期刊
MATERIALS HORIZONS
卷 9, 期 7, 页码 1992-1998出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2mh00442a
关键词
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资金
- National Science Foundation, Division of Materials Research, Polymers Program [DMR2103196]
- Office of Science [DE-SC0012704]
- Ministry of Science and Higher Education of the Russian Federation [075-01056-22-00]
This report discusses how high-power ultrasonic processing was used to enhance the piezoelectric performance of PVDF by inducing a hard-to-soft piezoelectric transition and increasing the piezoelectric coefficient d(31). The research found that breaking secondary crystals in the oriented amorphous fraction through ultrasonication can lead to improved piezoelectricity in PVDF.
Although high piezoelectric coefficients have recently been observed in poly(vinylidene fluoride-co-trifluoroethylene) [P(VDF-TrFE)] random copolymers, they have low Curie temperatures, which makes their piezoelectricity thermally unstable. It has been challenging to achieve high piezoelectric performance from the more thermally stable PVDF homopolymer. In this report, we describe how high-power ultrasonic processing was used to induce a hard-to-soft piezoelectric transition and improve the piezoelectric coefficient d(31) in neat PVDF. After high-power ultrasonication for 20 min, a uniaxially stretched and poled PVDF film exhibited a high d(31) of 50.2 +/- 1.7 pm V-1 at room temperature. Upon heating to 65 degrees C, the d(31) increased to a maximum value of 76.2 +/- 1.2 pm V-1, and the high piezoelectric performance persisted up to 110 degrees C. The enhanced piezoelectricity was attributed to the relaxor-like secondary crystals in the oriented amorphous fraction, broken off from the primary crystals by ultrasonication, as suggested by differential scanning calorimetry and broadband dielectric spectroscopy studies.
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