期刊
ORGANIC CHEMISTRY FRONTIERS
卷 3, 期 11, 页码 1420-1424出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6qo00318d
关键词
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资金
- JSPS [15K18837]
- Kitasato University
- Grants-in-Aid for Scientific Research [15K18837] Funding Source: KAKEN
A highly efficient manganese-catalysed hydroperoxidation of carbon-carbon double bonds of enynes as well as styrene derivatives using N-hydroxyphthalimide, N-hydroxybenzotriazole or N-hydroxysuccinimide was developed. This reaction proceeded at room temperature through the direct incorporation of molecular oxygen present in air. The required catalytic loading of manganese(III) acetylacetonate is extremely low (generally 0.02-0.5 mol%, and a minimum of 0.001 mol%).
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