4.7 Review

A review on oil/water emulsion separation membrane material

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Article Engineering, Environmental

Facile fabrication of TaON/Bi2MoO6 core-shell S-scheme heterojunction nanofibers for boosting visible-light catalytic levofloxacin degradation and Cr(VI) reduction

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Summary: The study developed a novel TaON/Bi2MoO6 S-scheme heterojunction photocatalyst with a core-shell fiber-shaped structure, demonstrating high catalytic activity towards levofloxacin antibiotic degradation and Cr(VI) reduction. The material showed excellent stability and reusability, and a possible photocatalytic reaction mechanism for removal of LEV and Cr(VI) was proposed, providing insights for fabricating efficient water purification photocatalysts.

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Article Engineering, Chemical

A novel monolithic mullite microfiltration membrane for oil-in-water emulsion separation

Mohammed Rashad et al.

Summary: Monolithic ceramic microfiltration membranes made of mullite crystals show excellent properties for oil-in-water emulsion separation, with high permeate flux and oil rejection rate. Compared to conventional asymmetric ceramic membranes, the fabrication of monolithic mullite membranes is more cost-effective and can be a viable alternative for oil-in-water emulsion separation.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Chemical

Poly (vinyl alcohol) modification of poly(vinylidene fluoride) microfiltration membranes for oil/water emulsion separation via an unconventional radiation method

Yu Gu et al.

Summary: This study developed a non-traditional but simple method to modify the surface of polymer membranes, providing good hydrophilicity and underwater superoleophobicity, with excellent separation performance for various oil-in-water emulsions and oil rejection up to 99.5%.

JOURNAL OF MEMBRANE SCIENCE (2021)

Review Nanoscience & Nanotechnology

Advanced Materials with Special Wettability toward Intelligent Oily Wastewater Remediation

Weiwei Zheng et al.

Summary: The importance of clean water resources and the urgency to solve oil-polluted water problems are highlighted in this review. Advanced materials with special wettability are being used for efficient oil/water separation, offering intelligent functions like self-healing and photocatalysis for water treatment. The challenges and outlook for oil/water separation based on special wettability materials are also discussed in the article.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Polymer Science

A solvent-resistance OTS/PDA/O-PASS composite membrane for water-in-oil emulsions separation

Faming Yang et al.

Summary: Water-in-oil emulsions separation is crucial for industrial wastewater treatment, and membrane technology with oxidized polyarylene sulfide sulfone membrane as substrate, octadecyltrichlorosilane coating, and polydopamine layer showed promising results for separation of corrosive emulsions. The composite membrane demonstrated good rejection and flux rates for both dichloromethane and n-hexane emulsions, making it a potential candidate for water-in-oil emulsions separation with resistance to aggressive solvents.

JOURNAL OF APPLIED POLYMER SCIENCE (2021)

Article Engineering, Chemical

Enabling polyketone membrane with underwater superoleophobicity via a hydrogel-based modification for high-efficiency oil-in-water emulsion separation

Yuandong Jia et al.

Summary: The study successfully deposited a hydrophilic alginate hydrogel onto a polyketone membrane, achieving underwater superoleophobicity and ultralow oil adhesion of the membrane. By optimizing the concentration of the alginate hydrogel, the membrane showed significantly improved separation efficiency for various oil-in-water emulsions.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Chemical

Wettability Switchable Membranes for Separating Both Oil-in-water and water-in-oil emulsions

Xi Zhang et al.

Summary: The study demonstrates the potential of separation membranes with switchable wettability in efficiently treating both oil-in-water and water-in-oil emulsions. By using a simple co-deposition method of tannic acid and diethylenetriamine, commercial polypropylene membranes are endowed with switchable surface wettability that can cyclically translate between hydrophilicity and hydrophobicity through water/ethanol treatments without losing surface wettability. Density functional theory simulations and UV-vis spectra analysis were used to illustrate the chemical mechanism behind this hydrophilicity-hydrophobicity translation.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Chemistry, Multidisciplinary

Construction of a Superhydrophobic Sodium Alginate Aerogel for Efficient Oil Absorption and Emulsion Separation

Yushuang Yang et al.

Summary: SA/GO/SiO2-M aerogels, fabricated from renewable raw materials, exhibit high absorbency for organic solvents and oils, and efficiency in separating surfactant-stabilized water-in-oil emulsions. They possess good mechanical properties for reusability in both absorption and separation.

