Designed assembly of heterometallic zeolite-like framework materials from two different supertetrahedral metal clusters

This work demonstrates a feasible strategy for the synthesis of new zeolite-like framework materials. With the strategy of using two different supertetrahedral clusters as secondary building units, two new heterometallic zeolite-like frameworks with isomeric structures but tunable topologies were first made. Besides, the porous nature and the proton conduction performance of the new materials were further studied.

Automated summary

This study demonstrates a feasible strategy for synthesizing new zeolite-like framework materials, and successfully prepares two heterometallic zeolite-like frameworks with isomeric structures but tunable topologies.