4.5 Article

MODELING ELECTRODE HETEROGENEITY IN LITHIUM-ION BATTERIES: UNIMODAL AND BIMODAL PARTICLE-SIZE DISTRIBUTIONS

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Fictitious phase separation in Li layered oxides driven by electro-autocatalysis

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Summary: Layered oxides electrodes in lithium-ion batteries are designed to be cycled under conditions avoiding phase transitions, but phase separation during delithiation has been observed, which is shown to be a dynamical artefact occurring in a many-particle system driven by autocatalytic electrochemical reactions.

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