☆ 4.8 Review

Porphyrins and phthalocyanines as biomimetic tools for photocatalytic H2 production and CO2 reduction

CHEMICAL SOCIETY REVIEWS (2022)

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Article Chemistry, Physical

Enhanced cocatalyst-free photocatalytic H2 evolution by the synergistic AIE and FRET for an Ir-complex conjugated porphyrin

Kailin Zheng et al.

Summary: A new ZnP-T-Ir photosensitizer, in which a T-Ir complex is conjugated to a porphyrin ring via a phenylene linkage, exhibits high efficiency in photocatalytic hydrogen evolution. The high efficiency can be attributed to the conjugation of the T-Ir moiety, along with the synergistic effect of aggregation-induced emission, inhibition of aggregation caused by quenching, and Forster resonance energy transfer.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Article Chemistry, Physical

Phenoxazine-Sensitized CO2-to-CO Reduction with an Iron Porphyrin Catalyst: A Redox Properties-Catalytic Performance Study

Martin Kientz et al.

Summary: We have evaluated six phenoxazine derivatives as visible light photosensitizers for the photochemical reduction of CO2 to CO with an iron porphyrin catalyst in organic media. The phenoxazine core was functionalized with electron-donating or -withdrawing groups to modify the photophysical properties. Our observation shows that there is no correlation between the production of CO and the excited state potential of the phenoxazine, but a clear correlation can be made between the oxidation potentials of the phenoxazine and the production of CO. This indicates that the process was limited by photosensitizer regeneration and that electron transfers not directly related to the catalyst activation could play a key role in homogeneous photocatalytic systems.

CHEMPHOTOCHEM (2022)

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Article Nanoscience & Nanotechnology

Rapid Exciton Migration and Amplified Funneling Effects of Multi-Porphyrin Arrays in a Re(I)/Porphyrinic MOF Hybrid for Photocatalytic CO2 Reduction

Sunghan Choi et al.

Summary: This study presents a novel porphyrinic metal-organic framework-Re(I) hybrid photocatalyst with high catalytic activity achieved through efficient exciton migration and funneling, as supported by serial photophysical measurements including decisive Stern-Volmer interpretation.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Physical

A Durable Metalloporphyrin 2D-Polymer for Photocatalytic Hydrogen and Oxygen Evolution from River and Sea Waters

Kayaramkodath Chandran Ranjeesh et al.

Summary: This study demonstrates the feasibility of solar seawater splitting through the design of a two-dimensional polymer catalyst and showcases its advantages in long-term stability and cycling performance.

CHEMCATCHEM (2021)

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Article Chemistry, Multidisciplinary

Controlling Solar Hydrogen Production by Organizing Porphyrins

Vasilis Nikolaou et al.

Summary: In this study, a highly efficient photocatalytic system for H-2 production is developed using porphyrins as photocatalysts. Self-organization of PdTCP and PtTCP into H- and J-aggregates on TiO2 NPs is crucial for H-2 evolution, with J-aggregated PtTCPs showing higher efficiency than H-aggregated PdTCPs. The simultaneous adsorption of PdTCP and PtTCP onto TiO2 NPs results in the most efficient catalytic system, achieving high turnover numbers.

CHEMSUSCHEM (2021)

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Article Chemistry, Inorganic & Nuclear

Synthesis and Characterization of a Covalent Porphyrin-Cobalt Diimine-Dioxime Dyad for Photoelectrochemical H2 Evolution

Asterios Charisiadis et al.

Summary: This study reports the synthesis and full characterization of the first covalently linked porphyrin-cobalt diimine-dioxime dyad (ZnP-Co), which was used to sensitize NiO films and evaluate the H2-evolving photoelectrochemical activity. The modest performances of the system could be explained through photolysis and post-operando characterizations, providing some guidelines for designing more efficient porphyrin-based assemblies.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Effect of Li ions doping into p-type semiconductor NiO as a hole injection/transfer medium in the CO2 reduction sensitized/catalyzed by Zn-porphyrin/Re-complex upon visible light irradiation

Ryosuke Nakazato et al.

