期刊
DALTON TRANSACTIONS
卷 51, 期 28, 页码 10702-10706出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt00607c
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In this study, a capped bioinspired ligand with a tris(2-pyridyl-methyl)amine (TPA) unit and a triazole-based intramolecular H-bonding secondary sphere was synthesized. The resulting cage has a well-defined cavity and combines hydrophobic nature with H-bonding properties.
A capped bioinspired ligand built from a tris(2-pyridyl-methyl)amine (TPA) unit and surmounted by a triazole-based intramolecular H-bonding secondary sphere was prepared. The resulting cage provides a well-defined cavity combining the hydrophobic nature with H-bonding properties. Its coordinating properties were explored using Zn(ii) and Cu(ii) metal ions.
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