期刊
ORGANIC CHEMISTRY FRONTIERS
卷 3, 期 2, 页码 156-164出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5qo00356c
关键词
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资金
- Federal Ministry of Research and Education (BMBF) (Chemische Prozesse und stoffliche Nutzung von CO2: Technologien fur Nachhaltigkeit und Klimaschutz) [01 RC 1004A]
Herein we report the development of a novel binary catalytic system for the addition of CO2 to epoxides based on zinc iodide and an imidazolium salt. The influence of the nature of the imidazolium ion and the anion has been studied in a test reaction. The optimized system exhibits excellent activity and selectivity. Furthermore, the reaction can be performed under very mild (30 degrees C) and solvent free conditions yielding the desired cyclic carbonates in up to 99%.
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