期刊
ORGANIC CHEMISTRY FRONTIERS
卷 3, 期 1, 页码 14-18出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5qo00289c
关键词
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资金
- National Natural Science Foundation of China [1202049]
- Recruitment Program of Global Experts (1000 Talents Plan)
- Fujian Hundred Talents Program
- Program of Innovative Research Team of Huaqiao University [Z14X0047]
A novel copper-catalyzed chemoselective reduction of a carbon-carbon double or triple bond to a carbon-carbon single bond in alpha,beta-unsaturated ketones is developed. This reaction proceeds under hydrogen gas or stoichiometric metal hydride free conditions. Saturated ketones were obtained in good to excellent yields with a broad substrate scope. Mechanistic studies reveal that the two hydrogen atoms come from H2O in the system. Thus this reaction represents a highly efficient, and remarkably chemo-selective strategy.
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