Summary: The study utilized a molecular catalyst sensitized system (MCSS) to catalyze the photoreduction of CO2 into CO on a p-type semiconductor NiO. Results showed that doping of Li ions could enhance the conductivity of NiO, and within a certain range, promote the photoreduction of CO2.

RESEARCH ON CHEMICAL INTERMEDIATES (2021)

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Article Chemistry, Physical

Device Performance of Emerging Photovoltaic Materials (Version 1)

Osbel Almora et al.

Summary: Emerging photovoltaics such as organic, dye-sensitized, and perovskite solar cells focus on various applications including building integration, greenhouses, wearable technology, and indoor use. Resources like the National Renewable Energy Laboratory chart and biannual efficiency tables compiled by Martin Green provide valuable information on research cell efficiencies. This alternative approach summarizes the best reports in diverse research subjects for emerging PVs, providing performance parameters as a function of the photovoltaic bandgap energy for each technology and application.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Physical

Enhancing CO2 Electrocatalysis on 2D Porphyrin-Based Metal-Organic Framework Nanosheets Coupled with Visible-Light

Yue Zhou et al.

Summary: A series of single metal atoms anchored 2D metal-organic framework nanosheets were fabricated, showing enhanced CO2 reduction activity and selectivity with the assistance of visible-light. Among them, MOF-NS-Co achieved a CO Faradaic efficiency of 98.7%, displaying excellent catalytic performance.

SMALL METHODS (2021)

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Article Chemistry, Multidisciplinary

Porphyrin Conjugated Polymer with Periodic Type II-Like Heterojunctions and Single-Atom Catalytic Sites for Broadband-Responsive Hydrogen Evolution

Jinming Wang et al.

Summary: A novel heterometallic Zn-/Co-porphyrin conjugated polymer (ZnCoP-F CP) with a Co-porphyrin bridging unit bearing two perfluorophenyls is synthesized via a Sonogashira coupling reaction. The enhanced performance of ZnCoP-F CP is attributed to the high electron-withdrawing capacity of its perfluorophenyls and the highly dispersed Co centers in Co-porphyrin bridging units. Broadband-responsive feature of ZnCoP-F CP is due to the large pi-conjugated system throughout the 2D internal framework of the porphyrin polymer.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Quantum Dot-Sensitized Photoreduction of CO2 in Water with Turnover Number > 80,000

Francesca Arcudi et al.

Summary: This study demonstrates the highly efficient catalytic photoreduction of CO2 to CO in pure water using CuInS2 colloidal quantum dots and Co-porphyrin catalyst. The breakthrough efficiency achieved represents a nonincremental step towards the realization of reaction networks for direct solar-to-fuel conversion.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Review Chemistry, Inorganic & Nuclear

An exciting twenty-year journey exploring porphyrinoid-based photo- and electro-active systems

Giovanni Bottari et al.

Summary: This review highlights the collaborative efforts of the Torres and Guldi groups in preparing and studying porphyrinoid-based photo- and electro-active systems. The deep knowledge of porphyrinoid chemistry and advanced carbon allotropes from the Spanish team, along with the expertise in photophysical characterization and charge management from the German group, has led to significant advancements in fields such as optoelectronics and solar energy conversion.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Chemistry, Applied

Photoelectrochemical properties of dyads composed of porphyrin/ruthenium catalyst grafted on metal oxide semiconductors

Asterios Charisiadis et al.

Summary: In this study, four different porphyrin-ruthenium dyads were utilized as sensitizers in both nand p-type DSSCs and DSPECs, demonstrating that dyads with ruthenium complexes exhibit improved performance in both systems.

DYES AND PIGMENTS (2021)

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Article Chemistry, Inorganic & Nuclear

Porphyrin-Based Metal-Organic Frameworks for Efficient Photocatalytic H2 Production under Visible-Light Irradiation

Chenxiang Lin et al.

