☆ 4.8 Review

Recent progress of Bi-based electrocatalysts for electrocatalytic CO2 reduction

NANOSCALE (2022)

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Review Chemistry, Multidisciplinary

Dynamic Evolution of Active Sites in Electrocatalytic CO2 Reduction Reaction: Fundamental Understanding and Recent Progress

Wenchuan Lai et al.

Summary: This review emphasizes the dynamic evolution of active sites in electrocatalytic CO2 reduction reaction (CO2RR) and its relationship with catalytic performance. The fundamental principles and operando techniques for studying dynamic evolution are first discussed, followed by the exploration of dynamic evolution behaviors and their correlations with catalytic properties on typical catalysts. Finally, the emerging technique for manipulating dynamic evolution and future opportunities are considered.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Integrated 3D Open Network of Interconnected Bismuthene Arrays for Energy-Efficient and Electrosynthesis-Assisted Electrocatalytic CO2 Reduction

Ying-Chun He et al.

Summary: An integrated 3D open network of interconnected bismuthene arrays was fabricated for electrocatalytic CO2 reduction reaction, demonstrating high Faradaic efficiency and current density for stable formate production. The research also showed the feasibility for practical implementation with substantially improved electrochemical and economic efficiency.

SMALL (2022)

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Article Chemistry, Physical

Customizable CO2 Electroreduction to C1 or C2+ Products through Cuy/CeO2 Interface Engineering

Jinlong Yin et al.

Summary: This study achieved efficient electroreduction of CO2 by decorating Cu on CeO2 and controlling the selectivity of products. The dependence of reduction pathway on the relative ratio of the low-frequency band *COLFB to the high-frequency band *COHFB was revealed using in situ infrared and Raman spectroscopy, providing a theoretical basis for the design of heterostructured catalysts for CO2 electroreduction.

ACS CATALYSIS (2022)

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Article Chemistry, Multidisciplinary

Bi particles with exposed (012) facet on 3D substrate as highly active and durable electrode for CO2 reduction to formate

Xinying Wei et al.

Summary: A highly challenging task to produce 3D electrodes with high activity, selectivity, and durability for CO2 mediated energy conversion was achieved by densely dispersing Bi dendrites on 3D carbon cloth and exposing specific facets of Bi nanoparticles. The resulting Bi NPs/CC electrode exhibited high current density, Faradaic efficiency, and durability, showcasing great potential for large-scale applications in CO2 conversion.

JOURNAL OF CO2 UTILIZATION (2022)

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Article Engineering, Environmental

Fabrication of Bi/Sn bimetallic electrode for high-performance electrochemical reduction of carbon dioxide to formate

Zong Li et al.

Summary: CO2 electrochemical reduction has been achieved to convert CO2 into formic acid using bimetallic bismuth and tin deposited on a copper mesh. The newly developed catalyst exhibits high Faradaic efficiency, partial current density, and formic acid production rate, demonstrating great potential for practical applications.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Chemistry, Physical

Customizable CO2 Electroreduction to C-1 or C-2(+) Products through Cu-y/CeO2 Interface Engineering

Jinlong Yin et al.

Summary: Cu-decorated CeO2 composites were synthesized through a controllable method, leading to enhanced CO2 electroreduction efficiency and selectivity by adjusting the Cu loading. In situ infrared and Raman spectroscopy provided insights into the reduction pathway.

ACS CATALYSIS (2022)

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Article Chemistry, Multidisciplinary

Monoclinic Scheelite Bismuth Vanadate Derived Bismuthene Nanosheets with Rapid Kinetics for Electrochemically Reducing Carbon Dioxide to Formate

Wenxiu Ma et al.

Summary: The study demonstrates the fabrication of bismuthene nanosheets as efficient electrocatalysts for CO(2) reduction to formate. The bismuthene nanosheets exhibit high formate Faradaic efficiency over a wide potential window, outperforming state-of-the-art electrocatalysts. Both experimental and theoretical investigations suggest that bismuthene nanosheets promote fast reaction kinetics towards formate production.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Review Chemistry, Multidisciplinary

Recent Progress in Electrocatalytic Methanation of CO2 at Ambient Conditions

Runbo Zhao et al.

