期刊
CHEMICAL COMMUNICATIONS
卷 58, 期 44, 页码 6401-6404出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc01409b
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资金
- Ministry of Education, Culture, Sports, Science, and Technology of Japan [21K05016]
- Cooperative Research Program of Network Joint Research Center for Materials and Devices'' (Institute for Materials Chemistry and Engineering, Kyushu University)
- Research Center for Computational Science, National Institute of Natural Science, Japan [21-IMS-C046, 22-IMS-C46]
- Grants-in-Aid for Scientific Research [21K05016] Funding Source: KAKEN
Cu complexes with p-dimethylaminophenolate ligands were synthesized and characterized in this study. The complexes exhibited a valence state change from Cu-II-phenolate to Cu-I-phenoxyl radical upon loss of the coordinated solvent. The Cu-I-phenoxyl radical species showed characteristic properties and reactivities.
Cu complexes with p-dimethylaminophenolate ligands were synthesized by the reaction of Cu-II ions with the ligands under inert gas atmosphere and characterized. The complexes showed a valence state change from Cu-II-phenolate to Cu-I-phenoxyl radical on loss of the coordinated solvent. The Cu-I-phenoxyl radical species showed the characteristic properties and reactivities.
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