期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 10, 期 24, 页码 13066-13073出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ta03368b
关键词
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资金
- NSF of China [12174349, 12074345]
- Henan provincial key science and technology research project [212102210130]
This research establishes a synergetic charge transfer mechanism between periodically confined d-block catalytic sites and p-block non-metal elements in a two-dimensional metal-organic framework. This mechanism can be used for efficient catalysis of oxygen and carbon monoxide reactions and has implications for designing low-cost hybrid catalyst systems.
Benefiting from the merits of d-block and p-block elemental single-atom catalysts (SACs), p-d hybridized SACs with atomically dispersed d-block catalytic sites periodically confined within the p-block-element represent a distinct development in the realm of highly efficient and low-cost SACs, which can not only effectively stabilize the single-atom reactive sites from clustering, but also practically maximize the utilization of the metal atoms to 100%. Here, based on density functional theorycalculations, taking two-dimensional metal-organic frameworks (2D-MOFs) TM3(C6O6)(2) (TM = Cr, Mn, Fe, Co, Ni, Cu, Mo, Ru, Rh, Pd, Ag, Pt, Au) as typical examples for p-d hybridized SAC platforms, we establish an intriguing synergetic charge transfer mechanism involved among the periodically confined d-block hosting TM active sites and p-block non-metal elements in the MOF structure for O-2 activation and CO oxidization. Specifically, for the key step of O-2 adsorption and activation, except for hosting d-block TM active sites, the second-nearest neighbouring p-block C atoms may dominate or donate significant charge via the bridge of the nearest neighbouring substrate O atoms, which effectively reduces the CO oxidization barriers to the range of 0.23-0.60 eV for most TM3(C6O6)(2). These findings are constructive for designing highly efficient and low-cost p- and d-block hybridized SAC systems.
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