Summary: This review systematically reviews the latest research on different electrocatalysts for the conversion of CO2 to CH4, as well as strategies for enhancing catalytic activity and selectivity. The review also highlights the importance of electrolyte influence on the activity and selectivity of CO2 electrocatalysis to CH4.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Electron Localization and Lattice Strain Induced by Surface Lithium Doping Enable Ampere-Level Electrosynthesis of Formate from CO2

Shuai Yan et al.

Summary: A surface-lithium-doped tin (s-SnLi) catalyst was developed to enhance the activity and selectivity of CO2 electroreduction to formate. The catalyst exhibited excellent performance with high Faradaic efficiency and stability in Zn-CO2 batteries, showing potential for commercialization.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Economics

Towards carbon neutrality by implementing carbon emissions trading scheme: Policy evaluation in China

Xing Chen et al.

Summary: This study examines the effectiveness of carbon trading in China's pilot program and finds that it significantly improves carbon/energy-carbon performance, promoting energy conservation and emission reduction. The results are robust and significant, confirming carbon trading as an effective policy tool for achieving carbon neutrality, providing policy suggestions for global implementation of carbon neutrality.

ENERGY POLICY (2021)

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Article Multidisciplinary Sciences

Insights on forming N,O-coordinated Cu single-atom catalysts for electrochemical reduction CO2 to methane

Yanming Cai et al.

Summary: Single-atom catalysts are promising for catalyzing CO2 reduction to produce high value hydrocarbons, but most reactions yield CO. In this study, a low-temperature calcining process was used to fabricate a carbon-dots-based SAC which efficiently converts CO2 to methane.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Physical

A general strategy for obtaining BiOX nanoplates derived Bi nanosheets as efficient CO2 reduction catalysts by enhancing CO2.- adsorption and electron transfer

Peng Liu et al.

Summary: The study presents a method for preparing Bi-based electrocatalysts via in situ reduction of BiOI in CO2-saturated electrolyte, and finds that Bi nanosheets exhibit excellent performance for CO2 reduction to formate. Bi nanosheets can increase CO2 adsorption, enlarge active surface area, show better reaction kinetics, and provide lower contact resistance for accelerated electron transfer.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Selective Etching Quaternary MAX Phase toward Single Atom Copper Immobilized MXene (Ti3C2Clx) for Efficient CO2 Electroreduction to Methanol

Qi Zhao et al.

Summary: An efficient method for producing single atom copper immobilized MXene for catalyzing CO2 reduction to methanol through selective etching of hybrid A layers in quaternary MAX phases was demonstrated. The single atom Cu catalyst exhibited high Faradaic efficiency and good electrocatalytic stability, attributed to its unique electronic structure and surface functional groups.

ACS NANO (2021)

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Article Chemistry, Physical

Facile synthesis of porous Cu-Sn alloy electrode with prior selectivity of formate in a wide potential range for CO2 electrochemical reduction

Da Li et al.

Summary: The study prepared a porous Cu6.26Sn5 electrode, tuning the electronic structure of the catalyst by alloying Cu with Sn atoms to balance the adsorption and protonation of intermediates, resulting in increased CO2 concentration and selectivity, promising efficient CO2 electroreduction.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Article Chemistry, Physical

High-selectivity electrochemical CO2 reduction to formate at low overpotential over Bi catalyst with hexagonal sheet structure

Hao Jiang et al.

Summary: This study developed a facile strategy to obtain Bi catalysts with a hexagonal sheet structure on copper foil, showing high efficiency for formate production and stability in CO2 reduction. The sharp edges and corner sites of the catalyst provided numerous surface-active sites, increasing electrical conductivity and local electric field intensities of the surface electrode.

APPLIED SURFACE SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Electrochemical Reductive N-Methylation with CO2 Enabled by a Molecular Catalyst

Conor L. Rooney et al.

Summary: The development of electrochemical reductive N-methylation reaction with CO2 as the building block demonstrates high monomethylation selectivity via the overall transfer of 12 electrons and 12 protons. The nucleophilicity of the amine reactant is found to be a descriptor for the C-N coupling efficacy in the reaction.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Accessing Organonitrogen Compounds via C-N Coupling in Electrocatalytic CO2 Reduction

Zixu Tao et al.

