4.7 Article

Copper-catalyzed aminotrifluoromethylation of alkenes: a facile synthesis nnnof CF3-containing lactams

期刊

ORGANIC CHEMISTRY FRONTIERS
卷 3, 期 2, 页码 222-226

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c5qo00353a

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  1. Duke University
  2. National Science Foundation [CHE-1455220]
  3. Direct For Mathematical & Physical Scien
  4. Division Of Chemistry [1455220] Funding Source: National Science Foundation

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Copper-catalyzed aminotrifluoromethylation of alkenes using amides as nucleophiles has been developed. It provides a rapid and efficient access to a variety of CF3-containing lactams. The reaction proceeds under mild conditions with a good scope and functional group tolerance, offering a valuable method to prepare CF3-containing lactams that are of great potential in pharmaceuticals and agrochemicals.

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