☆ 3.8 Review

Hydrogen storage in complex hydrides: past activities and new trends

PROGRESS IN ENERGY (2022)

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Summary: The thermodynamic properties of key compounds formed in the release and uptake of hydrogen by magnesium borohydride have been investigated using solid-state density functional theory calculations. The effects of cell-size and zero-point energy corrections on the entropies were analyzed. Experimental validation for the predicted chemical shifts of various compounds was provided. The reversible hydrogen storage characteristics of MgB2H6 and Mg-3(B3H6)(2) were discussed.

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11B Nuclear Spin-Electron Spin Interactions in 11B MAS NMR Spectra of Paramagnetic Metal Borohydrides

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Ca(BH4)2-MgF2 Reversible Hydrogen Storage: Reaction Mechanisms and Kinetic Properties

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In Situ Neutron Diffraction Study of the Deuteration of Isotopic Mg11B2

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Effect of Transition Metal Fluorides on the Sorption Properties and Reversible Formation of Ca(BH4)2

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Hydrogen storage properties of Mg(x)Fe (x: 2, 3 and 15) compounds produced by reactive ball milling

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Phase boundaries and reversibility of LiBH4/MgH2 hydrogen storage material

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Hydriding characteristics of Mg2Ni prepared by mechanical milling of the product of hydriding combustion synthesis

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Unexpected kinetic effect of MgB2 in reactive hydride composites containing complex borohydrides

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Synchrotron x-ray studies of Ti-doped NaAlH4

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Reversible storage of hydrogen in destabilized LiBH4

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Thermochemistry and crystal structures of lithium, sodium and potassium alanates as determined by ab initio simulations

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Interaction between lithium amide and lithium hydride

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Thermodynamics and dynamics of the Mg-Fe-H system and its potential for thermochemical thermal energy storage

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Investigations on the synthesis, structural and microstructural characterizations of Mg-based K2PtCl6 type (Mg2FeH6) hydrogen storage material prepared by mechanical alloying

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Reversible hydrogen storage via titanium-catalyzed LiAlH4 and Li3AlH6

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Ti-doped NaAlH4 as a hydrogen-storage material -: preparation by Ti-catalyzed hydrogenation of aluminum powder in conjunction with sodium hydride

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Investigation of the perovskite related structures of NaMgH3, NaMgF, and Na3AlH6

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