Summary: This research aims to broaden the product scope of electrocatalytic CO2 reduction reactions by introducing additional reactants containing inorganic heteroatoms, enabling the sustainable synthesis of valuable products such as organonitrogen compounds.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Physical

Tailoring the Electrochemical Protonation Behavior of CO2 by Tuning Surface Noncovalent Interactions

Xiao-Cheng Liu et al.

Summary: This study demonstrates that enhancing CO2 reduction catalysts through noncovalent interactions can improve the selectivity and activity of SnO catalysts, leading to efficient formate production. Moreover, the introduction of hydroxyl groups can be a general strategy for CO2 hydrogenation on various metal oxides.

ACS CATALYSIS (2021)

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Article Nanoscience & Nanotechnology

Hydrangea-like Superstructured Micro/Nanoreactor of Topotactically Converted Ultrathin Bismuth Nanosheets for Highly Active CO2 Electroreduction to Formate

Chan-Juan Peng et al.

Summary: By fabricating an extremely active and selective ultra-thin bismuth nanosheet nano-reactor, high-efficiency electrochemical reduction of carbon dioxide to formate with nearly 100% Faraday selectivity can be achieved. The reactor can maintain high current densities at low applied potentials without compromising selectivity.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Applied

Degradation study on tin- and bismuth-based gas-diffusion electrodes during electrochemical CO2 reduction in highly alkaline media

Fabian Bienen et al.

Summary: This study investigated the degradation of tin-based gas-diffusion electrodes (GDE) and a promising Bi2O3 GDE in highly alkaline media during electrochemical CO2 reduction, revealing that the SnO2 catalyst dissolves and may be partially redeposited, while the Bi2O3 GDE remains stable due to the redeposition of metallic Bi during CO2 conversion. The deterioration of electrode performance correlates with the differential double layer capacitance and the rate of increase for hydrogen FE, indicating the superposition of different degradation mechanisms.

JOURNAL OF ENERGY CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Bi-Sn Oxides for Highly Selective CO2 Electroreduction to Formate in a Wide Potential Window

Jianjian Tian et al.

Summary: In this study, highly stable SnO2/Bi2O3 oxide catalysts were obtained by distributing SnO2 nanoparticles on the surface of Bi2O3 sheets. The enhanced stability and high selectivity of the catalyst in CO2 electroreduction reaction were attributed to the strong interfacial interaction between SnO2 and Bi2O3, as well as the improved adsorption of HCOO* intermediate. The SnO2/Bi2O3 catalyst showed excellent performance with a high FEC1 value of 90% and a selectivity of HCOOH above 76% in a wide potential window and a long duration.

CHEMSUSCHEM (2021)

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Editorial Material Chemistry, Physical

Electrocatalytic conversion of carbon dioxide for the Paris goals

Sarah M. Jordaan et al.

Summary: The electrocatalytic conversion of CO2 into useful products can contribute to the Paris goals by utilizing abundant low-carbon power and technological advances. Coordinated efforts are needed to support the commercialization of such capture and catalytic technologies while deploying the necessary infrastructure.

NATURE CATALYSIS (2021)

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Article Chemistry, Physical

Nonnitrogen Coordination Environment Steering Electrochemical CO2-to-CO Conversion over Single-Atom Tin Catalysts in a Wide Potential Window

Wenpeng Ni et al.

Summary: Replacing Sn-N-4 moieties with a special Sn-C2O2F coordination structure in Sn SAC can efficiently convert CO2 to CO with a Faradaic efficiency up to 95.2%, and theoretical calculations reveal the significant influence of C and O coordination as well as the Sn-bonded F atom on the reaction.

ACS CATALYSIS (2021)

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Review Chemistry, Multidisciplinary

Recent Progresses in Electrochemical Carbon Dioxide Reduction on Copper-Based Catalysts toward Multicarbon Products

Jinli Yu et al.