Summary: A series of porphyrin-based zirconium MOFs were explored for photocatalytic H-2 production, with MOF containing more uniformly dispersed Pt2+ ions showing the highest H-2 evolution reaction rate under visible-light irradiation. The differences in photocatalytic activity were attributed to efficient charge transfer from photosensitizers to catalytic centers in MOF materials.

INORGANIC CHEMISTRY (2021)

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Article Chemistry, Physical

Phosphorous doped g-C3N4 supported cobalt phthalocyanine: An efficient photocatalyst for reduction of CO2 under visible-light irradiation

Gang Liu et al.

Summary: In this study, phosphorous doped graphitic carbon nitride (P-g-C3N4) sensitized by cobalt phthalocyanine complex was successfully synthesized for the efficient photoreduction of CO2 into CO under visible-light irradiation. The hybrid photocatalyst exhibited high efficiency and stability, with a by-product of low concentration hydrogen identified.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Article Chemistry, Inorganic & Nuclear

Gadolinium porphyrinate double-deckers for visible light driven H2 evolution

Emmanouil Nikoloudakis et al.

Summary: The study found that the double decker structure is essential for the photocatalytic activity of gadolinium porphyrin complexes, and different supramolecular architectures do not affect the photocatalytic activity of the complexes.

POLYHEDRON (2021)

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Article Chemistry, Multidisciplinary

Metal-organic frameworks embedded in a liposome facilitate overall photocatalytic water splitting

Huihui Hu et al.

Summary: By confining MOFs that can promote each half-reaction within liposomal structures and achieving efficient charge separation, overall photocatalytic water splitting has been successfully achieved. The assembly demonstrates ultrafast electron transport and efficient charge separation, resulting in a quantum yield of (1.5 +/- 1)%.

NATURE CHEMISTRY (2021)

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Article Biochemistry & Molecular Biology

High selective photocatalytic CO2 conversion into liquid solar fuel over a cobalt porphyrin-based metal-organic framework

N. Sadeghi et al.

Summary: In this study, Co/PMOF was synthesized and characterized, showing longer lifetime of photo-generated charge carriers and higher activity in CO2 photoconversion than porphyrin. The high selectivity, stability, and reusability of Co/PMOF for CO2 photoreduction were demonstrated, implying great potential for assembly porphyrin and cobalt into MOFs for CO2 photoreduction.

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES (2021)

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Article Multidisciplinary Sciences

Rational design of isostructural 2D porphyrin-based covalent organic frameworks for tunable photocatalytic hydrogen evolution

Rufan Chen et al.

Summary: Covalent organic frameworks show promise in photocatalytic hydrogen generation from water, with the incorporation of different transition metals allowing for tuning of the hydrogen evolution rate.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Multidisciplinary

Au-Modulated Z-Scheme CuPc/BiVO4 Nanosheet Heterojunctions toward Efficient CO2 Conversion under Wide-Visible-Light Irradiation

Ji Bian et al.

Summary: This study successfully fabricated ultrafine Au-modulated copper phthalocyanine/BiVO4 nanosheet heterojunctions with enhanced photocatalytic activity for CO2 conversion, attributed to the efficient electron migration induced by Au interfacial modulation and strengthened Z-scheme charge transfer and separation.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

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Article Chemistry, Physical

Construction of hierarchical ZnIn2S4@PCN-224 heterojunction for boosting photocatalytic performance in hydrogen production and degradation of tetracycline hydrochloride

Pengxia Jin et al.

Summary: The study demonstrates the synthesis of a hierarchical structured ZnIn2S4@PCN-224 composite, which shows enhanced photocatalytic activity and stable performance under visible-light irradiation. The establishment of a Z-scheme junction between ZnIn2S4 and PCN-224 contributes to the significant improvement in photocatalysis.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Article Polymer Science

Porphyrin-Based Conjugated Polyelectrolytes for Efficient Photocatalytic Hydrogen Evolution

Xin Zhao et al.

