS (2019)

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Article Chemistry, Multidisciplinary

Pd(II) Coordination Sphere Engineering: Pyridine Cages, Quinoline Bowls, and Heteroleptic Pills Binding One or Two Fullerenes

Bin Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Multidisciplinary Sciences

Light triggered encapsulation and release of C60 with a photoswitchable TPE-based supramolecular tweezers

Mousumi Samanta et al.

SCIENTIFIC REPORTS (2019)

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Article Chemistry, Multidisciplinary

Selective Separation of Polyaromatic Hydrocarbons by Phase Transfer of Coordination Cages

Dawei Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Multidisciplinary

Highly Strained, Radially π-Conjugated Porphyrinylene Nanohoops

Youzhi Xu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Review Chemistry, Multidisciplinary

Ion mobility-mass spectrometry of supramolecular complexes and assemblies

Elina Kalenius et al.

NATURE REVIEWS CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

Size-selective encapsulation of C60 and C60-derivatives within an adaptable naphthalene-based tetragonal prismatic supramolecular nanocapsule

Cristina Garcia-Simon et al.

CHEMICAL COMMUNICATIONS (2019)

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Review Chemistry, Multidisciplinary

Strategies for Reversible Guest Uptake and Release from Metallosupramolecular Architectures

Tae Y. Kim et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

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Article Chemistry, Multidisciplinary

A Shape-Adaptable Organometallic Supramolecular Coordination Cage for the Encapsulation of Fullerenes

Victor Martinez-Agramunt et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

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Article Chemistry, Multidisciplinary

Specific and Oriented Encapsulation of Fullerene C-70 into a Supramolecular Double-Decker Cage Composed of Shape-Persistent Macrocycles

Shin-ichiro Kawano et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Article Chemistry, Multidisciplinary

Selective Extraction of C-70 by a Tetragonal Prismatic Porphyrin Cage

Yi Shi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Article Chemistry, Organic

Self-Assembled Carcerand-like Cage with a Thermoregulated Selective Binding Preference for Purification of High-Purity C-60 and C-70

Weidong Sun et al.

JOURNAL OF ORGANIC CHEMISTRY (2018)

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Article Chemistry, Multidisciplinary

Anion Exchange Drives Reversible Phase Transfer of Coordination Cages and Their Cargoes

Angela B. Grommet et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Article Chemistry, Multidisciplinary

Separation and Selective Formation of Fullerene Adducts within an MII8L6 Cage

Wolfgang Brenner et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Article Chemistry, Inorganic & Nuclear

Platinum(II)-Based Convex Trigonal-Prismatic Cages via Coordination-Driven Self-Assembly and C60 Encapsulation

Mingming Zhang et al.

INORGANIC CHEMISTRY (2017)

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Article Chemistry, Multidisciplinary

Multicomponent Platinum(II) Cages with Tunable Emission and Amino Acid Sensing

Mingming Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Article Chemistry, Multidisciplinary

Tuning the Redox Properties of Fullerene Clusters within a Metal-Organic Capsule

Felix J. Rizzuto et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Article Chemistry, Physical

The Functions of Fullerenes in Hybrid Perovskite Solar Cells

Yanjun Fang et al.

ACS ENERGY LETTERS (2017)

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Review Chemistry, Physical

Fullerene applications in fuel cells: A review

Julieta Coro et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2016)

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Article Chemistry, Multidisciplinary

Pathway-Dependent Post-assembly Modification of an Anthracene-Edged M4IIL6 Tetrahedron

Tanya K. Ronson et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

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Article Chemistry, Organic

C60 Recognition from Extended Tetrathiafulvalene Bis-acetylide Platinum(II) Complexes

Guillaume Bastien et al.

ORGANIC LETTERS (2016)

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Article Chemistry, Multidisciplinary

Guest-Induced Transformation of a Porphyrin-Edged (Fe4L6)-L-II Capsule into a (CuFe2L4)-Fe-I-L-II Fullerene Receptor

Daniel M. Wood et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

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Review Chemistry, Multidisciplinary

Diffusion NMR of molecular cages and capsules

Liat Avram et al.

CHEMICAL SOCIETY REVIEWS (2015)

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Article Chemistry, Multidisciplinary

Anisotropic Expansion of an M2L4 Coordination Capsule: Host Capability and Frame Rearrangement

Masahiro Yamashina et al.

CHEMISTRY-A EUROPEAN JOURNAL (2015)

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Article Chemistry, Multidisciplinary

Molecular recognition in curved π-systems: effects of π-lengthening of tubular molecules on thermodynamics and structures

Taisuke Matsuno et al.

CHEMICAL SCIENCE (2015)

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Article Chemistry, Multidisciplinary

Pyrene-Edged Fe4IIL6 Cages Adaptively Reconfigure During Guest Binding

Tanya K. Ronson et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

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Article Multidisciplinary Sciences

Sponge-like molecular cage for purification of fullerenes

Cristina Garcia-Simon et al.