Summary: Electrochemical carbon dioxide reduction reaction offers a promising way of converting CO2 to value-added chemicals, but the conversion to more valuable multicarbon products remains challenging. Recent progress in using copper-based catalysts for electrochemical CO2 reduction to multicarbon products is reviewed, with a focus on catalyst engineering and cell engineering approaches.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Large-Area Vertically Aligned Bismuthene Nanosheet Arrays from Galvanic Replacement Reaction for Efficient Electrochemical CO2 Conversion

Jia Fan et al.

Summary: In this work, it is demonstrated that the galvanic replacement reaction is an effective method for preparing high-quality bismuthene nanosheet arrays, enabling the growth of small-thickness, large-surface-area bismuthene nanosheets on copper substrates, and achieving efficient CO2 reduction reactions.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Facet Engineering to Regulate Surface States of Topological Crystalline Insulator Bismuth Rhombic Dodecahedrons for Highly Energy Efficient Electrochemical CO2 Reduction

Huan Xie et al.

Summary: Bismuth is a topological crystalline insulator with gapless topological surface states protected by specific crystalline symmetry, making it a promising electrocatalyst for CO2 reduction reaction. By optimizing the crystal facet properties, single-crystalline Bi rhombic dodecahedrons demonstrate high selectivity and efficiency for formate production, showing potential for high-rate formate production and efficient energy storage of intermittent renewable electricity.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Synergistic Effect of Atomically Dispersed Ni-Zn Pair Sites for Enhanced CO2 Electroreduction

Youzhi Li et al.

Summary: Dual-atom catalysts have shown potential to outperform single-atom catalysts in the electrochemical conversion of CO2 due to a synergistic effect observed in atomically dispersed Ni-Zn bimetal sites. The heteronuclear coordination modifies the d-states of the metal atom, narrowing the gap between εd and EF to strengthen electronic interaction at the reaction interface, leading to improved catalytic efficiency.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Spontaneously Sn-Doped Bi/BiOx Core-Shell Nanowires Toward High-Performance CO2 Electroreduction to Liquid Fuel

Yang Zhao et al.

Summary: Spontaneously Sn doped Bi/BiOx nanowires exhibit impressive formate selectivity and high current density, with the introduction of Sn atoms promoting *OCHO intermediate stabilization and suppressing competitive H-2/CO production. This work provides insights into promoting electrochemical CO2 conversion into formate for practical applications through effective in situ construction of metal/metal oxide hybrid composites with heteroatom doping.

NANO LETTERS (2021)

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Article Green & Sustainable Science & Technology

Common strategies for improving the performances of tin and bismuth-based catalysts in the electrocatalytic reduction of CO2 to formic acid/formate

Xiaowei An et al.

Summary: This article critically reviews common strategies for improving the electrocatalytic performance of tin (Sn) and bismuth (Bi)-based catalysts in the electrochemical reduction of CO2 to formic acid/formate. The mechanisms for enhancing electrocatalytic performance are analyzed and discussed, providing inspiration for researchers to design and synthesize more efficient electrocatalysts for CO2 reduction.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2021)

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Article Chemistry, Multidisciplinary

Solvent-Mediated Shell Dimension Reconstruction of Core@Shell PdAu@Pd Nanocrystals for Robust C1 and C2 Alcohol Electrocatalysis

Fei Gao et al.

Summary: A facile one-step surfactant-free strategy was developed for reconstructing shell dimensions of PdAu@Pd core@shell nanocrystals, resulting in nanocrystals with different structures and excellent catalytic properties.

SMALL (2021)

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Article Multidisciplinary Sciences

Stable, active CO2 reduction to formate via redox-modulated stabilization of active sites

Le Li et al.

Summary: Alloying p-block elements with different electronegativities can modulate the redox potential of active sites in CO2 electrochemical reduction, leading to enhanced formic acid production and stability. Experimental findings demonstrate that stabilized Sn-Bi/SnO2 surfaces exhibit excellent Faradaic efficiency and overpotential.

NATURE COMMUNICATIONS (2021)

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Article Multidisciplinary Sciences

Regulation of functional groups on graphene quantum dots directs selective CO2 to CH4 conversion

Tianyu Zhang et al.