LANGMUIR (2021)

Article Polymer Science

Development of a superhydrophilic nanofiber membrane for oil/water emulsion separation via modification of polyacrylonitrile/polyaniline composite

Mohamadreza Shakiba et al.

Summary: In this study, PAN/PANI membranes were prepared by modifying PAN electrospun nanofibers with PANI. The PAN/40%PANI nanofibers prepared at 40 degrees C exhibited superhydrophilicity and were found to be the most suitable membrane for separating O/W emulsions. The membrane showed high water flux and efficient oil rejection, making it a promising candidate for water purification from industrial organic pollutants.

POLYMERS FOR ADVANCED TECHNOLOGIES (2021)

Article Engineering, Chemical

Preparation of carbon nanotube/tannic acid/polyvinylpyrrolidone membranes with superwettability for highly efficient separation of crude oil-in-water emulsions

Jittrakorn Udomsin et al.

Summary: A membrane composed of carbon nanotubes (CNTs), tannic acid (TA), and polyvinylpyrrolidone (PVP) was prepared using a green method, exhibiting superhydrophilicity and underwater superoleophobicity with excellent self-cleaning and anti-fouling properties towards highly viscous crude oil. The membrane showed remarkable oil/water separation performance and high permeation flux values for surfactant-free and -stabilized oil-in-water emulsions, indicating significant potential for practical applications.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Nanoscience & Nanotechnology

Self-Locked and Self-Cleaning Membranes for Efficient Removal of Insoluble and Soluble Organic Pollutants from Water

Kai Wang et al.

Summary: The study successfully fabricated a TiO2 nanorod-decorated membrane with self-locking and self-cleaning properties, exhibiting good mechanical strength, superhydrophilicity, and underwater superoleophobicity, capable of separating various highly emulsified oil-in-water emulsions and easily restorable by light irradiation. This membrane shows high efficiency in treating multipollutant wastewater.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Engineering, Environmental

A durable superwetting clusters-inlayed mesh with high efficiency and flux for emulsion separation

Jihao Zuo et al.

Summary: The superwetting copper mesh, embedded with PDA/PEI@CNTs-NH2 clusters, demonstrated high separation efficiency and flux for anionic surfactant-stabilized oil-in-water emulsions, achieving over 99.5% separation efficiency and a flux as high as 3946.3 L m(2) h(-1) driven solely by gravity. The mesh's strong demulsification ability and high permeation flux are attributed to the charge-screening effect of-NH3+ and size sieving effect of optimized pore size, making it promising for sustainable separation of highly stabilized oil/water emulsions.

JOURNAL OF HAZARDOUS MATERIALS (2021)

Article Engineering, Environmental

Preparation of a rice straw-based green separation layer for efficient and persistent oil-in-water emulsion separation

Lidong Feng et al.

Summary: An efficient and eco-friendly separation layer was fabricated from rice straw for large-scale oil-in-water emulsion separation, exhibiting superwettability and high electronegativity. The overlapped and intertwined structure of the layer showed excellent performance for CTAB adsorption and oil interception, leading to stable fluxes and low TOC contents in the obtained filtrates. The renewability of the separation layer was demonstrated through multiple cycles with substantial flux recovery, and effective emulsion treatment with a high TOC removal rate was achieved.

JOURNAL OF HAZARDOUS MATERIALS (2021)

Article Engineering, Chemical

In situ generated micro-bubbles enhanced membrane antifouling for separation of oil-in-water emulsion

Yang Wang et al.

Summary: A novel membrane antifouling method using in situ generated micro-bubbles for oil/water separation was proposed in this study, which combined membrane separation with catalytic reaction to reduce fouling. The in situ generated micro-bubbles significantly inhibited the surface deposition of rejected oils, leading to a remarkable reduction in membrane fouling.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Chemical

One-step engineering of low-cost kaolin/fly ash ceramic membranes for efficient separation of oil-water emulsions

Dong Zou et al.

Summary: The study utilized fly ash and kaolin to prepare ceramic membranes, with the introduction of alumina particles enhancing the strength of the support layer, leading to successful reduction of raw material costs, sintering energy consumption, and fabrication time.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Chemical

Gravity assisted super high flux microfiltration polyamide-imide membranes for oil/water emulsion separation

Asad Asad et al.

