期刊
CHEMICAL SCIENCE
卷 13, 期 19, 页码 5465-5504出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2sc00202g
关键词
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资金
- Canada Research Chair Foundation
- Canada Foundation for Innovation
- FQRNT Centre in Green Chemistry and Catalysis
- Natural Sciences and Engineering Research Council of Canada
- McGill University
This review presents recent advancements and representative examples in photocatalytic generation of C(sp(3)) radicals (R), categorized into C-H, C-C, and C-X bond cleavages based on key bond cleavages. A general mechanistic scenario and key steps in R formation are discussed in each section.
C(sp(3)) radicals (R) are of broad research interest and synthetic utility. This review collects some of the most recent advancements in photocatalytic R generation and highlights representative examples in this field. Based on the key bond cleavages that generate R, these contributions are divided into C-H, C-C, and C-X bond cleavages. A general mechanistic scenario and key R-forming steps are presented and discussed in each section.
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