CO2 hydrogenation to methanol over Rh/In2O3-ZrO2 catalyst with improved activity

Article Chemistry, Applied

CO2 hydrogenation to methanol over Rh/In2O3 catalyst

Jing Wang et al.

Summary: Highly dispersed Rh/In2O3 catalyst prepared by deposition-precipitation method shows excellent activity and selectivity for CO2 hydrogenation to methanol, promoting the reaction even at lower temperatures.

CATALYSIS TODAY (2021)

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Article Chemistry, Physical

Atomically dispersed Ptn+species as highly active sites in Pt/In2O3 catalysts for methanol synthesis from CO2 hydrogenation

Zhe Han et al.

Summary: The methanol selectivity of In2O3 catalyst can be significantly enhanced by introducing a small amount of Pt, leading to a higher efficiency in the process of CO2 hydrogenation to methanol.

JOURNAL OF CATALYSIS (2021)

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Article Chemistry, Physical

Relations between Surface Oxygen Vacancies and Activity of Methanol Formation from CO2 Hydrogenation over In2O3 Surfaces

Ang Cao et al.

Summary: The study investigated the catalytic activity of In2O3 (111) and In2O3 (110) in methanol synthesis, finding a relationship between the number of reduced surface In layers and catalytic activity. By adding a ZrO2 support, the activity of In2O3 catalyst in methanol formation can be optimized.

ACS CATALYSIS (2021)

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Article Chemistry, Physical

CO2-Promoted Reactions: An Emerging Concept for the Synthesis of Fine Chemicals and Pharmaceuticals

Prakash Kumar Sahoo et al.

Summary: Carbon dioxide serves as a crucial C-1 building block and can trigger changes in chemical properties without toxicity, potentially replacing toxic reagents in industrial applications. This promotes the synthesis of pharmaceuticals and important molecules.

ACS CATALYSIS (2021)

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Article Chemistry, Multidisciplinary

Experimental and theoretical studies of CO2 hydrogenation to methanol on Ru/In2O3

Qinglei Wu et al.

Summary: In this study, a Ru/In2O3 catalyst with high dispersion and activity was prepared by deposition precipitation method for CO2 hydrogenation to methanol. The Ru loading enhanced the activation ability of hydrogen and CO2, leading to high methanol selectivity and space-time yield. Theoretical analysis showed that the CO-hydrogenation route on Ru/In2O3 was thermodynamically favored for methanol production from CO2.

JOURNAL OF CO2 UTILIZATION (2021)

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Article Multidisciplinary Sciences

Nanostructure of nickel-promoted indium oxide catalysts drives selectivity in CO2 hydrogenation

Matthias S. Frei et al.

Summary: This study investigates the complex interplay between nanostructure and product selectivity of nickel-promoted In2O3 in CO2 hydrogenation to methanol. The presence of nickel on the oxide surface forms InNi3 patches, which boost methanol production by providing neutral hydrogen species. Ratios of nickel to In content influence the formation of different structures and the production of CO and methane in the reaction.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Physical

Highly Active Ir/In2O3 Catalysts for Selective Hydrogenation of CO2 to Methanol: Experimental and Theoretical Studiese

Chenyang Shen et al.

Summary: Iridium (Ir) catalysts supported by indium oxide show high activity and selectivity in CO2 hydrogenation to methanol, with higher Ir loading leading to enhanced activity. The intense interaction between Ir and In2O3 on the catalysts results in high dispersion and the Ir-In2O3 interface as the active site for selective hydrogenation of CO2 into methanol.

ACS CATALYSIS (2021)

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Article Chemistry, Physical

Role of Zirconia in Indium Oxide-Catalyzed CO2 Hydrogenation to Methanol

Matthias S. Frei et al.

ACS CATALYSIS (2020)

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Article Chemistry, Multidisciplinary

Methanol Synthesis at a Wide Range of H2/CO2Ratios over a Rh-In Bimetallic Catalyst

Molly Meng-Jung Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Efficient hydrogenation of CO2 to methanol over Pd/In2O3/SBA-15 catalysts

Haoxi Jiang et al.

JOURNAL OF CO2 UTILIZATION (2020)

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Article Chemistry, Physical

Hydrogenation of CO2 to Methanol on a Auδ+-In2O3-x Catalyst

Ning Rui et al.

ACS CATALYSIS (2020)

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Article Chemistry, Multidisciplinary

Advancing halide-free catalytic synthesis of CO2-based heterocycles

Arjan W. Kleij

CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY (2020)

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Article Chemistry, Physical

A Highly Active Au/In2O3-ZrO2 Catalyst for Selective Hydrogenation of CO2 to Methanol

Zhe Lu et al.

