期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 20, 期 29, 页码 5845-5851出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ob00872f
关键词
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A metal-free inactive C(sp(3))-H bond functionalization of thioethers with styrenes has been developed, using TBHP as an initiator and DBU as a base, achieving moderate yields. Extended experiments were conducted to confirm the radical relay process, reaction energy, and intermediate transformations.
A metal-free inactive C(sp(3))-H bond functionalization of thioethers with styrenes using TBHP as an initiator and DBU as a base has been developed. This transformation has broken through the low activity of thioethers and realized moderate yields. Herein extended experiments were conducted to confirm the radical relay process, reaction energy and intermediate transformations.
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