Photocatalytic C(sp3) radical generation via C-H, C-C, and C-X bond cleavage

C(sp(3)) radicals (R) are of broad research interest and synthetic utility. This review collects some of the most recent advancements in photocatalytic R generation and highlights representative examples in this field. Based on the key bond cleavages that generate R, these contributions are divided into C-H, C-C, and C-X bond cleavages. A general mechanistic scenario and key R-forming steps are presented and discussed in each section.

Automated summary

This review presents recent advancements and representative examples in photocatalytic generation of C(sp(3)) radicals (R), categorized into C-H, C-C, and C-X bond cleavages based on key bond cleavages. A general mechanistic scenario and key steps in R formation are discussed in each section.