期刊
ANALYTICAL METHODS
卷 14, 期 27, 页码 2714-2722出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ay00849a
关键词
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资金
- National Natural Science Foundation of China [22075040]
- Jilin Provincial Department of Education
Two fluorescent chemosensors based on MOF-5 and curcumin were designed and synthesized, showing highly selective fluorescence enhancement responses towards Al3+ with low detection limits. These materials can be used as fluorescent sensors to identify and detect Al3+ in water samples.
Two fluorescent chemosensors based on MOF-5 and curcumin (A-curcumin@MOF-5 and B-curcumin@MOF-5) were designed and synthesized. The two curcumin@MOF-5 materials retained the framework structure of MOF-5 and the fluorescence properties of curcumin. Importantly, both curcumin@MOF-5 materials in ethanol displayed highly selective fluorescence enhancement responses toward Al3+ with the special pore structure of MOF-5 as the main reason for the high selectivity. The fluorescence intensities of the two curcumin@MOF-5 materials showed a good linear relationship with Al3+ concentration with low detection limits of 3.10 mu M for A-curcumin@MOF-5 and 2.84 mu M for B-curcumin@MOF-5, respectively. The complexation of curcumin with Al3+ inhibited the photoinduced electron-transfer (PET) process and further enhanced the fluorescence of the curcumin molecules. Both the curcumin@MOF-5 materials can be used as fluorescent sensors to identify and detect Al3+ in water samples.
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