期刊
DALTON TRANSACTIONS
卷 51, 期 22, 页码 8557-8570出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt00459c
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资金
- U.S. Department of Energy (Office of Science, Office of Basic Energy Sciences, Catalysis Program) [DE-SC0022203]
- National Science Foundation [CHE-2101582, DMR-1305724]
- U.S. Department of Energy (DOE) [DE-SC0022203] Funding Source: U.S. Department of Energy (DOE)
Understanding the interaction between ligands and metals is essential in inorganic chemistry. This article focuses on the coordination complexes formed between extended surface ligands and metals.
Understanding how a ligand affects the steric and electronic properties of a metal is the cornerstone of the inorganic chemistry enterprise. What happens when the ligand is an extended surface? This question is central to the design and implementation of state-of-the-art functional materials containing transition metals. This perspective will describe how these two very different sets of extended surfaces can form well-defined coordination complexes with metals. In the Green formalism, functionalities on oxide surfaces react with inorganics to form species that contain X-type or LX-type interactions between the metal and the oxide. Carbon surfaces are neutral L-type ligands; this perspective focuses on carbons that donate six electrons to a metal. The nature of this interaction depends on the curvature, and thereby orbital overlap, between the metal and the extended pi-system from the nanocarbon.
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