期刊
CHEMICAL SCIENCE
卷 13, 期 21, 页码 6283-6290出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2sc01387h
关键词
-
资金
- National Natural Science Foundation of China [22071077, 21774042, 21871107, 21975102]
In this study, a cyclic CO2-based polycarbonate with an innovative structure was synthesized, and complete chemical recycling of PCHC was achieved, representing closed-loop recycling of CO2-based polycarbonates.
It is highly desirable to reduce the environmental pollution related to the disposal of end-of-life plastics. Polycarbonates derived from the copolymerization of CO2 and epoxides have attracted much attention since they can enable CO2-fixation and furnish biorenewable and degradable polymeric materials. So far, only linear CO2-based polycarbonates have been reported and typically degraded to cyclic carbonates. Here we synthesize a homogeneous dinuclear methyl zinc catalyst ((BDI-ZnMe)(2), 1) to rapidly copolymerize meso-CHO and CO2 into poly(cyclohexene carbonate) (PCHC) with an unprecedentedly cyclic structure. Moreover, in the presence of trace amounts of water, a heterogeneous multi-nuclear zinc catalyst ((BDI-(ZnMe2 center dot xH(2)O))(n), 2) is prepared and shows up to 99% selectivity towards the degradation of PCHC back to meso-CHO and CO2. This strategy not only achieves the first case of cyclic CO2-based polycarbonate but also realizes the complete chemical recycling of PCHC back to its monomers, representing closed-loop recycling of CO2-based polycarbonates.
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