4.7 Review

Advances and challenges in user-friendly alkyne metathesis catalysts

期刊

TRENDS IN CHEMISTRY
卷 4, 期 6, 页码 540-553

出版社

CELL PRESS
DOI: 10.1016/j.trechm.2022.03.004

关键词

-

资金

  1. National Science Foundation [CHE-2108197]
  2. Natural Science Foundation of Shandong Province [ZR2021MB033]
  3. Innovative Research Programs of Higher Education of Shandong Province [2019KJC009]
  4. Incubation Program of Youth Innovation of Shandong Province

向作者/读者索取更多资源

Alkyne metathesis (AM), a relative of alkene metathesis, has gained significant attention and is widely used in the synthesis of natural products, functional polymers, and molecular architectures. This article focuses on the rational design of catalysts, substrate structures, and reaction conditions to meet specific metathesis pathways and make the catalytic systems more user-friendly and practical.
Alkyne metathesis (AM), the cousin of the 'noble' alkene metathesis, has attracted rapidly growing attention within the past 20 years and has been widely used in the synthesis of natural products, functional polymers, and shapepersistent molecular architectures. Given some excellent reviews in recent years, this article will not provide a comprehensive review of the catalyst development and the wide applications of AM, but rather will focus on the rational design of the catalysts, substrate structures, and reaction conditions that meet the requirements of certain metathesis pathways (e.g., cyclooligomerization, polymerization, self-correction) and will make the catalytic systems more userfriendly and practically useful (e.g., operating in air and with long lifetimes and broad substrate scope).

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据