Summary: Functionalized graphene quantum dots can efficiently convert CO2 to CH4, with the yield of CH4 positively correlated to the electron-donating ability of the functional groups. The electron-donating groups play a significant role in regulating the reactivity of graphene quantum dots in CO2 electro-reduction, providing insight into the design of active carbon catalysts for this process.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Multidisciplinary

Effects of thicknesses and sizes of BiOX nanoplates precursors on derived Bi nanosheets for efficient CO2 electroreduction

Peng Liu et al.

Summary: The study demonstrates that in situ transformed electrocatalysts from BiOX precursors can achieve efficient 2D Bi nanosheets for CO2 reduction reaction, improving formate selectivity and stability, potentially due to more exposed active sites and enhanced electrochemical active areas.

JOURNAL OF CO2 UTILIZATION (2021)

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Article Chemistry, Multidisciplinary

Sn-Doped Bi2O3 nanosheets for highly efficient electrochemical CO2 reduction toward formate production

Xiao Li et al.

Summary: An Sn-doped Bi2O3 nanosheet electrocatalyst has been developed for efficient electrochemical reduction of CO2 to formate, exhibiting high catalytic activity and selectivity in the H-cell. The synergistic effect between Sn and Bi enhances the adsorption capacity of intermediates and improves the activity for formate production. Additionally, coupling with a dimensionally stable anode enables battery-driven CO2 reduction and oxygen evolution reactions with decent activity and efficiency.

NANOSCALE (2021)

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Article Chemistry, Multidisciplinary

Engineering a conductive network of atomically thin bismuthene with rich defects enables CO2 reduction to formate with industry-compatible current densities and stability

Min Zhang et al.

Summary: The self-supported large-size three-dimensional porous conductive network of bismuthene shows outstanding performance in the electrochemical CO2 reduction reaction, efficiently producing formate and maintaining high stability under high current density conditions.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Facile treatment tuning the morphology of Pb with state-of-the-art selectivity in CO2 electroreduction to formate

Weiting Yu et al.

Summary: A facile treatment was used to modify commercial irregular shaped polycrystalline Pb into well-defined octahedral Pb with unique Pb(111) facets, leading to efficient, selective, and stable electrochemical reduction of CO2 toward formate. The enhanced catalytic performance on the treated Pb electrode is attributed to the electrode morphology characterized by a unique Pb(111) surface with lower Gibbs free energies for the formation of intermediate OCHO*.

CHEMICAL COMMUNICATIONS (2021)

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Article Materials Science, Multidisciplinary

Ce-doped Bi based catalysts for highly efficient electroreduction of CO2 to formate

De-Huang Zhuo et al.

Summary: Ce-Bi@CeBiOx/C with core-shell structure was synthesized by pyrolysis of cerium doped bismuth-based metal-organic frameworks. This novel catalyst exhibits excellent performance for electrochemical CO2 reduction to formate, attributed to the synergistic effects of electronic structure modification of Bi as well as the enrichment of oxygen vacancies on catalyst surfaces.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

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Review Chemistry, Multidisciplinary

Gas diffusion electrodes (GDEs) for electrochemical reduction of carbon dioxide, carbon monoxide, and dinitrogen to value-added products: a review

Hesamoddin Rabiee et al.

Summary: Electrochemical reduction of gaseous feeds such as CO2, CO, and N-2 holds promise for sustainable energy and chemical production. Gas diffusion electrodes (GDEs) maintain a high gas concentration in the vicinity of the catalyst and improve mass transport, resulting in higher current densities. However, challenges exist in tuning product selectivity and reaction stability in the GDE environment, requiring further research and development of solutions.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Review Chemistry, Multidisciplinary

Regulating the oxidation state of nanomaterials for electrocatalytic CO2 reduction

Zhi-Zheng Wu et al.

Summary: Electrochemical carbon dioxide reduction reaction (CO2RR) converts CO2 into value-added chemicals and fuels, addressing renewable energy shortage and environmental pollution. Regulating the oxidation state of catalysts has been identified as an effective method for designing high-performing CO2RR catalysts that can influence catalyst activity and selectivity.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Review Chemistry, Multidisciplinary

CO2 valorisation towards alcohols by Cu-based electrocatalysts: challenges and perspectives

Hilmar Guzman et al.

