期刊
ORGANIC CHEMISTRY FRONTIERS
卷 9, 期 12, 页码 3312-3316出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2qo00511e
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资金
- Xi'an Jiaotong University
This article describes the alkynyl-induced stereoselective construction of polysubstituted enynes via Pd-catalyzed allylic arylations. The interaction between the alkynyl group and the Pd-allyl fragment is proposed to be crucial for obtaining the desired products with exclusive (Z)-configurations.
The alkynyl-induced stereoselective construction of polysubstituted enynes via Pd-catalyzed allylic arylations is described. The interaction between the alkynyl group and the Pd-allyl fragment is proposed to be the key toward the desired products with exclusive (Z)-configurations. This methodology enables the construction of a number of structurally diverse and otherwise synthetically challenging (Z)-polysubstituted enynes under user-friendly conditions.
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