4.7 Article

Treatment dependent sodium-rich Prussian blue as a cathode material for sodium-ion batteries

期刊

DALTON TRANSACTIONS
卷 51, 期 25, 页码 9622-9626

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2dt01171a

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资金

  1. National Natural Science Foundation of China [21771166]
  2. Center Plain Science and Technology Innovation Talents [194200510013]
  3. Key R&D and Promotion Special Projects in Henan Province [222102240029, 222102240030]
  4. Natural Science Foundation of Henan Province [222300420581]

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The use of sodium ascorbate solution as the washing solution can effectively suppress the loss of sodium ions and oxidation of Fe2+ during the preparation of Prussian blue analogs (PBAs). As the cathode material for sodium-ion batteries, it exhibits excellent electrochemical performance.
In the preparation of Prussian blue analogs (PBAs), Na+ loss and Fe2+ oxidation take place when washing with water. Sodium-rich PBAs were prepared with sodium ascorbate aqueous solution as the washing solution, which can suppress the Na+ loss and Fe2+ oxidation. As the cathode of sodium-ion batteries, it exhibited excellent electrochemical performance.

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