4.6 Article

Efficient conversion of furfural to cyclopentanol over lignin activated carbon supported Ni-Co catalyst

期刊

RSC ADVANCES
卷 12, 期 19, 页码 11843-11852

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ra00016d

关键词

-

资金

  1. [2019YFB1503804]
  2. [CAFYBB2018SZ011]
  3. [BRA2019293]

向作者/读者索取更多资源

In this study, Ni3Co1/ELAC catalyst was used to selectively convert furfural to cyclopentanol. The reaction mechanism was deduced and confirmed through experimental results and characterization techniques. The importance of aqueous solution in the reaction was also demonstrated.
Ni3Co1/ELAC catalyst, prepared by the enzymatically hydrolyzed lignin activated carbon as a carrier and a 3 : 1 ratio content of nickel and cobalt, can selectively convert furfural to cyclopentanol (CPL) in aqueous solution. We used activated carbon prepared by the phosphoric acid method as the carrier, and investigated the effect of the carrier on the catalyst activity. The ratio of bimetal (Ni, Co) content and reaction conditions (reaction temperature, reaction time, initial H-2 pressure) have also been investigated in the furfural hydrogenation. With the optimal Ni3Co1/ELAC catalyst, the conversion rate of furfural and the selectivity of CPL were 100% and 94.1%, respectively. In this process, some important catalysts were studied by XRD, XPS, ICP-AES, BET and TEM characterization. Through experimental results and other people's research, we deduced a reasonable reaction path and verified it by replacing the reaction substrate and solvents. Finally, the experiment proved that the formation of CPL by furfural required the occurrence of a rearrangement reaction and the participation of aqueous solution.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据