CATALYSTS (2020)

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Article Chemistry, Multidisciplinary

Density functional theoretical study of Au4/In2O3 catalyst for CO2 hydrogenation to methanol: The strong metal-support interaction and its effect

Ning Rui et al.

JOURNAL OF CO2 UTILIZATION (2020)

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Article Chemistry, Physical

Rh promoted In2O3 as a highly active catalyst for CO2 hydrogenation to methanol

Nazmul Hasan M. D. Dostagir et al.

CATALYSIS SCIENCE & TECHNOLOGY (2020)

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Article Chemistry, Physical

Pd Supported on MIL-68(In)-Derived In2O3 Nanotubes as Superior Catalysts to Boost CO2 Hydrogenation to Methanol

Zhongjie Cai et al.

ACS CATALYSIS (2020)

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Review Chemistry, Multidisciplinary

Photocarboxylation with CO2: an appealing and sustainable strategy for CO2 fixation

Xing He et al.

GREEN CHEMISTRY (2020)

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Article Chemistry, Applied

Selective hydrogenation of CO2 to methanol over Ni/In2O3 catalyst

Xinyu Jia et al.

JOURNAL OF ENERGY CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

A highly active Pt/In2O3catalyst for CO2hydrogenation to methanol with enhanced stability

Kaihang Sun et al.

GREEN CHEMISTRY (2020)

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Article Chemistry, Physical

Synergy between active sites of Cu-In-Zr-O catalyst in CO2 hydrogenation to methanol

Libo Yao et al.

JOURNAL OF CATALYSIS (2019)

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Article Multidisciplinary Sciences

Atomic-scale engineering of indium oxide promotion by palladium for methanol production via CO2 hydrogenation

Matthias S. Frei et al.

NATURE COMMUNICATIONS (2019)

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Article Chemistry, Physical

CO2 Hydrogenation to Methanol over ZrO2-Containing Catalysts: Insights into ZrO2 Induced Synergy

Kongzhai Li et al.

ACS CATALYSIS (2019)

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Article Chemistry, Multidisciplinary

Structural Evolution and Dynamics of an In2O3 Catalyst for CO2 Hydrogenation to Methanol: An Operando XAS-XRD and In Situ TEM Study

Athanasia Tsoukalou et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Review Chemistry, Physical

Catalytic Strategies for the Cycloaddition of Pure, Diluted, and Waste CO2 to Epoxides under Ambient Conditions

Rafik Rajjak Shaikh et al.

ACS CATALYSIS (2018)

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Article Chemistry, Physical

Direct Production of Lower Olefins from CO2 Conversion via Bifunctional Catalysis

Peng Gao et al.

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Article Chemistry, Physical

Theoretical study of the promotional effect of ZrO2 on In2O3 catalyzed methanol synthesis from CO2 hydrogenation

Minhua Zhang et al.

APPLIED SURFACE SCIENCE (2018)

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Direct Conversion of Syngas into Light Olefins over Zirconium-Doped Indium(III) Oxide and SAPO-34 Bifunctional Catalysts: Design of Oxide Component and Construction of Reaction Network

Junjie Su et al.

CHEMCATCHEM (2018)

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Article Chemistry, Physical

CO2 hydrogenation to methanol over Pd/In2O3: effects of Pd and oxygen vacancy

Ning Rui et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2017)

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Article Chemistry, Multidisciplinary

Indium Oxide as a Superior Catalyst for Methanol Synthesis by CO2 Hydrogenation

Oliver Martin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Review Chemistry, Multidisciplinary

Silver-catalyzed carboxylation

K. Sekine et al.

CHEMICAL SOCIETY REVIEWS (2016)

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Article Chemistry, Multidisciplinary

Hydrogenation of CO2 to methanol over In2O3 catalyst

Kaihang Sun et al.

JOURNAL OF CO2 UTILIZATION (2015)

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Review Chemistry, Multidisciplinary

Ionic liquid-based green processes for energy production

Suojiang Zhang et al.

CHEMICAL SOCIETY REVIEWS (2014)

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Article Chemistry, Physical

Active Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenation on In2O3(110): A DFT Study

Jingyun Ye et al.

ACS CATALYSIS (2013)

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Article Chemistry, Physical

Comparative study of CO and CO2 hydrogenation over supported Rh-Fe catalysts

Makarand R. Gogate et al.

CATALYSIS COMMUNICATIONS (2010)

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Stabilization of active Rh2O3 species for catalytic decomposition of N2O on La-, Pr-doped CeO2

A. Bueno-Lopez et al.

JOURNAL OF CATALYSIS (2006)

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CO2 hydrogenation reactivity and structure of Rh/SiO2 catalysts prepared from acetate, chloride and nitrate precursors

H Kusama et al.

APPLIED CATALYSIS A-GENERAL (2001)

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CO2 hydrogenation to methanol over Rh/In2O3-ZrO2 catalyst with improved activity

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