Summary: Through the use of hydrogel-facilitated phase separation technique, researchers successfully developed polyamide-imide microfiltration membranes that exhibit high oil removal efficiency, ultra-high water flux, and excellent anti-oil fouling properties. These membranes provide a promising solution to the challenge of oil/water separation.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Chemical

Tailoring the morphology of polyethersulfone/sulfonated polysulfone ultrafiltration membranes for highly efficient separation of oil-in-water emulsions using TiO2 nanoparticles

Christine N. Matindi et al.

Summary: PES/SPSf/TiO2 mixed matrix membranes were fabricated for oil-in-water emulsion separation using non-solvent induced phase inversion technique. The addition of TiO2 nanoparticles and variation of polymer concentrations resulted in membranes with excellent water permeability, oil rejection, and permeance recovery rate. Molecular dynamic simulations and spectroscopic analyses showed that the TiO2 NPs formed hydrogen bonds with polymer chains, leading to desirable morphological changes in the membranes.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Chemical

Three-dimensional structure design of tubular polyvinyl chloride hybrid nanofiber membranes for water-in-oil emulsion separation

Hongyan Xu et al.

Summary: A novel tubular polyvinyl chloride (PVC) hybrid nanofiber membrane with three-dimensional structure interwoven by three-dimensional microspheres and two-dimensional nanofibers was fabricated via electrospinning process. The membrane showed excellent liquid separation efficiency and hydrophobicity, making it suitable for separation of various water-in-oil emulsions.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Chemical

In situ biomineralization-constructed superhydrophilic and underwater superoleophobic PVDF-TiO2 membranes for superior antifouling separation of oil-in-water emulsions

Wei Deng et al.

Summary: The in situ biomineralization method was used to fabricate PVDF-TiO2 membranes with superhydrophilic and underwater superoleophobic properties, which showed excellent antifouling performance and high rejection of oil during crossflow filtration of oil-in-water emulsions. The superior performance of the membrane was attributed to the durable and super-wetting TiO2 coatings, as well as the relatively smooth surface structure that prevented oil trapping.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Chemical

A robust and repairable copper-based superhydrophobic microfiltration membrane for high-efficiency water-in-oil emulsion separation

Jiaxu Zhang et al.

Summary: This study developed superhydrophobic microfiltration membranes with low energy consumption, low cost, and high efficiency, which demonstrated excellent separation performance for water-in-oil emulsion even after multiple cycles and abrasion tests.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

Article Engineering, Environmental

Dual-functional superwettable nano-structured membrane: From ultra-effective separation of oil-water emulsion to seawater desalination

Shiyi Chen et al.

Summary: The nanofibrous poly(vinyl alcohol) based membrane (NPM) demonstrated dual functions of oil/water separation and solar water desalination, with superwettability and anti-fouling properties. The membrane, enhanced with interconnected polypyrrole nanoparticles and graphene oxide, showed excellent efficiency and durability in treating industrial wastewater and desalinating seawater. In on-site tests, the solar vapor system exhibited a promising daily solar water purification yield under natural sunlight irradiation, suggesting great potential for mass manufacture seawater purification systems without extra energy source.

CHEMICAL ENGINEERING JOURNAL (2021)

Article Chemistry, Physical

Surface wettability switching of a zeolitic imidazolate framework-deposited membrane for selective efficient oil/water emulsion separation

Hui You et al.

Summary: Oil/water emulsion separation, especially for surfactant stabilized emulsions, remains a big challenge for environmental protection. Membrane separation technology based on special wettable materials shows promise for this application due to low energy consumption and good separation performance. The study found that sequential deposition of micro particles followed by nanoparticles can form a dense selective layer for efficient oil/water emulsion separation.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2021)

Article Engineering, Environmental

Facile and sustainable fabrication of high-performance cellulose sponge from cotton for oil-in-water emulsion separation

Sudong Yang et al.

Summary: The study demonstrates a smart strategy to transform raw cotton into uniform cellulose sponge for efficient separation of oil-in-water emulsion. The cellulose sponge, composed of partially dissolved cotton fiber and exfoliated regenerated cellulose, exhibits 3D hierarchical porous structure and stable superoleophobic wettability. With excellent underwater superoleophobicity, the cellulose sponge can efficiently separate highly emulsified oil-in-water emulsions solely under gravity, providing a generic way for oil/water emulsions separation with high permeability, separation efficiency, antifouling, and reusability properties.