Summary: This study designed a series of porphyrin-based conjugated polyelectrolytes (CPEs) with different coordinated metals for efficient photocatalytic hydrogen evolution. The incorporation of Pt atoms significantly improved the photocatalytic performance, allowing the material to achieve high hydrogen production efficiency without the assistance of co-catalysts.

MACROMOLECULES (2021)

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Article Multidisciplinary Sciences

Promoting photocatalytic CO2 reduction with a molecular copper purpurin chromophore

Huiqing Yuan et al.

Summary: Designing highly efficient chromophores comprising earth-abundant elements is essential for both light harvesting and electron transfer reactions. Here, authors prepare a copper purpurin complex that shows enhanced photocatalytic activity for CO2 reduction to CO with a high selectivity.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Multidisciplinary

Visible-Light Driven CO2 Reduction to Formate with Electron Mediated Nicotinamide-Modified Viologen in the System of Water-Soluble Zinc Porphyrin and Formate Dehydrogenase

Akimitsu Miyaji et al.

Summary: The study investigated the visible-light driven CO2 reduction to formate using a system consisting of ZnTPPS, CbFDH, and NEMBP, with TEOA as an electron donor. NEMBP, as a co-enzyme for CbFDH, showed an 80% yield in reduction. The turnover numbers of NEMBP and CbFDH in the CO2 reduction system were estimated to be 0.14 and 1.53 h(-1) respectively.

CHEMNANOMAT (2021)

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Article Chemistry, Physical

A Mo2-ZnP molecular device that mimics photosystem I for solar-chemical energy conversion

Xiao Liu et al.

Summary: The study demonstrates a molecular photocatalyst integrating zinc porphyrin with a quadruply-bonded Mo-2 unit, capable of efficiently catalyzing hydrogen evolution from water under visible light and mimicking enzymatic reduction in natural photosynthesis. The insights gained from this research are valuable for engineering photocatalysts for solar fuel production.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Article Chemistry, Applied

Effective visible-light CO2 photoreduction over (metallo)porphyrin-based metal-organic frameworks to achieve useful hydrocarbons

Roya Hariri et al.

Summary: Metalloporphyrin-based MOFs, PCN-222(M), have been shown to be efficient photocatalysts for converting CO2 into valuable chemicals. The metalloporphyrinic MOFs exhibit high stability and enhanced CO2 reduction compared to nonmetal porphyrinic MOFs.

APPLIED ORGANOMETALLIC CHEMISTRY (2021)

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Article Chemistry, Physical

In-situ synthesized porphyrin polymer/TiO2 composites as high-performance Z-scheme photocatalysts for CO2 conversion

Yue Zhang et al.

Summary: In this study, TiO2 nanoparticles were composited with covalent porphyrin polymers to enhance the photocatalytic activity of CO2 conversion. The composite of sulfonated hollow COP-P and TiO2 showed the best performance with a CO production rate of 5.70 μmol.g(-1).h(-1). A Z-scheme photocatalytic mechanism was proposed to explain the working principle of the composite material.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Article Chemistry, Inorganic & Nuclear

Hydroxylporphyrin/NiO nanosheet nanocomposite with strong interfacial interaction for highly efficient hydrogen generation

Mengya Xi et al.

Summary: The study on THPP/NiO nanosheet photocatalysts revealed that the special coordination interaction between THPP and NiO significantly influences the photocatalytic performance, and controlling the interaction between the two can achieve a photocatalyst with high and stable photocatalytic activity. This provides a new concept for fabricating highly efficient photocatalysts for hydrogen production.

JOURNAL OF SOLID STATE CHEMISTRY (2021)

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Article Chemistry, Physical

Earth-Abundant Photocatalytic CO2 Reduction by Multielectron Chargeable Cobalt Porphyrin Catalysts: High CO/H2 Selectivity in Water Based on Phase Mismatch in Frontier MO Association

Xian Zhang et al.

Summary: Efforts have been made to reduce CO2 emissions through photocatalytic and electrocatalytic CO2 reduction into fuels. A recent study focuses on developing environmentally friendly photo-catalytic systems, using non-precious-metal molecular CO2 reduction catalysts in aqueous conditions, and suppressing hydrogen evolution during CO2 reduction.

