4.7 Article

Synthesis, structure and properties of trivalent and pentavalent tricarbabismatranes

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CHEMICAL COMMUNICATIONS
卷 58, 期 46, 页码 6614-6617

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc00751g

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The first trivalent and pentavalent tricarbabismatranes were synthesized and their properties were investigated. The pentavalent bismatrane difluoride showed good stability to air, while the pentavalent bismatrane dichloride underwent C-Cl bond reductive elimination even at room temperature.
The first trivalent and pentavalent tricarbabismatranes were synthesized by the reaction of N(CH2{2-LiC6H4})(3) with BiCl3 and subsequent reaction with XeF2, respectively. The trivalent bismatrane was easily oxidized by air, while the pentavalent bismatrane difluoride was relatively stable to air. A similar pentavalent bismatrance dichloride was prone to C-Cl bond reductive elimination even at room temperature.

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