JOURNAL OF HAZARDOUS MATERIALS (2021)

Article Engineering, Chemical

In situ mussel-inspired Janus membranes using catechol and polyethyleneimine as the additives for highly efficient oil/water emulsions separation

Hou-Ying Ma et al.

Summary: Janus membranes with asymmetrical wettability have been successfully prepared by depositing dopamine and its derivatives on hydrophobic substrates, along with poly(vinylidene fluoride) membranes using catechol and polyethyleneimine as additives. These membranes exhibit excellent emulsion separation, stability, and durability, offering potential applications in lossless transportation of liquids.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

Article Nanoscience & Nanotechnology

One-Step Fabrication of a Micro/Nanosphere-Coordinated Dual Stimulus-Responsive Nanofibrous Membrane for Intelligent Antifouling and Ultrahigh Permeability of Viscous Water-in-Oil Emulsions

Yajie Ding et al.

Summary: A dual-responsive nanofibrous membrane with high water-in-oil emulsion separation efficiency and smart cleaning properties has been developed, showing complete restoration of its original separation performance. The membrane exhibits different hydrophilic/oleophilic properties under different conditions, achieving efficient separation of water-in-D5 emulsions at room temperature.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Chemistry, Physical

Constructing CNTs-based composite membranes for oil/water emulsion separation via radiation-induced grafting to strategy

Yu Gu et al.

Summary: The radiation-induced grafting method was used for the first time to modify multiwalled carbon nanotubes with polyvinyl alcohol, resulting in excellent dispersibility and stability. Composite membranes based on modified carbon nanotubes showed high filtration flux, oil rejection, and water flux recovery, demonstrating great potential for diverse applications.

CARBON (2021)

Article Chemistry, Physical

One-step in-situ fabrication of carbon nanotube/stainless steel mesh membrane with excellent anti-fouling properties for effective gravity-driven filtration of oil-in-water emulsions

Xiangying Yin et al.

Summary: In this study, bio-inspired inorganic carbon nanotube stainless steel meshes with superhydrophilic-underwater superoleophobic properties were fabricated via a one-step thermal chemical vapor deposition method. These meshes showed excellent antifouling properties, high water flux, and efficient separation of oily wastewater, making them promising candidates for treatment of hazardous oily wastewater in extreme conditions.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

Article Engineering, Chemical

Preparation of Janus membrane based on biomimetic polydopamine interface regulation and superhydrophobic attapulgite spraying for on-demand oil-water emulsion separation

Atian Xie et al.

Summary: A Janus membrane was constructed using sustainable regenerated cellulose as matrix, with superhydrophilic top surface and superhydrophobic bottom surface, showing excellent separation efficiency and stability in oil-water separation applications.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Chemical

An integrated Janus porous membrane with controllable under-oil directional water transport and fluid gating property for oil/water emulsion separation

Zhecun Wang et al.

Summary: The development of a novel integrated Janus porous membrane enables self-propelled energy free directional water transport in oil systems, holding significant implications for areas such as liquid separation.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Engineering, Chemical

Enhancing oil-in-water emulsion separation performance of polyvinyl alcohol hydrogel nanofibrous membrane by squeezing coalescence demulsification

Xu Zhu et al.

Summary: The PVA hydrogel nanofibrous membrane achieves sustained separation capability in oil-water emulsion separation through the SCD method, indicating great potential for practical applications.

JOURNAL OF MEMBRANE SCIENCE (2021)

Article Materials Science, Multidisciplinary

Deacetylated Cellulose Acetate/Polyurethane Composite Nanofiber Membranes with Highly Efficient Oil/Water Separation and Excellent Mechanical Properties

Weiwen Wang et al.

Summary: In this study, a novel type of multifunctional deacetylated cellulose acetate/polyurethane composite nanofiber membranes for oil/water separation were successfully fabricated by electrospinning. These membranes show super-amphiphilicity in air, super-hydrophilicity in oil, and oleophobicity in water, with high separation flux and efficiency. They also exhibit outstanding mechanical performance, antifouling, and self-cleaning ability, indicating great application prospects in oil/water separation.