ACS CATALYSIS (2021)

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Article Chemistry, Physical

Supramolecular Zinc Porphyrin Photocatalyst with Strong Reduction Ability and Robust Built-In Electric Field for Highly Efficient Hydrogen Production

Jianfang Jing et al.

Summary: The ultrathin 2D self-assembled tetrakis (4-carboxyphenyl) zinc porphyrin (SA-ZnTCPP) is successfully fabricated for photocatalytic hydrogen production, showing 85 times increase in H-2 evolution rate compared to metal-free self-assembled tetrakis (4-carboxyphenyl) porphyrin (SA-TCPP). The enhanced photocatalytic activity of SA-ZnTCPP is attributed to the deep conduction band contributed by Zn2+ coordination and the strong built-in electric field that boosts the separation and mobility of photogenerated carriers.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Self-Assembly of Porphyrin Dipeptide Conjugates toward Hydrogen Production

Emmanouil Nikoloudakis et al.

Summary: In this research, diphenylalanine dipeptide was covalently attached to a tripyridyl porphyrin macrocycle, imparting self-assembling properties to the resulting hybrid used for non-noble metal photocatalytic hydrogen evolution studies. The self-assembling nanostructures of the hybrid were found to enhance hydrogen production in the photocatalytic system. This was supported by fluorescence and transient absorption experiments shedding light on electron transfer processes during photocatalysis.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

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Article Chemistry, Multidisciplinary

Construction of dual ligand Ti-based MOFs with enhanced photocatalytic CO2 reduction performance

Siyuan Chen et al.

Summary: In this study, Zn(II) porphyrin was used to coordinate with titanium oxo clusters to enhance the photoelectric conversion ability and CO2 adsorption capacity of NH2-MIL125(Ti), leading to an 11-fold increase in CO2/CO conversion efficiency.

JOURNAL OF CO2 UTILIZATION (2021)

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Article Chemistry, Physical

Antenna Effect in BODIPY-(Zn)Porphyrin Entities Promotes H2 Evolution in Dye-Sensitized Photocatalytic Systems

Vasilis Nikolaou et al.

Summary: This study utilizes BODIPY-(Zn)Porphyrin hybrids as photosensitizers for photocatalytic hydrogen production from water, comparing the impact of different connectivity on catalytic activity. Covalently connected dyad BDP-Por demonstrated higher catalytic activity compared to axially coordinated BDP(Im)-Por, with the introduction of an additional BDP(Im) moiety leading to further enhanced performance in dye-sensitized photocatalytic systems.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Chemistry, Physical

Improving the Photocatalytic Hydrogen Generation Using Nonaggregated Zinc Phthalocyanines

Eminegul Genc Acar et al.

Summary: Compared to traditional solar cells, dye-sensitized photocatalytic systems are attractive artificial photosynthesis mechanisms due to their low cost and easy fabrication. The presence of a cocatalyst greatly enhances the hydrogen generation efficiency of ZnPc-1/TiO2 and ZnPc-2/TiO2 photocatalysts. Density functional theory (DFT) studies reveal the structural differences between ZnPc-1 and ZnPc-2, shedding light on their distinct photocatalytic activities.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Imidazole substituted Zinc(ii) phthalocyanines for co-catalyst-free photoelectrochemical and photocatalytic hydrogen evolution: influence of the anchoring group

A. Celil Yuzer et al.

Summary: Novel zinc phthalocyanine derivatives with different numbers of imidazole units were synthesized and utilized as photosensitizers for photocatalytic H-2 evolution. The presence of one imidazole unit in ZnPc-1/TiO2 showed the best photoactivity with a high H-2 evolution rate, turnover number, and solar-to-hydrogen energy conversion efficiency.

CHEMICAL COMMUNICATIONS (2021)

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Review Chemistry, Multidisciplinary

Dye-sensitized solar cells strike back

Ana Belen Munoz-Garcia et al.