NATURE COMMUNICATIONS (2014)

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Article Chemistry, Multidisciplinary

Giant Electroactive M4L6 Tetrahedral Host Self-Assembled with Fe(II) Vertices and Perylene Bisimide Dye Edges

Kingsuk Mahata et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

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Article Chemistry, Multidisciplinary

A C60-Templated Tetrameric Porphyrin Barrel Complex via Zinc-Mediated Self-Assembly Utilizing Labile Capping Ligands

Takashi Nakamura et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

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Article Chemistry, Multidisciplinary

Facile Catch and Release of Fullerenes Using a Photoresponsive Molecular Tube

Norifumi Kishi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

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Article Chemistry, Organic

Hemicarceplex Formation With a Cyclotriveratrylene-Based Molecular Cage Allows Isolation of High-Purity (≥99.0%) C70 Directly from Fullerene Extracts

Ming-Jhe Li et al.

ORGANIC LETTERS (2012)

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Review Chemistry, Multidisciplinary

Wraparound Hosts for Fullerenes: Tailored Macrocycles and Cages

David Canevet et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

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Article Chemistry, Multidisciplinary

A Self-Assembled M8L6 Cubic Cage that Selectively Encapsulates Large Aromatic Guests

Wenjing Meng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

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Article Chemistry, Multidisciplinary

Fullerene-templated synthesis of a cyclic porphyrin trimer using olefin metathesis

Amy R. Mulholland et al.

CHEMICAL COMMUNICATIONS (2011)

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Review Chemistry, Multidisciplinary

Supramolecular Coordination: Self-Assembly of Finite Two- and Three-Dimensional Ensembles

Rajesh Chakrabarty et al.

CHEMICAL REVIEWS (2011)

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Article Chemistry, Multidisciplinary

An M2L4 Molecular Capsule with an Anthracene Shell: Encapsulation of Large Guests up to 1 nm

Norifumi Kishi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

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Article Chemistry, Multidisciplinary

Macrocyclic Hosts for Fullerenes: Extreme Changes in Binding Abilities with Small Structural Variations

David Canevet et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

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Article Chemistry, Multidisciplinary

A Highly C70 Selective Shape-Persistent Rectangular Prism Constructed through One-Step Alkyne Metathesis

Chenxi Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

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Article Chemistry, Multidisciplinary

Ferromagnetic Spin Coupling between Endohedral Metallofullerene La@C82 and a Cyclodimeric Copper Porphyrin upon Inclusion

Fatin Hajjaj et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

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Article Chemistry, Multidisciplinary

Supramolecular Structures and Photoelectronic Properties of the Inclusion Complex of a Cyclic Free-Base Porphyrin Dimer and C-60

Hirofumi Nobukuni et al.

CHEMISTRY-A EUROPEAN JOURNAL (2010)

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Review Thermodynamics

Solubility of Light Fullerenes in Organic Solvents

Konstantin N. Semenov et al.

JOURNAL OF CHEMICAL AND ENGINEERING DATA (2010)

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Article Chemistry, Multidisciplinary

Coronene Nanophase within Coordination Spheres: Increased Solubility of C60

Kosuke Suzuki et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

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Article Chemistry, Multidisciplinary

A Porphyrin Nanobarrel That Encapsulates C60

Jianxin Song et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

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Article Chemistry, Organic

Structurally-variable, rigid and optically-active D-2 and D-3 macrocycles possessing recognition properties towards C-60

Carmine Coluccini et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2010)

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Article Chemistry, Organic

Supramolecular multicomponent self-assembly of shape-adaptive nanoprisms:: Wrapping up C60 with three porphyrin units

Michael Schmittel et al.

ORGANIC LETTERS (2008)

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Article Chemistry, Multidisciplinary

A double concave hydrocarbon buckycatcher

Andrzej Sygula et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2007)

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Article Chemistry, Multidisciplinary

Selective binding and easy separation C-70 by nanoscale self-assembled capsules

Elisa Huerta et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2007)

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Article Chemistry, Multidisciplinary

Supramolecular receptor design: Anion-triggered binding of C-60

Kent A. Nielsen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2006)

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Article Chemistry, Multidisciplinary

Inclusion of C-60 into an adjustable porphyrin dimer generated by dynamic disulfide chemistry

AL Kieran et al.

CHEMICAL COMMUNICATIONS (2005)

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Article Chemistry, Multidisciplinary

Complexation of carbon nanorings with fullerenes: Supramolecular dynamics and structural tuning for a fullerene sensor

T Kawase et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2003)

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Article Chemistry, Organic

Inclusion of [60]fullerene in a self-assembled homooxacalix[3]arene-based dimeric capsule constructed by a PdII-pyridine interaction.: The Li+-binding to the lower rims can improve the inclusion ability

A Ikeda et al.

TETRAHEDRON (2000)

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Review Chemistry, Multidisciplinary

Discrete fulleride anions and fullerenium cations

CA Reed et al.

CHEMICAL REVIEWS (2000)

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Gram-scale synthesis of a covalent nanocage that preserves the redox properties of encapsulated fullerenes

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