4.8 Article

Chemical recycling of polyhydroxybutyrate and polylactic acid over supported Ru catalysts

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GREEN CHEMISTRY
卷 24, 期 10, 页码 -

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d2gc00216g

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  1. Exploratory Research Space of RWTH Aachen University (ERS) in the Center for Polymer Recycling [C4PR]
  2. German federal and state governments [EXC 2186, 390919832]
  3. European Regional Development Fund (ERDF)
  4. federal state of North-Rhine Westphalia, Germany

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In this study, a novel protocol for catalytic depolymerisation of bio-based polyhydroxybutyrate and polylactic acid over Ru/CeO2 was presented. The corresponding monomers, 3-hydroxybutyric acid and lactic acid, were obtained with high yields of 79% and 94% respectively. Furthermore, the transformation of a mixture of both biopolyesters was also possible with comparable results.
Herein, we present a novel protocol for the catalytic depolymerisation of bio-based polyhydroxybutyrate and polylactic acid over Ru/CeO2. The corresponding monomers of 3-hydroxybutyric acid and lactic acid were afforded with yields of 79 and 94%, respectively. Moreover, the transformation of a mixture of both biopolyesters was possible with a comparable outcome.

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