Summary: Dye-sensitized solar cells (DSCs) and dye-sensitized photoelectrochemical cells (DSPECs) have seen a revival in recent years as they offer unique properties such as low cost, non-toxic materials, colorfulness, transparency, and efficiency in low light conditions. This review covers advancements in DSC technology over the past decade, including theoretical studies, characterization techniques, materials, applications, and commercialization efforts by various companies.

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Coupling of a new porphyrin photosensitizer and cobaloxime cocatalyst for highly efficient photocatalytic H2 evolution

Govardhana Babu Bodedla et al.

Summary: ZnDC(p-NI)PP is an efficient and effective photocatalytic hydrogen evolution system with significantly improved performance compared to other common PS. This is achieved through mechanisms of intramolecular energy transfer and electrostatic force promoting rapid electron transfer.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Incorporating porphyrin-Pt in light-harvesting metal-organic frameworks for enhanced visible light-driven hydrogen production

Huihui Hu et al.

Summary: A molecular catalyst [(TCPP)Pt-II] was reported for H-2 evolution, with chloranilic acid as a sacrificial electron donor, and integration into a light-harvesting network significantly increased its activity by about 830 times.

CHINESE JOURNAL OF CATALYSIS (2021)

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Visible-light driven reduction of CO2 to formate by a water-soluble zinc porphyrin and formate dehydrogenase system with electron-mediated amino and carbamoyl group-modified viologen

Akimitsu Miyaji et al.

Summary: The study explored the visible-light-driven CO2 reduction to formate using a system with ZnTPPS, CbFDH, ACBP, and TEOA, with high affinity and interaction between ACBP and CbFDH demonstrated through photochemical and electrochemical approaches. The reduction yield of ACBP to ACBP(+center dot) was estimated to be over 95% under visible-light conditions, with turnover numbers of 0.17 and 15.2 h(-1) for ACBP and CbFDH in the system, respectively.

NEW JOURNAL OF CHEMISTRY (2021)

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Photocatalytic hydrogen production of porphyrin nanostructures: spheres vs. fibrils, a case study

Vasilis Nikolaou et al.

Summary: In this study, a covalently connected peptide-porphyrin hybrid was prepared and found to self-assemble into either spheres or fibrils depending on the solvent mixture. Photocatalytic hydrogen evolution experiments showed that fibrils were more efficient in H-2 production compared to spheres.

CHEMICAL COMMUNICATIONS (2021)

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The effect of bulky electron-donating thioether substituents on the performances of phthalocyanine based dye sensitized solar cells

Mine Ince et al.

Summary: Incorporation of sulfur atoms onto zinc-phthalocyanine molecules led to a red shift in the absorption spectrum and decreased solar cell performance, likely due to the symmetrical electronic structure and lower excited state level caused by sulfur atoms.

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Supramolecular strategies in artificial photosynthesis

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Summary: Artificial photosynthesis aims to convert solar power into chemical fuel for sustainable energy production, with three fundamental steps including light harvesting, charge-separation, and redox catalysis. Supramolecular chemistry, with its ability to control molecular components precisely through self-assembly processes, can provide important tools for preparing, integrating, and optimizing artificial photosynthetic devices.

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A novel copper-bridged graphitic carbon nitride/porphyrin nanocomposite with dramatically enhanced photocatalytic hydrogen generation

Kun Zhu et al.

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Bias-free solar syngas production by integrating a molecular cobalt catalyst with perovskite-BiVO4 tandems

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Controlled synthesis of novel Z-scheme iron phthalocyanine/porous WO3 nanocomposites as efficient photocatalysts for CO2 reduction

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Naphthalimide-porphyrin hybridized graphitic carbon nitride for enhanced photocatalytic hydrogen production

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Efficient hybrid solar-to-alcohol system via synergistic catalysis between well-defined Cu-N4 sites and its sulfide (CuS)

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Fabrication of antennae-like nanoheterostructure attached by porphyrin for increased photocatalytic hydrogen generation and electron transfer mechanism

