4.7 Article

Robust formation of discrete non-covalent pyrene dimers in an amorphous film by strong π-π interaction

期刊

CHEMICAL COMMUNICATIONS
卷 58, 期 59, 页码 8250-8253

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ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc02125k

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资金

  1. National Natural Science Foundation of China [52073117, 91833304, 51873077, 52103209]
  2. National Key Research and Development Program of China [2020YFA0714603]

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A pyrene-based non-covalent dimer was found to exhibit a strengthened pi-pi interaction in both crystal and amorphous film, indicating its stability and potential as a monomer.
A pyrene-based non-covalent dimer in a crystal showed a strengthened pi-pi interaction, which was robust enough against external disturbances. Such a strong pi-pi interaction made the pyrene-based dimer easily form in the amorphous film, indicating that the dimer could potentially work as the monomer.

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