Summary: This review discusses recent advances in electrochemical transformation of CO2 to alcohols, with a focus on copper-based electrocatalysts. Various factors affecting reaction activity and selectivities are considered. The review provides insights into the challenges and outlook for practical applications of this technology.

GREEN CHEMISTRY (2021)

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Review Chemistry, Multidisciplinary

Engineering the atomic arrangement of bimetallic catalysts for electrochemical CO2 reduction

Linfeng Xie et al.

Summary: This review article summarizes recent advances, challenges, and opportunities in developing bimetallic catalysts for electrochemical CO2 reduction reactions. It focuses on engineering the atomic arrangement of bimetallic nanocatalysts to improve catalytic performance and discusses the correlations between structures and catalytic properties. The article also provides a perspective on future research directions, emphasizing current challenges and opportunities.

CHEMICAL COMMUNICATIONS (2021)

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Article Chemistry, Multidisciplinary

Flexible synthesis of Au@Pd core-shell mesoporous nanoflowers for efficient methanol oxidation

Shuli Yin et al.

Summary: A flexible method was reported to synthesize Au@Pd core-shell mesoporous nanoflowers with excellent electrocatalytic activity and stability for methanol oxidation reaction. This versatile strategy can be used for the fabrication of core-shell mesoporous nanoflowers with adjustable composition.

NANOSCALE (2021)

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Review Chemistry, Physical

Electrochemical reduction of carbon dioxide (CO2): bismuth-based electrocatalysts

Yayu Guan et al.

Summary: This review comprehensively examines the recent development of bismuth-based ERCO2 catalysts, focusing on catalyst material design, synthesis, reaction mechanisms, and performance validation/optimization. Various influencing factors on the catalytic performance are discussed and analyzed, and the main technical challenges and future research directions for Bi-based electrocatalysts are proposed.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Engineering, Chemical

Novel Bi, BiSn, Bi2Sn, Bi3Sn, and Bi4Sn Catalysts for Efficient Electroreduction of CO2 to Formic Acid

Qingqing Li et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2020)

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Article Multidisciplinary Sciences

Bismuthene for highly efficient carbon dioxide electroreduction reaction

Fa Yang et al.

NATURE COMMUNICATIONS (2020)

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Review Multidisciplinary Sciences

Strategies in catalysts and electrolyzer design for electrochemical CO2 reduction toward C2+ products

Lei Fan et al.

SCIENCE ADVANCES (2020)

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Article Multidisciplinary Sciences

Chloroplast-like porous bismuth-based core-shell structure for high energy efficiency CO2 electroreduction

Yi-Rong Wang et al.

SCIENCE BULLETIN (2020)

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Article Chemistry, Physical

Electrocatalytic reduction of CO2 to ethylene and ethanol through hydrogen-assisted C-C coupling over fluorine-modified copper

Wenchao Ma et al.

NATURE CATALYSIS (2020)

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Article Chemistry, Multidisciplinary

Novel Bi-Doped Amorphous SnOx Nanoshells for Efficient Electrochemical CO2 Reduction into Formate at Low Overpotentials

Qi Yang et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Physical

Boosting formate production at high current density from CO2 electroreduction on defect-rich hierarchical mesoporous Bi/Bi2O3 junction nanosheets

Dan Wu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Article Multidisciplinary Sciences

Electrochemical CO2 reduction to high-concentration pure formic acid solutions in an all-solid-state reactor

Lei Fan et al.

NATURE COMMUNICATIONS (2020)

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Article Chemistry, Multidisciplinary

Bi@Sn Core–Shell Structure with Compressive Strain Boosts the Electroreduction of CO 2 into Formic Acid

Yulin Xing et al.

Advanced Science (2020)

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Review Chemistry, Multidisciplinary

Catalyst-electrolyte interface chemistry for electrochemical CO2 reduction

Young Jin Sa et al.

CHEMICAL SOCIETY REVIEWS (2020)

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Article Chemistry, Physical

Catalytic mechanism for selective hydrogen production based on formate decomposition with polyvinylpyrrolidone-dispersed platinum nanoparticles

Yusuke Minami et al.