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Covalent Organic Framework Hosting Metalloporphyrin-Based Carbon Dots for Visible-Light-Driven Selective CO2Reduction

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Photocatalytic CO2 Reductions Catalyzed by meso-(1,10-Phenanthrolin-2-yl)-Porphyrins Having a Rhenium(I) Tricarbonyl Complex

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Porous Hybrid Materials Based on Mesotetrakis(Hydroxyphenyl) Porphyrins and TiO2for Efficient Visible-Light-Driven Hydrogen Production

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Anchored Cu(II) tetra(4-carboxylphenyl)porphyrin to P25 (TiO2) for efficient photocatalytic ability in CO2 reduction

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Enhanced CO2 photoreduction by a graphene-porphyrin metal-organic framework under visible light irradiation

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Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst

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A Dinuclear Cobalt Cryptate as a Homogeneous Photocatalyst for Highly Selective and Efficient Visible-Light Driven CO2 Reduction to CO in CH3CN/H2O Solution

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Synthesis of bio-inspired mononuclear nickel hydrogen production catalysts and photocatalytic efficiency improvement with porphyrin covalently functionalized graphene nanohybrid

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Construction of a Noble-Metal-Free Photocatalytic H2 Evolution System Using MoS2/Reduced Graphene Oxide Catalyst and Zinc Porphyrin Photosensitizer

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Development of a dye molecule-biocatalyst hybrid system with visible-light induced carbon-carbon bond formation from CO2 as a feedstock

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A novel electron carrier molecule based on a viologen derivative for visible light-driven CO2 reduction to formic acid with the system of zinc porphyrin and formate dehydrogenase

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Photosensitized H2 generation from one-pot and two-pot assemblies of a zinc-porphyrin/platinum nanoparticle/protein scaffold

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Dye-Sensitized Solar Hydrogen Production: The Emerging Role of Metal-Free Organic Sensitizers

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Visible-light-driven hydrogen production from water in a noble-metal-free system catalyzed by zinc porphyrin sensitized MoS2/ZnO

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Photochemical CO2 Reduction Catalyzed by Phenanthroline Extended Tetramesityl Porphyrin Complexes Linked with a Rhenium(I) Tricarbonyl Unit

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Effect of chemical structure of bipyridinium salts as electron carrier on the visible-light induced conversion of CO2 to formic acid with the system consisting of water-soluble zinc porphyrin and formate dehydrogenase

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A review of iron and cobalt porphyrins, phthalocyanines and related complexes for electrochemical and photochemical reduction of carbon dioxide

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JOURNAL OF PORPHYRINS AND PHTHALOCYANINES (2015)

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A new route for visible/near-infrared-light-driven H2 production over titania: Co-sensitization of surface charge transfer complex and zinc phthalocyanine

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Visible-Light Photoreduction of CO2 in a Metal-Organic Framework: Boosting Electron-Hole Separation via Electron Trap States

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Heterostructured nanocomposite tin phthalocyanine@mesoporous ceria (SnPc@CeO2) for photoreduction of CO2 in visible light

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Photocatalytic H-2 production under visible-light irradiation based on covalent attachment of manganese phthalocyanine to graphene

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Visible/Near-Infrared-Light-Induced H2 Production over g-C3N4 Co-sensitized by Organic Dye and Zinc Phthalocyanine Derivative

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Homogeneous Photocatalytic Reduction of CO2 to CO Using Iron(0) Porphyrin Catalysts: Mechanism and Intrinsic Limitations

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Sterically Hindered Phthalocyanines for Dye-Sensitized Solar Cells: Influence of the Distance between the Aromatic Core and the Anchoring Group

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Visible light-induced reduction of carbon dioxide sensitized by a porphyrin-rhenium dyad metal complex on p-type semiconducting NiO as the reduction terminal end of an artificial photosynthetic system

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Carboxyethynyl Anchoring Ligands: A Means to Improving the Efficiency of Phthalocyanine-Sensitized Solar Cells

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