4.6 Article

Solvent-free continuous flow hydrogenation of N-methylpyrrolidone to N-methylpyrrolidine catalyzed by bimetallic Pt/V on HAP

期刊

CATALYSIS SCIENCE & TECHNOLOGY
卷 12, 期 14, 页码 4605-4612

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cy00581f

关键词

-

资金

  1. National Natural Science Foundation of China [21871275]
  2. Natural Science Foundation of Hebei Province [B2019205149]

向作者/读者索取更多资源

In this study, a solvent-free continuous flow bimetallic Pt/V catalytic hydrogenation method for N-methylpyrrolidone (NMP) to prepare N-methylpyrrolidine (NMPD) was developed. The yield of NMPD reached 89.41% under the optimal reaction conditions, and the best catalyst proportion was found to be Pt/V = 1:0.5 on HAP. The catalysts exhibited excellent stability, with a yield of 85.21% even after running for 100 hours.
Herein, solvent-free continuous flow bimetallic Pt/V catalytic hydrogenation of N-methylpyrrolidone (NMP) to prepare N-methylpyrrolidine (NMPD) was developed. The yield of NMPD was as high as 89.41%, and the best weight hourly space velocity was 1.2 h(-1) under the optimal reaction conditions, which were screened by the response surface methodology. The catalysts with different ratios of Pt and V supported on hydroxyapatite (HAP) were prepared and evaluated for activity for the hydrogenation of NMP. The best catalyst proportion was Pt/V = 1 : 0.5 on HAP, which was characterized by STEM-EDS, ICP-OES, BET, XPS, and PSD analyses. It was shown that polyvalent Pt and V were highly dispersed on HAP and the synergistic effect between Pt and V species contributed to the excellent catalytic performance. More importantly, the catalyst stability was excellent and after running for 100 h, the yield remained at 85.21%. Significantly, this solvent-free continuous flow catalytic hydrogenation of an amide provides a green, efficient, low-cost and environmentally friendly process for the synthesis of NMPD.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据