SUSTAINABLE ENERGY & FUELS (2020)

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Article Electrochemistry

Bi nanoparticles/Bi2O3 nanosheets with abundant grain boundaries for efficient electrocatalytic CO2 reduction

Le Li et al.

ELECTROCHIMICA ACTA (2019)

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Article Chemistry, Multidisciplinary

Enhanced Electrocatalytic Reduction of CO2 via Chemical Coupling between Indium Oxide and Reduced Graphene Oxide

Zhirong Zhang et al.

NANO LETTERS (2019)

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Review Chemistry, Multidisciplinary

Progress and Perspectives of Electrochemical CO2 Reduction on Copper in Aqueous Electrolyte

Stephanie Nitopi et al.

CHEMICAL REVIEWS (2019)

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Review Nanoscience & Nanotechnology

Advances in Sn-Based Catalysts for Electrochemical CO2 Reduction

Shulin Zhao et al.

NANO-MICRO LETTERS (2019)

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Article Electrochemistry

Surface Modification of Tin Dioxide via (Bi, S) Co-Doping for Photoelectrocatalytic Reduction of CO2 to Formate

Yupeng Li et al.

CHEMELECTROCHEM (2019)

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Article Chemistry, Physical

Spin-Orbit Coupling-Dominated Catalytic Activity of Two-Dimensional Bismuth toward CO2 Electroreduction: Not the Thinner the Better

Yu Wang et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2019)

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Article Energy & Fuels

Continuous production of pure liquid fuel solutions via electrocatalytic CO2 reduction using solid-electrolyte devices

Chuan Xia et al.

NATURE ENERGY (2019)

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Article Nanoscience & Nanotechnology

Bi-Doped SnO Nanosheets Supported on Cu Foam for Electrochemical Reduction of CO2 to HCOOH

Xiaowei An et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Electrochemistry

Direct synthesis of bismuth nanosheets on a gas diffusion layer as a high-performance cathode for a coupled electrochemical system capable of electroreduction of CO2 to formate with simultaneous degradation of organic pollutants

Qinian Wang et al.

ELECTROCHIMICA ACTA (2019)

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Article Chemistry, Multidisciplinary

Cu3N Nanocubes for Selective Electrochemical Reduction of CO2 to Ethylene

Zhouyang Yin et al.

NANO LETTERS (2019)

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Article Multidisciplinary Sciences

Advantages of eutectic alloys for creating catalysts in the realm of nanotechnology-enabled metallurgy

Jianbo Tang et al.

NATURE COMMUNICATIONS (2019)

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Article Chemistry, Multidisciplinary

Copper atom-pair catalyst anchored on alloy nanowires for selective and efficient electrochemical reduction of CO2

Jiqing Jiao et al.

NATURE CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

Nature of Oxygen-Containing Groups on Carbon for High-Efficiency Electrocatalytic CO2 Reduction Reaction

Fa Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Multidisciplinary

Efficient and Robust Carbon Dioxide Electroreduction Enabled by Atomically Dispersed Snδ+ Sites

Xiaolong Zu et al.

ADVANCED MATERIALS (2019)

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Article Chemistry, Multidisciplinary

Bismuth oxyiodide microflower-derived catalysts for efficient CO2 electroreduction in a wide negative potential region

Peng Fei Liu et al.

CHEMICAL COMMUNICATIONS (2019)

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Article Chemistry, Physical

3D hierarchical porous indium catalyst for highly efficient electroreduction of CO2

Wen Luo et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Chemistry, Multidisciplinary

Facile synthesis of a bismuth nanostructure with enhanced selectivity for electrochemical conversion of CO2 to formate

Peilong Lu et al.

NANOSCALE (2019)

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Article Chemistry, Multidisciplinary

Electrochemical exfoliation from an industrial ingot: ultrathin metallic bismuth nanosheets for excellent CO2 capture and electrocatalytic conversion

Dan Wu et al.

NANOSCALE (2019)

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Tunable and Efficient Tin Modified Nitrogen-Doped Carbon Nanofibers for Electrochemical Reduction of Aqueous Carbon Dioxide

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Selective electroreduction of CO2 to formate on Bi and oxide-derived Bi films

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Enhancing CO2 electrolysis to formate on facilely synthesized Bi catalysts at low overpotential

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