期刊
ORGANIC CHEMISTRY FRONTIERS
卷 3, 期 6, 页码 693-696出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6qo00070c
关键词
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资金
- National Natural Science Foundation of China [21372046, 21532001]
The scaffold of benzo[b]thiophene 1,1-dioxides can be easily constructed through a copper(I)-catalyzed insertion of sulfur dioxide into (2-alkynylaryl)boronic acids. The reaction proceeds in the presence of 10 mol% copper(I) acetate in DMF at 100 degrees C with high efficiency, leading to benzo[b]thiophene 1,1-dioxides in good to excellent yields. The sulfonyl group can be easily introduced via insertion of sulfur dioxide and the subsequent intramolecular 5-endo cyclization affords the core of benzo[b]thiophene 1,1-dioxide.
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