4.6 Article

Monolithic Epitaxial Integration of β-Ga2O3 with 100 Si for Deep Ultraviolet Photodetectors

期刊

ACS APPLIED ELECTRONIC MATERIALS
卷 4, 期 4, 页码 1619-1625

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acsaelm.1c01296

关键词

heteroepitaxy; gallium oxide on Si(100); monolithic integration; X-ray diffraction; DUV photodetectors; spectral response

资金

  1. Ministry of Electronics and Information Technology (MeitY), Government of India [MeitY 5(3)/2017-NANO]
  2. Department of Science and Technology, Government of India [DST/NM/NNetRA/2018(G)-IISc]
  3. Ministry of Human Resource and Development (MHRD), Government of India
  4. NIEIN
  5. Media Lab Asia, MeitY

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In this report, direct epitaxial integration of beta-Ga2O3 on a Si(100) substrate is demonstrated, providing opportunities for the development of deep-UV optoelectronics.
In this report, we demonstrate direct epitaxial integration of beta-Ga2O3 on a (400) oriented silicon on insulator substrate toward deep-UV (DUV) optoelectronics. The 550 nm thick (400) epitaxial-beta-Ga2O3 films are deposited onto Si(100) using a two-step buffer and a two-step epilayer scheme. The epitaxial orientation relation between beta-Ga2O3, MgO, and silicon(100) is given by (400) ss-Ga2O3||(100) MgO||(100) Si and.010. beta-Ga2O3 parallel to.011. MgO parallel to.110.Si. The presence of rotational variants is confirmed by Xray diffraction and transmission electron microscopy. Epitaxy was found to be mediated through a MgGa2O4 layer formed at the beta-Ga2O3/MgO interface under oxygen-deficient conditions during pulsed layer deposition. The.-scan symmetric and asymmetric full width at half-maximum values of beta-Ga2O3 are 2.41 and 2.39 degrees, respectively. Photodetectors realized in a conventional metalsemiconductor-metal geometry exhibit a maximum responsivity of 11.8 A/W at 246 nm at 40 V with a photo to dark current ratio of 2.5 x 10(2) and a UV-to-visible rejection ratio > 103. The detectors do not exhibit any persistent photoconductivity as is evident from the rise and fall times of 0.54 and 0.32 s, respectively. Such a monolithic integration of beta-Ga2O3 on Si(100) opens up opportunities for the development of integrated DUV focal plane arrays on a SoC chip.

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