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Article Engineering, Chemical

Coaxial electrospun nanofibrous aerogels for effective removal of oils and separation of water-in-oil emulsions

Guojun Jiang et al.

Summary: A facile and fluorine-free method was developed to fabricate PAN@PDMS NFAs, which exhibited excellent absorption capacities, efficient water-in-oil emulsions separation, outstanding mechanical resilience, and good resistance against various chemicals, making them promising candidate materials for practical oily wastewater treatment in environmental protection.

SEPARATION AND PURIFICATION TECHNOLOGY (2021)

Article Chemistry, Multidisciplinary

Robust and Durable Superhydrophobic Polythiophene/SiO2 Coated Cotton Fabric for Versatile Oil-Water Separation

Weibin Bai et al.

Summary: A robust and durable superhydrophobic material with a contact angle above 160 degrees was prepared by coating SiO2 particles/polythiophene on cotton fabrics through a sol-gel process and an oxidation coupling polymerization. The modified fabric displays excellent resistance to various environmental conditions and is successfully used as a filter for oil-water separation with high efficiency and reusability. This work provides a facile and selectable solution for the treatment of oily sewage and efficient oil-water separation using modified fabrics.

ADVANCED MATERIALS INTERFACES (2021)

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Microscopically tuning the graphene oxide framework for membrane separations: a review

Bofan Li et al.

Summary: Membrane-based separations, particularly using graphene oxide (GO) membranes, have attracted increasing attention due to their ability for microscopically tuning the GO framework, resulting in enhanced stability and separation performance. Various materials have been intercalated with GO nanosheets to achieve this, leading to improved membrane properties. Additionally, designing horizontal GO membranes and functionalizing GO nanosheets have also been shown to enhance membrane performance. This review highlights the importance of microscopically tuning the GO framework for improving membrane properties and performance.

NANOSCALE ADVANCES (2021)

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A robust surface with superhydrophobicity and underwater superoleophobicity for on-demand oil/water separation

Siyang. Zhao et al.

Summary: The study presented a strategy to fabricate a robust surface with superhydrophobicity and underwater superoleophobicity, which can be conveniently prepared on diverse substrates while maintaining stability under acid/base aqueous solution conditions, O-2 plasma etching, and sand impingement. Taking advantage of the coatings' properties, on-demand and multicycle separation under gravity was successfully achieved.

NANOSCALE (2021)

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Regenerated cellulose strongly adhered by a supramolecular adhesive onto the PVDF membrane for a highly efficient oil/water separation

Junkai Gao et al.

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GREEN CHEMISTRY (2021)

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Jichao Zhang et al.

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MATERIALS CHEMISTRY FRONTIERS (2021)

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Haoyu Li et al.

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Metal-Organic Framework-Intercalated Graphene Oxide Membranes for Highly Efficient Oil/Water Separation

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Wood-Nanotechnology-Based Membrane for the Efficient Purification of Oil-in-Water Emulsions

Seongmin Kim et al.

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ZIF-8@Poly(ionic liquid)-Grafted Cotton Cloth for Switchable Water/Oil Emulsion Separation

Xu Ou et al.

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Antimicrobial Janus Filters that Break Oil-in-Water Emulsions and Separate Oil

Morgan J. Lehtinen et al.

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Krishnan Muthukumar et al.

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Ceramic membranes with mussel-inspired and nanostructured coatings for water-in-oil emulsions separation

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Sustainable, Flexible, and Superhydrophobic Functionalized Cellulose Aerogel for Selective and Versatile Oil/Water Separation

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Egg Shell Powders-Coated Membrane for Surfactant-Stabilized Crude Oil-in-Water Emulsions Efficient Separation

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Robust and durable superhydrophobic steel and copper meshes for separation of oil-water emulsions

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Robust superhydrophobic attapulgite meshes for effective separation of water-in-oil emulsions

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Biomimetic and Superwettable Nanofibrous Skins for Highly Efficient Separation of Oil-in-Water Emulsions

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Thermo-Driven Controllable Emulsion Separation by a Polymer-Decorated Membrane with Switchable Wettability

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Robust Tunicate Cellulose Nanocrystal/Palygorskite Nanorod Membranes for Multifunctional Oil/Water Emulsion Separation

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Biomimetic Silicification on Membrane Surface for Highly Efficient Treatments of Both Oil-in-Water Emulsion and Protein Wastewater

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